Product ID:SULFURIC ACID (99%)
MSDS Date:07/01/1982
FSC:6810
NIIN:00-146-7520
MSDS Number: BDCKC

ALLIED-SIGNAL INC, ENGINEERED MATERIALS SECTOR

COLUMBIA RD AND PARK AVE
MORRISTOWN, NJ 07960
US

Cage: 1L164

ALLIED-SIGNAL INC

2332R MORRISTOWN, NJ 07962-2332 US

Telephone: 201-455-4414

Cage: 1L164

SULFURIC ACID (SARA III)

CAS: 7664-93-9

RTECS: WS5600000

Fraction By Weight: 99.0%

OSHA PEL 1 MG/M3

ACGIH TLV: 1 MG/M3; 9192

EPA Report Quantity: 1000 LBS

DOT Report Quantity: 1000 LBS

WATER; CAS #7732-18-5

CAS: 7732-18-5

RTECS: ZC0110000

Fraction By Weight: 01.0%

Routes of Entry: Inhalation:YES Skin:NO Ingestion:NO
Reports of Carcinogenicity:NTP:NO IARC:NO OSHA:NO
Effects of Overexposure:SKIN: CAUSES IRRITATION/CORROSIVE BURNS. EYES:
IRRITATION, CORNEAL BURNS, CONJUNCTIVITIS. INGESTION: IRRITATION,
CORROSIVE BURNS TO MOUTH, THROAT, AND STOMACH. CAN BE FATAL IF
SWALLOWED. INHALATION: I RRITATION/BURNS TO UPPER RESPIRATORY
SYSTEM, LUNGS, ETC.

First Aid:INHALATION: REMOVE TO FRESH AIR. IF NOT BREATHING, GIVE CPR.
IF BREATHING IS DIFFICULT, GIVE OXYGEN. SEE DOCTOR. EYES:
IMMEDIATELY FLUSH WITH PLENTY OF WATER FOR AT LEAST 15 MINUTES. SEE
DOCTOR. SKIN: WASH/RINSE WITH SOAP AND WATER. REMOVECONTAMINATED
CLOTHING/SHOES. SEE DOCTOR. INGESTION: DILUTE WITH H2O/MILK. DO NOT
INDUCE VOMITING. SEE DOCTOR.

Flash Point:NONE
Extinguishing Media:USE WATER SPRAY/SUITABLE AGENTS FOR ADJACENT TANK;
DRY CHEMICAL
Fire Fighting Procedures:WEAR APPROVED SCBA WITH FULL FACEPIECE. COOL
NON-LEAKERS WITH WATER SPRAY.
Unusual Fire/Explosion Hazard:FLAMMABLE/EXPLOSIVE HYDROGEN GAS CAN BE
GIVEN INSIDE METAL DRUMS/STORAGE TANKS. CONCENTRATED ACID CAN
IGNITE COMBUSTIBLE MATERIALS.

Spill Release Procedures:SMALL SPILLS:DILUTE W LG AMT WATER.NEUT
RESIDUE W ALKALI SUCH AS SODA ASH/LIME.ADEQUATE VENT IS REQD DUE TO
RELEASE OF CO2 FROM SODAASH.LG SPILLS:EVACUATE AREA.USE PROTEC
EQUIP.STOP LEAK W/O RISK.DIKE W/ABSORBENT/SAND.PUMP LIQ INTO DRUMS
FOR DISPOSA

Handling and Storage Precautions:USE FULL PROTECTIVE EQUIPMENTS.STORE
IN COOL,WELL-VENTILATED AREA AWAY FROM COMBUSTBLE/REACTVE CHEM.VENT
CNTNRS IN HOT WEATHR TO AVOID H2 BUILD-UP.
Other Precautions:SAFETY SHOWERS/EYEWASH FACILITIES SHOULD BE AVAILABLE
NEARBY H2SO4 HANDLING EQUIP.DO NOT ADD WATER CAUSTIOUSLY W
AGITATION. PKG/UNLOADG AREA NEED EXH SYSTM.

Respiratory Protection:IF REQUIRED USE NIOSH APPROVED RESPIRATOR FOR
MISTS/GAS. MAY REQUIRE SELF-CONTAINED BREATHING APPARATUS.
Ventilation:SUFFICIENT TO REDUCE ACID MIST BELOW TLV LEVELS. MAY
REQUIRE MECHANICAL EXHAUST.
Protective Gloves:ACID RESISTANT
Eye Protection:CHEMICAL SAFETY GOGGLES/FACESHIELD
Other Protective Equipment:ACID RESISTANT APRON, BOOTS, JACKET,
TROUSERS
Supplemental Safety and Health

HCC:C1
Boiling Pt:B.P. Text:590F,310C
Spec Gravity:1.842
Solubility in Water:COMPLETE
Appearance and Odor:OILY, COLORLESS TO SLIGHT YELLOW, CLEAR TO TURBID
LIQUID.

Stability Indicator/Materials to Avoid:YES
OXIDIZERS, FLAMMABLE MATERIALS, REDUCING MATERIALS, CARBIDES,
CHLORATES, SULFIDES
Stability Condition to Avoid:HEATING >300C(572F): YIELDS SULFUR
TRIOXIDE GAS, WHICH IS OXIDIZER/CORROSIVE/TOXIC.
Hazardous Decomposition Products:SULFUR TRIOXIDE. MAY ALSO YIELD
HYDROGEN GAS WITH METAL CONTACT.
Conditions to Avoid Polymerization:AVOID ALLYL COMPOUNDS AND ALDEHYDES:
UNDERGOES POLYMERIZATION WITH THESE.

Waste Disposal Methods:DILUTE W/WATER,NEUTRALIZE W/ALKALI & FLUSH TO
SEWER WITH PLENTY OF WATER IF PERMITTED BY APPLICABLE DISPOSAL
REGULATIONS. NEUTRALIZED WASTE MAY HAVE TO BE DISPOSED OF BY AN
APPROVED CONTRACTOR. DISPOS ER MUST COMPLY W/FED,STATE & LOCAL
DISPOSAL REGS.

Disclaimer (provided with this information by the compiling agencies):
This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.