Product ID:FREON TF CLEANING AGENT FREON PRECISION CLEANING AGENT
MSDS Date:10/19/1996
FSC:6850
NIIN:00-319-0834
MSDS Number: BDWSC

Emergency Phone: 800-441-3637/800-424-9300(CHEMTREC)

Info Phone: 800-441-7515/MSDS 302-992-3511

Preparer: ENGINE & PRODUCT SAFETY

Cage: 18873

Telephone: 504-366-4542

Cage: 0T5C6

1,1,2-TRICHLORO-1,2,2-TRIFLUOROETHANE (FREON 113) (SARA

CAS: 76-13-1

RTECS: KJ4000000

Fraction By Weight: 100%

OSHA PEL 1000 PPM

ACGIH TLV: 1000PPM/1250STEL; 96

LD50 LC50 Mixture:ORAL LD50: 43000MG/KG IN RATS.
Routes of Entry: Inhalation:NO Skin:NO Ingestion:NO
Reports of Carcinogenicity:NTP:NO IARC:NO OSHA:NO
Health Hazards Acute and Chronic:VERY LOW TOXICITY BY
INHAL.LIFE-THREATENING EXPO MAY OCCUR IF HNDLD CARELESSLY.VAP
HEAVIER THAN AIR POSING HAZ OF ASPHYXIATION IF TRAPPED IN
ENCLSD/LOW PLACES.@FLAME TEMPS CMPD DECPO TO HYDROGEN FLUO
RIDE-LETHAL @LOW CONC.PRODUCT POSES HAZOF FATAL HEART IRREG IF
INHAL @HI CONC.SKIN/EYE IRRIT.PROL SKIN (SIGNS/SYMPTOMS)
Explanation of Carcinogenicity:PER MSDS:NONE OF COMPONENTS PRESENT IN
MATL @CONC =/> 0.1% ARE LISTED BY IARC/NTP/OSHA/ACGIH AS
CARCINOGEN.
Effects of Overexposure:HEALTH HAZ:CONTACT DRYING.INHAL/INGEST CAUSE
DIZZ,HEAD,CONFUSION,INCOORD,LOSS OF CONSC. MILD SKIN/EYE
IRRIT,DISCOMFT,RASH,TINGLING NUMB,COLD,DRY.TEARING,BLUR
VISION.ASPIRATION-CHEM PNEUMONIA,COUGH,GAS P,CHOKE,BREATH
SHORTNESS,BLUISH DISCOLOR,RAPID
BREATH,DROWS,CONF,COMA,SEIZURES.TEMP CNS DEPRESS,ALT HEART ELECT
ACTIVITY
Medical Cond Aggravated by Exposure:NONE SPECIFIED BY MANUFACTURER.

First Aid:INHAL:IMMED REMOVE TO FRESH AIR.KEEP CALM.NOT BREATH GIVE ART
RESP;DIFFI BREATH GIVE OXY.CALL DR.SKIN:FLUSH W/PLENTY OF WATER FOR
15MINS.IRRIT PRESENT GET MED ATTN.EYE:IMMED FLUSH W/PLENTY OF WATER
FO R 15MINS.CALL DR.INGEGST:NO SPECIFIC INTERVENTION INDICATED AS
CMPD NOT LIKELY TO BE HAZ BY INGEST.DO NOT INDUCE VOMIT.HOWEVER
CONSULT DR IF NECESSARY.DR:ADMIN ACTIVATE CHARCOAL
SLURRY(50G/400ML)(SUP)

Flash Point:WILL NOT BURN
Autoignition Temp:Autoignition Temp Text:NP
Lower Limits:NP
Upper Limits:NP
Extinguishing Media:NONE SPECIFIED BY MANUFACTURER.
Fire Fighting Procedures:USE WATERSPRAY/FOG TO COOL
CNTNR.SELF-CONTAINED BREATHING APPARATUS(SCBA)REQUIRED IF DRUMS
RUPTURE & CONTENTS SPILLED UNDER FIRE CONDITIONS.
Unusual Fire/Explosion Hazard:DRUMS MAY RUPTURE UNDER FIRE CONDITIONS.
DECOMPOSITION MAY OCCUR.

Spill Release Procedures:REVIEW MSDS.USE APPROPRIATE PPE DURING
CLEANUP.VENTILATE AREA.DONT FLUSH INTO SEWERS.DIKE/COLLECT ON
ABSORBENT MATL.TRANSF TO STEEL DR FOR RECOVER/DISPO.USE SCBA FOR LG
SPILLS.COMPLY W/FED/STATE/LOC R EGS ON REPORTING RELEASES.
Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER.

Handling and Storage Precautions:AVOID BREATH VAP/PROL SKIN EXPO.USE
W/SUFFICIENT VENTI TO KEEP EMPLOYEE EXPO BELOW RECOMMENDED
LIMITS.STORE IN CLEAN DRY AREA.DO NOT HEAT >125F.
Other Precautions:NONE SPECIFIED BY MANUFACTURER.

Respiratory Protection:UNDER NORMAL USE CONDITIONS NO RESPIRATORY
PROTECTION IS REQUIRED WHEN USING THIS PRODUCT.SELF-CONTAINED
BREATHING APPARATUS IS REQUIRED IF LARGE SPILL OCCURS.
Ventilation:NORMAL VENTIL FOR STD USE PROCEDURES GEN ADEQUATE.LOC EXHAU
FOR WHEN LG AMTS RELEASED.MECHAN VENTI IN LOW/ENCLSD PLACES.
Protective Gloves:IMPERVIOUS GLOVES.
Eye Protection:CHEM SPLASH GOGG.
Other Protective Equipment:NONE SPECIFIED BY MANUFACTURER.
Work Hygienic Practices:NONE SPECIFIED BY MANUFACTURER.
Supplemental Safety and Health
1STAID:ADMIN 5ML/KG(350ML).CATECHOLAMINE DRUGS SHOULD BE USED W/SPECIAL
CAUTION IN SITUATIONS OF EMERG LIFE SUPPORT.EMESIS/GASTRIC LAVAGE
SHOULDN'T BE EMPLOYED UNLESS RISK IS JUSTIFIED BY PRESENCE OF ADDN
TOXIC SUBSTANCES.

HCC:N1
Boiling Pt:B.P. Text:118F,48C
Melt/Freeze Pt:M.P/F.P Text:NP
Decomp Temp:Decomp Text:NP
Vapor Pres:6.46PSIA
Vapor Density:2.9
Spec Gravity:DENS=1.57G/CC
pH:NEUTRA
Viscosity:NP
Evaporation Rate & Reference:>1 (CCL4=1).
Solubility in Water:0.02%, NEGLIGIBLE.
Appearance and Odor:SLIGHT ETHEREAL ODOR, LIQUID, CLEAR, COLORLESS.
Percent Volatiles by Volume:100
Corrosion Rate:NP

Stability Indicator/Materials to Avoid:YES
INCOMPATIBLE W/ALKALI OR ALKALINE EARTH METALS-POWDERED AL, ZN, BE,
ETC.
Stability Condition to Avoid:AVOID OPEN FLAMES AND HIGH TEMPERATURES.
Hazardous Decomposition Products:DECOMP PROD HAZ.CAN BE DECOMPO BY HI
TEMP(OPN FLAME,GLOW METAL SURFACES,ETC)FORM HCL,HYDROFLUORIC
ACIDS,CARBONYL HALIDES

Waste Disposal Methods:COMPLY W/FED/STATE/LOC REGS.REMOVE TO PERMITTED
WASTE DISPO FACILITY.EPA HAZ WASTE #:F001,F002 MAY APPLY TO WASTE
MATLS. CONTAINS TOXIC CHEM REQUIRED UNDER SEC 313 TITLE III
SARA/40CFR372 TO BE REPORT ED.

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