Product ID:TRI-ETHANE 366
MSDS Date:10/05/1988
FSC:6810
NIIN:00-551-1487
MSDS Number: BFDYX

PPG INDUSTRIES,INC.

1-PPG PLACE
PITTSBURGH, PA 15272
US

Emergency Phone: 304-843-1300

Info Phone: 304-843-1300

Preparer: R. KENNETH LEE

Cage: GO796

SHIELDING SYSTEMS CORP

PITTSBURGH, PA 15272 US

Telephone: 1-800-245-2974 (CAL HYPO)

Cage: 49942

METHYL CHLOROFORM (1,1,1-TRICHLOROETHANE) (SARA III)

CAS: 71-55-6

RTECS: KJ2975000

Fraction By Weight: 96.0%

OSHA PEL 350 PPM

ACGIH TLV: 350 PPM/450STEL;9394

EPA Report Quantity: 1000 LBS

DOT Report Quantity: 1000 LBS

1,4-DIOXANE (DIETHYLENE DIOXIDE) (SARA III)

CAS: 123-91-1

RTECS: JG8225000

OSHA PEL S, 100 PPM

ACGIH TLV: S, 25 PPM; 9293

EPA Report Quantity: 100 LBS

DOT Report Quantity: 100 LBS

GLYCOL METHYLENE ETHER

CAS: 646-06-0

RTECS: JH6760000

SEC-BUTYL ALCOHOL (SARA III)

CAS: 78-92-2

RTECS: EO1750000

OSHA PEL 150 PPM

ACGIH TLV: 100 PPM; 9293

OTHER STABILIZERS

LD50 LC50 Mixture:LD50 RAT ORAL10-12G/KG;DERMAL RAB:15G/KG
Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:NO IARC:NO OSHA:NO
Health Hazards Acute and Chronic:ACUTE:IRRITATION OF
EYES,SKIN,RESPIRATORY OR G.I. TRACT,CNS EFFECTS LIKE
HEADACHE,DIZZINESS,NAUSEA,LOSS OF CO-ORDINATION.
CHRONIC:DERMATITIS.
Explanation of Carcinogenicity:DATA PER MSDS.
Effects of
Overexposure:INHALE:DIZZINESS,NAUSEA,UNCONSCIOUSNESS.SKIN/EYE:IRRIT
ANT.INGEST:IRRITATION OF THE MOUTH.
Medical Cond Aggravated by Exposure:NO DATA AVAILABLE.

First Aid:INHALE:REMOVE TO FRESH AIR.GIVE CPR/OXYGEN IF NEEDED.
EYE/SKIN:FLUSH WITH PLENTY OF WATER. INGEST:IF CONSCIOUS,DRINK
LARGE QUANTITIES OF WATER,DO NOT INDUCE VOMITING.TAKE TO A
HOSPITAL;IF UNCONSCIOUS, TAKE IMMEDIATELY TO A HOSPITAL.

Lower Limits:7
Upper Limits:15
Extinguishing Media:CO*2, FOAM, DRY CHEM & H*2O FOG.
Fire Fighting Procedures:WEAR SELF-CNTND BRTHG APP
Unusual Fire/Explosion Hazard:VAPORS CONCENTRATED IN A CONFINED OR
POORLY VENTILATED AREA CAN BE IGNITED WITH A HIGH ENERGY SPARK.

Spill Release Procedures:EVACUATE & VENTILATE THE AREA.STAY UPWIND.WEAR
PROPER PROTECTION.DIKE AREA TO CONTAIN SPILL.AVOID CONTAMINATING
WATER.RECOVER SPILLED MATERIAL ON ABSORBENTS & SWEEP INTO CLOSED
CONTAINERS.

Handling and Storage Precautions:DO NOT USE IN POORLY VENTILATED OR
CONFINED AREA.KEEP CONTAINER CLOSED.DO NOT STORE OR STACK ALUMINUM
IN CONTACT WITH TRI-ETHANE-POSSIBLE SOLV DECOMPO
Other Precautions:AVOID PROLONGED OR REPEATED BREATHING OF VAPOR. AVOID
CONTACT WITH EYES OR PROLONGED/REPEATED CONTACT WITH SKIN. DO NOT
USE IN POORLY VENTILATED OR CONFINED SPACES.

Respiratory Protection:USE NIOSH/MSHA APPROVED RESPIRATOR FOR ORGANIC
VAPORS/MIST IF ABOVE PEL/TLV.
Ventilation:LOCAL EXHAUST TO MAINTN BELOW TLV.
Protective Gloves:VITON
Eye Protection:CHEM SPLASH GOGGLES
Other Protective Equipment:PROTECTIVE CLOTHING,EYE-WASH
FACILITIES,BOOTS,APRON.
Work Hygienic Practices:AVOID CONTACT WITH EYES AND SKIN;DO NOT BREATHE
VAPORS/MIST.
Supplemental Safety and Health

HCC:T4
Boiling Pt:B.P. Text:72-88C
Vapor Pres:135
Vapor Density:4.54
Spec Gravity:1.30-1.32
pH:6-7.5
Evaporation Rate & Reference:0.35,ETHER=1
Solubility in Water:NEG.
Appearance and Odor:CLEAR,COLORLESS LIQUID WITH ETHER-LIKE ODOR.
Percent Volatiles by Volume:100

Stability Indicator/Materials to Avoid:YES
CAUSTIC SODA,OXIDIZING MATERIALS.
Stability Condition to Avoid:OPEN FLAMES,HOT SURFACES,ELECTRIC ARCS.
Hazardous Decomposition Products:HCL,TRACES OF PHOSGENE.

Waste Disposal Methods:KEEP IN COVERED DRUMS,PENDING DISPOSAL. HANDLE &
DISPOSE IN FULL COMPLIANCE WITH ALL APPLICABLE
INTERNATIONAL,FEDERAL,STATE, & LOCAL REGULATIONS.

Disclaimer (provided with this information by the compiling agencies):
This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.