Product ID:DIBROM 14 CONCENTRATE
MSDS Date:12/19/1988
FSC:6840
NIIN:01-099-9844
MSDS Number: BGLTT

CHEVRON ENVIRONMENTAL HEALTH CENTER INC.

15299 SAN PABLO AVE.
RICHMOND, CA 94804-0054
US

Emergency Phone: 415-233-3737

Info Phone: 415-233-3737

Cage: 0AHD1

SUMMIT CHEMICAL CO

BALTIMORE, MD 21224-2028 US

Telephone: 410-282-5200

Cage: 6R717

DIMETHYL-1,2-DIBROMO-2,2-DICHLOROETHYL PHOSPHATE (NALED)

CAS: 300-76-5

RTECS: TB9450000

Fraction By Weight: 85%

OSHA PEL S, 3 MG/M3

ACGIH TLV: S, 3 MG/M3; 9192

EPA Report Quantity: 10 LBS

DOT Report Quantity: 10 LBS

NON-HAZARDOUS INGREDIENTS (INERT)

Fraction By Weight: 15%

DICHLORVOS (DDVP) (SARA III)

CAS: 62-73-7

RTECS: TC0350000

Fraction By Weight: 1.5%

OSHA PEL S, 1 MG/M3

ACGIH TLV: S, 0.1 MG/M3; 9192

EPA Report Quantity: 10 LBS

DOT Report Quantity: 10 LBS

LD50 LC50 Mixture:ORAL LD50 (RAT) = 376 MG/KG BODY WT.
Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:NO IARC:NO OSHA:NO
Health Hazards Acute and Chronic:ACUTE: CORROSIVE TO EYES; CAUSES
DAMAGE. CORROSIVE TO SKIN; MAY CAUSE DAMAGE. MAY CAUSE ALLERGIC
SKIN REACTIONS. MODRATELY TOXIC BY SKIN ABSORPTION. BREATHING VAPOR
OR MIST MAY BE IRRITATING TO THE RE SPIRATORY TRACT & CAUSE
SYSTEMIC TOXICITY. MODERATE ACUTE TOXICITY BY INGESTION. CHRONIC:
MAY INHIBIT CHOLINESTERASE.
Explanation of Carcinogenicity:NONE OF THE CHEMICALS IN THIS PRODUCT
ARE LISTED AS CARCINOGENIC BY NTP, IARC OR OSHA.
Effects of Overexposure:INHIBITS THE ENZYME CHOLINESTERASE. THE
FOLLOWING SIGNS & SYMPTOMS MAY BE DELAYED UP TO 12 HOURS AFTER
OVEREXPOSURE: HEADACHE, DIZZINESS, WEAKNESS, CONSTRICTION OF THE
PUPIL OF THE EYE, BLURRED OR DAR K VISION, EXCESSIVE SALIVATION OR
NASALDISCHARGE, PROFUSE SWEATING, ABDOMINAL CRAMPS, NAUSEA AND
VOMITING.
Medical Cond Aggravated by Exposure:PERSONS WITH CHRONIC RESPIRATORY
DISORDERS OR PRE-EXISTING DERMATITIS SHOULD USE EXTRA CARE IN
HANDLING THIS PRODUCT.

First Aid:IF POISONING IS SUSPECTED, IMMEDIATELY CONTACT A PHYSICIAN OR
POISON CONTROL CENTER. INHALATION: MOVE TO FRESH AIR. GIVE CPR IF
NECESSARY. EYE: IMMEDIATELY RINSE WITH LARGE AMOUNTS OF WATER FOR
15 MIN UTES. GET MEDICAL HELP. SKIN: REMOVE CONTAMINATED CLOTHING &
SHOES. WASH WITH PLENTY OF SOAP AND WATER. INGESTION: DO NOT INDUCE
VOMITING. GIVE WATER TO DRINK IF CONSCIOUS. GET MEDICAL ATTENTION.

Flash Point Method:SCC
Flash Point:132F,56C
Autoignition Temp:Autoignition Temp Text:UNKNON
Extinguishing Media:USE CARBON DIOXIDE, FOAM, DRY CHEMICAL, OR WATER
FOG.
Fire Fighting Procedures:FIRE FIGHTERS SHOULD USE NIOSH APPROVED SCBA &
FULL PROTECTIVE EQUIPMENT WHEN FIGHTING CHEMICAL FIRE. MINIMIZE THE
AMOUNT OF WATER USED FOR FIRE FIGHTING.
Unusual Fire/Explosion Hazard:LIQUID EVAPORATES & FORMS VAPOR (FUMES)
WHICH CAN CATCH FIRE & BURN WITH EXPLOSIVE VIOLENCE. INVISIBLE
VAPOR SPREADS EASILY & CAN BE IGNITED EASILY BY FLAME ETC

Spill Release Procedures:CLEAN UP SPILLS IMMEDIATELY, OBSERVING
PRECAUTIONS IN SPECIAL PROTECTIVE INFORMATION AND ON PRODUCT LABEL.
COVER SPILL WITH GENEROUS AMOUNT OF OIL DRY, CAT LITTER, CLAY OR
OTHER ABSORBENT. USE A STIFF BROOM TO MIX THOROUGHLY. SCRUB
CONTAMINATED AREA.
Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER.

Handling and Storage Precautions:STORE IN A WELL-VENTILATED SECURE AREA
OUT OF THE REACH OF CHILDREN AND DOMESTIC ANIMALS. DO NOT STORE
FOOD, BEVERAGES OR TOBACCO PRODUCTS IN AREA.
Other Precautions:PREVENT EATING, DRINKING, TOBACCO USAGE, AND COSMETIC
APPLICATION IN AREAS WHERE THERE IS A POTENTIAL FOR EXPOSURE TO THE
MATERIAL. ALWAYS WASH THOROUGHLY AFTER HANDLING.

Respiratory Protection:WEAR A NIOSH-APPROVED FULL FACE MASK CHEMICAL
CARTRIDGE RESPIRATOR WITH ORGANIC VAPOR CARTRIDGE AND PESTICIDE
PREFILTER.
Ventilation:USE ADEQUATE VENTILATION TO KEEP THE AIRBORNE
CONCENTRATIONS OF THIS MATERIAL BELOW THE RECOMMENDED EXPOSURE
STANDARD.
Protective Gloves:VITON RUBBER GLOVES
Eye Protection:CHEMICAL SAFETY GOGGLES AND FACE SHIELD.
Other Protective Equipment:WATERPROOF BOOTS, LONG-SLEEVED SHIRT, LONG
PANTS AND HAT. EYE WASH STATION & SAFETY SHOWER SHOULD BE
AVAILABLE.
Work Hygienic Practices:ALWAYS WASH THOROUGHLY AFTER HANDLING. LAUNDER
CONTAMINATED CLOTHING BEFORE REUSE. AVOID SKIN CONTACT & BREATHING
MISTS.
Supplemental Safety and Health
NALED DID NOT CAUSE ANY ADVERSE REPRODUCTIVE EFFECTS IN RATS AND WAS
NOT TERATOGENIC IN RATS OR RABBITS. NALED WAS NOT MUTAGENIC IN
STUDIES USING SEVERAL TEST SYSTEMS. THE ONLY SIGNIFICANT FINDING IN
TEST SPECIES REPEATEDLY ADMINISTERED NALED WAS DOSE-DEPENDENT
INHIBITION OF CHOLINESTERASE.

HCC:T4
Boiling Pt:B.P. Text:302F,150C
Spec Gravity:1.96
Solubility in Water:SLIGHT
Appearance and Odor:LIGHT STRAW-COLORED LIQUID WITH SLIGHTLY PUNGENT
ODOR.

Stability Indicator/Materials to Avoid:YES
UNSTABLE IN THE PRESENCE OF IRON OR ALKALINE MEDIA. HYDROLYZES SLOWLY
UNDER NEUTRAL OR ACID CONDITIONS.
Stability Condition to Avoid:EXPOSURE TO DIRECT SUNLIGHT MAY CAUSE SLOW
DECOMPOSITION.
Hazardous Decomposition Products:THERMAL DECOMPOSITION MAY PRODUCE
TOXIC COMPOUNDS OF PHOSPHORUS, CHLORINE & BROMINE. INCOMPLETE
BURNING: CARBON MONOXIDE

Waste Disposal Methods:DO NOT REUSE PRODUCT CONTAINERS. DISPOSE OF
PRODUCT CONTAINERS, WASTE CONTAINERS, AND RESIDUES ACCORDING TO
LOCAL, STATE, AND FEDERAL HEALTH AND ENVIRONMENTAL REGULATIONS.

Disclaimer (provided with this information by the compiling agencies):
This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.