Product ID:MIL-C-46168D PART B 4:1 BLEND
MSDS Date:11/17/1988
FSC:8010
NIIN:01-260-0913
Kit Part:Y
MSDS Number: BHBFJ

NILES CHEMICAL PAINT COMPANY

225 FORT STREET
NILES, MI 49120
US

Emergency Phone: 219-236-5856 (24 HOURS)

Info Phone: 616-683-3377 (INFORMATION)

Preparer: MIKE LICHATOWICH

Cage: 02388

NILES CHEMICAL PAINT

307 NILES, MI 49120 US

Telephone: 616-683-3377/219-236-5856

Cage: 02388

HOMOPOLYMER OF HDI

CAS: 28182-81-2

RTECS: NQ9170000

Fraction By Weight: 75%

1,6-DIISOCYANATOHEXANE (HEXAMETHYLENE DIISOCYANATE)

CAS: 822-06-0

RTECS: MO1740000

Fraction By Weight: <0.7%

ACGIH TLV: 0.005 PPM; 9192

EPA Report Quantity: 1 LB

DOT Report Quantity: 1 LB

XYLENES (O-,M-,P- ISOMERS) (SARA III)

CAS: 1330-20-7

RTECS: ZE2100000

Fraction By Weight: 12.5%

OSHA PEL 100 PPM/150 STEL

ACGIH TLV: 100 PPM/150STEL;9192

EPA Report Quantity: 1000 LBS

DOT Report Quantity: 1000 LBS

N-BUTYL ACETATE (SARA III)

CAS: 123-86-4

RTECS: AF7350000

Fraction By Weight: 12.5%

OSHA PEL 150 PPM/200 STEL

ACGIH TLV: 150 PPM/200STEL;9192

EPA Report Quantity: 5000 LBS

DOT Report Quantity: 5000 LBS

Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Health Hazards Acute and Chronic:IRRITATE MUCOUS MEMBRANE IN
NOSE,THROAT,LUNGS CAUSING RUNNY NOSE,SORE THROAT, COUGHING,CHEST
DISCOMFORT,SHORT BREATH,REDUCED LUNG FUNCTIONS. EXPOSURE ABOVE
TLV MAY LEAD TO BRONCHITIS,ASTHMA,PULMON ARY EDEMA.DELIBERATE
INHALE CAN CAUSEPERMANENT BRAIN/NERVOUS SYS DAMAGE,DEATH.CAUSE SKIN
IRRITATION,EYE IRRITATION.
Effects of
Overexposure:EYE:TEARING,RED,SWELLING.INGEST:IRRITATION,CORROSIVE
ACTION IN MOUTH,STOMACH, GI TRACT.INHALE:CAN DEVELOP ISOCYANATE
SENSITIZATION(CHEST TIGHTNESS,WHEEZING, COUGH,SHORT
BREATH,ASTHMATIC ATTACK,CAN BE DELAYED SEVERAL HOURS.
SKIN:REDDENINGSWELLING,RASH,SCALING,BLISTER,SKIN
SENSITIZATION,CRACKED.
Medical Cond Aggravated by Exposure:ASTHMA,RESPIRATORY DISORDERS SUCH
AS BRONCHITIS, EMPHYSEMA, AND HYPERREACTIVITY:SKIN ALLERGIES AND
ECZEMA.

First Aid:INHALE:REMOVE.GIVE OXYGEN/CPR IF NEEDED.GET MED
ATTENTION.ASTHMATIC SYMPTOMS MAYDEVELOP.CAN BE IMMEDIATE OR
DELAYED.SKIN:REMOVE CLOTHING IMMEDIATELY.WASH AFFECTED AREA WITH
SOAP AND WATER.GET MED ATTE NTION IF IRRITATION
DEVELOPS/PERSISTS.EYE:FLUSH WITH CLEAN LUKEWARM WATER FOR AT LEAST
15 MIN.OCC LIFT EYELIDS.GET MEDATTN.INGEST:DO NOT INDUCE
VOMITING.GET MEDICAL ATTENTION.

Flash Point Method:PMCC
Flash Point:91F/33C
Lower Limits:1.0
Upper Limits:7.6
Extinguishing Media:FOAM,"ALCOHOL" FOAM, CO2, DRY CHEMICAL
Fire Fighting Procedures:SELF-CONTAINED BREATHING APPARATUS AND FULL
PROTECTIVE CLOTHING SHOULD BE WORN BY FIRE-FIGHTERS.
Unusual Fire/Explosion Hazard:HIGHLY TOXIC GASES MAY BE GENERATED BY
THERMAL DECOMP,OR COMBUSTION.ISOLATE FROMHEAT. CLOSED CONTAINERS
MAY EXPLODE WHEN EXPOSED TO EXTREME HEAT.

Spill Release Procedures:EVACUATE.REMOVE SOURCES OF IGNITION,VENT
AREA.DIKEOR IMPOUND SPILLED MATERIAL,CONTROL FURTHER
SPILL-AGE.NOTIFY APPROP AUTHOR.PUT SAWDUST,ETC ON SPILL.POUR DECONT
SOLV OVER SPILL,ALLOW TO REACT FOR 10 MIN,PUT IN OPEN CONT COVER
LOOSE,LET STAND 48 HOUR
Neutralizing Agent:TERGITOL TMN-10(20%)WATER(80%),CONC
AMMONIA(3-8%)DETERGENT(2%)WATER(90-95%).

Handling and Storage Precautions:TEMP:32 F(0C)MIN/122 F(50C)MAX.AVERAGE
SHELF LIFE;12 MONTHS @ 77 F (25C).
Other Precautions:SINCE THIS PRODUCT MEETS CRITERION OF IGNITIBILITY,IT
IS HAZARDOUS WHEN DISCARD.IF CONTAINER IS EXPOSED TO HIGH HEAT,IT
CAN BE PRESSURIZED AND POSSIBLY RUPTURE EXPLOSIVELY.HDI REACTS SLOW
W/WTR TO FOR M C02 GAS.CAN CAUSE CONT TO EXPAND/EXPLD

Respiratory Protection:RESPIRATOR IS MANDATORY IF SPRAYING/WORKING IN
CONFINED AREA.(POSITIVE PRESSURE)RESPIRATOR THAT IS
RECOMMENDED/APPROVED FOR USE IN ISOCYANATE CONTAINING ENVI- ROMENT
MAY BE NECESSARY.
Ventilation:EXHAUST VENTILATION SUFFICIENT TO KEEP THE AIRBORNE CON-
CENTRATION OF SOLVENT/HDI,POLYISOCYANATE BELOW TLV'S.
Protective Gloves:CHEMICAL RESISTANT GLOVES.
Eye Protection:SAFETY GLASSES,SPLASH GOGGLES,FACESHIELD
Other Protective Equipment:SKIN CREAMS,PROTECTIVE CLOTHING.SAFETY
SHOWERS/EYEWASH STATIONS.EDUCATE EMPLOYEES IN SAFE USE OF
PRODUCT.
Work Hygienic Practices:WASH HANDS THOROUGHLY BEFORE EATING AND BEFORE
USING REST- ROOMS.SMOKE ONLY IN SMOKING AREAS.
Supplemental Safety and Health
CONTACT LENSES SHOULD NOT BE USED.MATERIAL IS HARD TO REMOVE FROM SKIN
WHEN CUREKEEP FROM HEAT,SPARKS OPEN FLAMES.GROUND CONT DURING
STORAGE/TRANSFER OPERATIONSEYES:STAIN FOR EVIDENCE OF CORNEAL INJUR
Y.SKIN:SKIN SENSITITZER,TREAT SYMPTOMAT-ICALLY.INGEST:THERE IS NO
SPECIFIC ANTIDOTE.INHALE:KNOWN AS PULMONARY SENSITIZER

Boiling Pt:B.P. Text:NE
Vapor Density:>AIR
Evaporation Rate & Reference:SLOWER THAN ETHER
Solubility in Water:INSOLUBLE/REACTS WTR
Appearance and Odor:CLEAR TO PALE YELLOW LIQUID/SOLVENT ODOR
Percent Volatiles by Volume:CA 30

Stability Indicator/Materials to Avoid:YES
WATER, AMINES, STRONG BASES, ALCOHOLS, METAL COMPOUNDS, AND SURFACE
ACTIVE MATERIALS.
Stability Condition to Avoid:MOISTURE, HIGH TEMPERATURES, SHOCK FROM
DROPPING
Hazardous Decomposition Products:BY HIGH HEAT AND FIRE: CARBON
DIOXIDE,CARBON MONOXIDE,OXIDESOF NITROGEN, TRACES OF HNC AND HDI.
Conditions to Avoid Polymerization:MAY OCCUR IF IN CONTACT W/ MOISTURE
OR OTHER MATERIALS WHICHREACT W/ ISOCYANATES. MAY OCCUR AT
TEMPERATURES OVER 400F.

Waste Disposal Methods:MUST BE DISPOSED OF IN ACCORD W/FED,STATE,LOCAL
ENVIORNMENTAL REGS.INCINERATION IS PREFERRED.EMPTYCONT MUST BE
HANDLED W/CARE DUE TO PROD RESIDUE, FLAMMABLE SOLV
VAPOR.DECONTAMINATE CONT PRIOR TO DISPOSAL.DONT HEAT/CUT ON/NEAR
EMPTY CONTAINER.

Disclaimer (provided with this information by the compiling agencies):
This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.