Product ID:CPE134020 AEROZINE-50 BLEND
MSDS Date:01/01/1991
FSC:9135
NIIN:00-753-4919
MSDS Number: BHGRJ

OLIN CORPORATION

120 LONG RIDGE ROAD
STAMFORD, CT 06904

Emergency Phone: (203) 356-3449

Info Phone: (203) 356-3449

Preparer: C. J. MICHAELS

Cage: 0G578

OLIN CORPORATION

STAMFORD, CT 06904-1355 US

Telephone: 203-356-3449

Cage: 0G578

HYDRAZINE

CAS: 302-01-2

RTECS: MU7175000

Fraction By Weight: 50-55%

OSHA PEL S, 1 PPM

ACGIH TLV: S, 0.1 PPM, A2; 9293

EPA Report Quantity: 1 LB

DOT Report Quantity: 1 LB

1,1-DIMETHYLHYDRAZINE, UDMH

CAS: 57-14-7

RTECS: MV2450000

Fraction By Weight: 45-50%

OSHA PEL 1 MG/CUM

ACGIH TLV: 0.025 MG/CUM IC (A2)

EPA Report Quantity: 10 LBS

DOT Report Quantity: 10 LBS

WATER, H2O

CAS: 7732-18-5

RTECS: ZC0110000

Fraction By Weight: 0.5-2%

LD50 LC50 Mixture:ORAL LD50 (RAT): = 90 MG/KG
Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:NO IARC:NO OSHA:NO
Health Hazards Acute and Chronic:INHALATION: NOSE/THROAT/UPPER
RESPIRATORY TRACT/LUNG IRRITATION/BRONCHITIS/PULMONARY
EDEMA/LUNG/LIVER/KIDNEY/BLOOD DAMAGE/HEMOLYSIS OF BLOOD CELLS.
SKIN: ABSORPTION/IRRITATION/BURNS/DERMATITIS. EYES:
HARMFUL/INFLAMMATION/SWELLING/REDNESS/DISCHARGE/TEMPORARY
BLINDNESS/BURNS/PERMANENT CORNEAL DAMAGE/VISION IMPAIRMENT.
Explanation of Carcinogenicity:NONE
Effects of Overexposure:INHALATION:
VOMITING/DIARRHEA/NAUSEA/DIZZINESS/CYANOSIS/CONVULSIONS/FATAL.
SINGLE EXPOSURE WOULD NOT LIKELY PRODUCE FETAL
TOXICITY/MALFORMATIONS, BUT SEVERAL EXPOSURE MAY CAUSE EFFECTS TO
FETUS. INGES TION: GASTROINTESTINAL TRACT
IRRITATION/NAUSEA/VOMITING/DIARRHEA/ABDOMINAL PAIN/BLEEDING/TISSUE
ULCERATION/ABSORPTION.
Medical Cond Aggravated by Exposure:LIVER, KIDNEY, BLOOD DISEASE AS
WELL AS ASTHMA & CARDIOVASCULAR DISEASE.

First Aid:EYES: FLUSH W/PLENTY OF WATER FOR AT LEAST 15 MINS. SKIN:
FLUSH W/WATER FOR AT LEAST 15 MINS. INGESTION: DRINK PLENTY OF
WATER. INDUCE VOMITING. DON'T GIVE ANYTHING BY MOUTH IF UNCONSCIOUS
OR CONVULSI NG. INHALATION: REMOVE TO FRESH AIR. IFBREATHING IS
DIFFICULT, ADMINISTER OXYGEN. IF BREATHING STOPS, GIVE ARTIFICIAL
RESPIRATION. ENSURE ADEQUATE VENTILATION. OBTAIN MEDICAL ATTENTION
IN ALL CASES.

Flash Point Method:COC
Flash Point:34.7F
Lower Limits:2%
Upper Limits:100%
Extinguishing Media:ALCOHOL FOAM, CO2, OR WATER SPRAY
Fire Fighting Procedures:USE WATER TO COOL FIRE EXPOSED CONTAINERS.
WEAR FULL ENCAPSULATED SUIT & SELF-CONTAINED BREATHING APPARATUS.

Spill Release Procedures:REMOVE ALL IGNITION SOURCES. STOP SOURCE OF
SPILL AS SOON AS POSSIBLE. DIKE SPILL AREA & DILUTE W/WATER ON 3
TO 1 RATION. AFTER DILUTION, NEUTRALIZE. TREAT/ABSORB IN SAND,
CLAY, OR NON-FLAMMABLE ABSO RBENT, CONTAINERIZE.

Handling and Storage Precautions:STORE IN WELL-VENTILATED AREA. DON'T
CONTAMINATE. ELECTRICALLY GROUND ALL CONTAINERS & HANDLING
EQUIPMENT. DON'T EXPOSE TO DIRECT LIGHT.
Other Precautions:AVOID CONTACT W/SKIN, EYES, & CLOTHING. AVOID
BREATHING VAPORS.

Respiratory Protection:USE NIOSH/MSHA APPROVED RESPIRATOR WHEN >TLV.
Ventilation:LOCAL EXHAUST TO KEEP Protective Gloves:BUTYL RUBBER OR NEOPRENE
Eye Protection:FACE SHIELD, SAFETY GLASSES
Other Protective Equipment:BOOTS, APRON, FULL CHEMICAL IMPERMEABLE
SUIT. HARD HAT, SPLASH-PROOF GOGGLES, & IMPERVIOUS CLOTHING WHEN
FIGHTING FIRE.
Work Hygienic Practices:REMOVE/LAUNDER CONTAMINATED CLOTHING BEFORE
REUSE.
Supplemental Safety and Health
VAPOR DENSITY: 1.1 (HYDRAZINE). MATERIALS TO AVOID: METAL OXIDES, IRON,
COPPER, LEAD, MANGANESE, MOLYBDENUM, COTTON WASTE, & SAWDUST.

Boiling Pt:B.P. Text:158F
Melt/Freeze Pt:M.P/F.P Text:18-21F
Decomp Temp:Decomp Text:535F
Vapor Pres:142 MM HG
Vapor Density:SEE SUPP.
Spec Gravity:0.90
pH: 10.4
Solubility in Water:COMPLETE
Appearance and Odor:CLEAR, COLORLESS LIQUID W/AMMONIA-LIKE ODOR
Percent Volatiles by Volume:100%

Stability Indicator/Materials to Avoid:YES
STRONG OXIDIZERS, HYDROGEN PEROXIDE/NITROGEN TETROXIDE/FLUORINE/HALOGEN
FLUORIDES/BLEACH/FUMING NITRIC ACID SEE SUPP.
Stability Condition to Avoid:TEMPERATURES >535F, HEAT, SPARKS, & OPEN
FLAME
Hazardous Decomposition Products:AMMONIA, HYDROGEN, & CO

Waste Disposal Methods:HAZARDOUS LIQUID WASTE MUST BE DISPOSED OF IN
PERMITTED HAZARDOUS WASTE TREATMENT/STORAGE/DISPOSAL FACILITY BY
INCINERATION ACCORDING TO LOCAL/STATE/FEDERAL LAWS. MEETS CRITERIA
OF HAZARDOUS WASTE, EP A NUMBERS U133 & U098. FLAMMABLE
LIQUIDUN1992.

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This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.