Product ID:MIL-C-45168 PART B 4:1 BLEND
MSDS Date:11/17/1988
FSC:8010
NIIN:01-131-0612
Kit Part:Y
MSDS Number: BHNDS

NILES CHEMICAL PAINT COMPANY

225 FORT STREET
NILES, MI 49120
US

Emergency Phone: 219-236-5856 (24 HOURS)

Info Phone: 616-683-3377 (INFORMATION)

Preparer: MIKE LICHATOWICH

Cage: 02388

NILES CHEMICAL PAINT

307 NILES, MI 49120 US

Telephone: 616-683-3377/219-236-5856

Cage: 02388

HOMOPOLYMER OF HDI

CAS: 28182-81-2

RTECS: NQ9170000

Fraction By Weight: 75%

1,6-DIISOCYANATOHEXANE (HEXAMETHYLENE DIISOCYANATE)

CAS: 822-06-0

RTECS: MO1740000

ACGIH TLV: 0.005 PPM; 9192

EPA Report Quantity: 1 LB

DOT Report Quantity: 1 LB

XYLENES (O-,M-,P- ISOMERS) (SARA III)

CAS: 1330-20-7

RTECS: ZE2100000

Fraction By Weight: 12.5%

OSHA PEL 100 PPM/150 STEL

ACGIH TLV: 100 PPM/150STEL;9192

EPA Report Quantity: 1000 LBS

DOT Report Quantity: 1000 LBS

N-BUTYL ACETATE (SARA III)

CAS: 123-86-4

RTECS: AF7350000

Fraction By Weight: 12.5%

OSHA PEL 150 PPM/200 STEL

ACGIH TLV: 150 PPM/200STEL;9192

EPA Report Quantity: 5000 LBS

DOT Report Quantity: 5000 LBS

VOC. ORGANIC CMPD 2.21 LB/GAL

RTECS: 9999999VO

Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Health Hazards Acute and Chronic:INHALE:IRR MUCOUS MEMBRANES.RUNNY
NOSE,SORE THRT,COUGH,CHEST DISCOMFORT,SHORT BREATH,REDUCED LUNG
FUNC,HEADACHE,NAUSEA,NARCOSIS,FATIGUE,LOSS APPET,ISOCYANATE
SENSITIZATION.SKIN:IRR,SWELL,RASH,SCALIN G,BLISTER,DERM,SCALING,SKN
SENSITIZATIONEYE:IRR,TEAR,RED,SWELL.INGEST:IRR/CORROSIVE ACT IN
MOUTH,STOMACH,DIG TRACT.
Effects of Overexposure:INHALE:ASTHMA ATTACK,BRONCHITIS,BRONCHIAL
SPASM,PUL EDEMA,PNEUMONITIS,DRY THROATTIGHT
CHEST,HEADACHE,NAUSEA,NARCOSIS,FATIGUE,LOSS APPET,PERM BRAIN & NERV
SYSTEMDAMAGE/DEATH,LUNG DAMAGE,MEM LOSS,INTELL ECT LOSS,COORD
LOSS,SKIN:DRY,DEFATTED,CRACKED.SIMILAR EFFECTS TO THOSE OF INHALE
EXPOSURE.
Medical Cond Aggravated by Exposure:ASTHAMA,RESPIRATORY DISORDERS SUCH
AS BRONCHITIS, EMPHYSEMA,HYPERREACTIVITY,SKIN ALLERGY,ECZEMA.
TARGET ORGANS:RESPIRATORY SYS,CENTRAL NERVOUS SYS EYES,GI
TRACT,BLOOD,LIVER, KIDNEYS,SKIN.

First Aid:INHALE:MOVE AWAY FROM EXPOSURE.GIVE OXYGEN/CPR.GET MED
ATTN.TREAT SYMPTOMATICAL.SKIN:REMOVE CLOTH IMM.WASH
W/SOAP&WATER.WASH CLOTH.GET MED ATTN IF IRR PERSISTS.EYE:FLUSH
W/LUKEWARM WTR(LOW PRESS)15 MI N,LIFTING EYELIDS,GET MED
ATTN.INGEST:DONT INDUCE VOMITING. DONT GIVE ANYTHING BY MOUTH.GET
MED ATTN.ASTHAMTIC TYPE SYMPTOMS MAY DEVELOP & MAY BE IMMEDIATE
OR DELAYED UP TO SEVERAL HOURS.

Flash Point Method:PMCC
Flash Point:91F/33C
Lower Limits:1.0
Upper Limits:7.6
Extinguishing Media:FOAM, "ALCOHOL" FOAM, C02, DRY CHEMICAL
Fire Fighting Procedures:WEAR SCBA W/FULL PROTECTIVE CLOTHING.ISOLATE
FROM HEAT,ELEC EQUIP,SPARKS,& OPEN FLAME.CLOSED CONTAINERS CAN
EXPLODE/BURST WHEN EXPOSED TO EXTREME HEAT OR WATER.
Unusual Fire/Explosion Hazard:HDI VAPORS,HIGH TOXIC GAS GENRD BY
THERMAL DECOMP/COMB.SOLVENT VAPORS MAYBE >AIRSTAGNANT AIR MAY CAUSE
VAPORS TO BUILDUP & TRAVEL ON GROUND TO IGNITION SOURCES.

Spill Release Procedures:REMOVE ALL IGNITION SOURCES.DIKE/IMPOUND
SPILLED MATL & CONTRL FURTHER SPILLAGE IF FEASIBLE.COVER THE
SPILL W/SAWDUST,VERMICULITE,EARTH,OR ABSORBANTMATL.POUR DECONTAM
SOLUTION OVER SPILL & ALLOW TO REACT FOR 10MINS.COLL MATL OPEN
CONTNR COVER LOOSE
Neutralizing Agent:DETERGENT(2%)WATER(90-95%)CONCENT
AMMONIA(3-8%)/UNION CARB TERGITOL(20%)WTR(80%)

Handling and Storage Precautions:GROUND CONTAINERS DURING
STORAGE/TRANSFER OPERATN.IDEAL STORAGE TEMP IS 50-81F/10-27C.KEEP
AWAY FROMHEAT,SPARKS,& OPEN FLAME.DONOT RESEAL IF CONTAMIND
Other Precautions:STORE IN TIGHTLY CLOSED CONTAINERS TO PREVENT
MOISTURE CONTAMINATION.AT MAXIMUM STORAGE TEMP NOTED, MATL MAY
SLOWLY POLYMERIZE W/O HAZARD. AVOID CONTACT W/SKIN & EYES.IF
CONTAINER IS EXPOSED TO HIGH H EAT, IT CAN BE PRESS & POSS RUPTURE.

Respiratory Protection:SPRAY APPLICATIONS A PROPERLY FITTED AIR
PURIFYING RESPIRATOR WILL PROVIDE SUFFICIENT PROTECTION.IF SPRAYING
IS PERFORMED IN A CONFINED AREA W/LIMITED VENTL USEA POSITIVE PRESS
SUPPLIED AIR RESP MANDA TORY.ALSO AIR PURIFYING/FRESH AIR SUPPLD
Ventilation:EXHAUST VENTILATION SUFFICIENT TO KEEP AIRBORNE CONCENTR OF
SOLVENT,HDI,& POLYISOCYANATE BELOW THEIR RESPECTIVE TLV'S.
Protective Gloves:CHEMICAL RESISTANT GLOVES.
Eye Protection:SAFETY GLASSES/SPLASH GOGGLE/FACE SHIELD
Other Protective Equipment:SAFETY SHOWERS/EYEWASH STATIONS SHOULD BE
AVAILABLE W/NEEDEDCOVER AS MUCH OF THE SKIN AREA AS POSS
W/APPROPRIATE CLOTHS
Work Hygienic Practices:WASH HANDS THOROUGHLY BEFORE EATING AND BEFORE
USING REST- ROOMS. SMOKE ONLY IN SMOKING AREAS.
Supplemental Safety and Health
CONTACT LENSES SHOULD NOT BE WORN.IF SKIN CREAMS ARE USED, KEEP THE
AREA PROTECTED ONLY BY THE CREAM TO A MINIMUM. EVEN DURING NON
SPRAY OPERATIONS SUCH AS MIX-ING,BRUSH OR ROLLER APPLICATION
DEPENDIN G ON THE CONDITIONS IT IS POSSIBLE TO BEEXPOSED TO
AIRBORNE SOLVENT OR ISOCYANATE VAPORS.

Vapor Density:>AIR
Viscosity:MPAS@20C 183
Evaporation Rate & Reference:SLOWER THAN ETHER
Solubility in Water:INSOLUBLE/REACTS WTR
Appearance and Odor:CLEAR TO PALE YELLOW LIQUID/SOLVENT ODOR.
Percent Volatiles by Volume:30

Stability Indicator/Materials to Avoid:YES
WATER, AMINES, STRONG BASES, ALCOHOLS, METAL COMPOUNDS, AND SURFACE
ACTIVE MATERIALS.
Stability Condition to Avoid:MOISTURE,HIGH TEMPERATURES, SHOCK FROM
DROPPING.
Hazardous Decomposition Products:CARBON DIOXIDE/MONOXIDE,OXIDES OF
NITROGEN, TRACES OF HNC & HDI
Conditions to Avoid Polymerization:MAY OCCUR IF IN CONTACT WITH
MOISTURE OR OTHER MATERIALS WHICH REACT W/ISOCYANATES.MAY OCCUR
AT TEMP OVER 400 F(204C)

Waste Disposal Methods:DISPOSE W/FEDERAL,STATE,LOCAL REGULATIONS.
ICINER-ATION IS PREF.EMPTY CONTAINERS,HANDLE W/CARE,DUE TO PRODCT
RESIDUE/FLAM SOLVENT VAPOR.DECONTAMINATECONTAINERS PRIOR TO
DISPOSAL.DONT HEAT/CUT ON OR NEAR EMPTY CONTAINER W/ELEC TORCH OR
GAS TORCH.

Disclaimer (provided with this information by the compiling agencies):
This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.