Product ID:MIL C 46168D PART B 4:1 BLEND
MSDS Date:01/01/1987
FSC:8010
NIIN:01-141-2416
Kit Part:Y
MSDS Number: BHNFJ

NILES CHEMICAL PAINT COMPANY

225 FORT STREET
NILES, MI 49120
US

Emergency Phone: 219-236-5856 (24 HOURS)

Info Phone: 616-683-3377 (INFORMATION)

Preparer: MIKE LICHATOWICH

Cage: 02388

NILES CHEMICAL PAINT

307 NILES, MI 49120 US

Telephone: 616-683-3377/219-236-5856

Cage: 02388

HOMOPOLYMER OF HDI

CAS: 28182-81-2

RTECS: NQ9170000

Fraction By Weight: 75%

1,6-DIISOCYANATOHEXANE (HEXAMETHYLENE DIISOCYANATE)

CAS: 822-06-0

RTECS: MO1740000

ACGIH TLV: 0.005 PPM; 9192

EPA Report Quantity: 1 LB

DOT Report Quantity: 1 LB

XYLENES (O-,M-,P- ISOMERS) (SARA III)

CAS: 1330-20-7

RTECS: ZE2100000

Fraction By Weight: 12.5%

OSHA PEL 100 PPM/150 STEL

ACGIH TLV: 100 PPM/150STEL;9192

EPA Report Quantity: 1000 LBS

DOT Report Quantity: 1000 LBS

N-BUTYL ACETATE (SARA III)

CAS: 123-86-4

RTECS: AF7350000

Fraction By Weight: 12.5%

OSHA PEL 150 PPM/200 STEL

ACGIH TLV: 150 PPM/200STEL;9192

EPA Report Quantity: 5000 LBS

DOT Report Quantity: 5000 LBS

VOC. ORGANIC CMPD 2.21LB/GAL LESS WATER & NPRS*

RTECS: 9999999VO

Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Health Hazards Acute and Chronic:INHALE:IRR MUCOUS
MEMBRANES/NOSE,THROAT,LUNGS,CAUSING RUN NOSE,SORE THRT,COUGH, CHEST
DISCOMF,SHRT BREATH,REDUCED LUNG FUNC.CAN DEVELOPE ISOCYANATE
SENSITAZA- TION.SKIN:IRR,SKN SENSITIZATION,DEFAT.DE RMATITIS,SKN
RASH,RED,SWELL,RASH,SCALE,BLISTER.EYES:IRR,TEAR,RED,SWELLING.INGEST
:IRR,CORROSIVE ACT IN MOUTH,STOM,DIGEST
Effects of Overexposure:EXPOSURE OVER TLV,BRONCHITIS,BRONCHIAL
SPASM,PULM EDEMA.RED,ITCHY EYES.DRYNESS OF THRT,TGHT
CHEST,HEADACHE,NAUSEA,NARCOSIS,FATIGUE,LOSS APPET,ASTHMA ATTACH,
ONCE SNSITIZED CAN EXPER THESE SYP WHEN EXP TO DUST,COLD AIR,
IRRITANTS. CAN CSEPERMANENT LUNG DAMAGE,PERM BRAIN DAMAGE,NERVOUS
SYSTEM DAMAGE.
Medical Cond Aggravated by Exposure:ASTHMA,RESPIRATORY DISORDERS SUCH
AS BRONCHITIS, EMPHYSEMA, AND HYPERREACTIVITY: SKIN ALLERGIES
ANDECZEMA.

First Aid:INHALE:REMOVE FROM EXPOSURE.GIVE OXYGEN/CPR IF NEED.GET MED
ATTN.ASTHMATICE SYMPMAY DEVELOP IMMED/DELAY SEV HOURS.TREAT
SYMPTOMATIC.SKIN:REMVE CLOTH.WASH THORO W/SOAP&WTR.WSH CONTAM
CLOTH.GET MED ATTN IF IRR DEV.EYE:FLUSH LUKEWRM WTR 15 MINLIFT
EYELIDS.GET MED ATTN.INGEST:DONT VOMIT.GET MED ATT.THIS COMPOUND IS
KNOWN SKIN/PULMONARY SENSITIZER,TREAT SYMPTOMATIC.EYE:STAIN FOR
EVID CORNEAL INJURY.

Flash Point Method:PMCC
Flash Point:91 F/ 33 C
Lower Limits:1.0
Upper Limits:7.6
Extinguishing Media:FOAM, "ALCOHOL" FOAM, CO2, DRY CHEMICAL.
Fire Fighting Procedures:FULL EMERG EQUIP W/SELF-CONT BREATH
APPARATUS,FULL PROT CLOTH.HDI VAPOR,&HIGH TOXIC GAS MAY GENERATE
BY THERMAL DECOMP/COMBUST.KEEP FROM HEAT,ELECT EQUIP,SPRK
Unusual Fire/Explosion Hazard:CLSD CONT MAY EXP WHEN EXPOSE EXTRM
HEAT,BURST WHEN CONTAMINATED W/WTR CREATING C02.SOLVENT VAPOR MAY
BE >AIR.STAG AIR MAY CAUSE VAPOR TO TRVL IGN SOURCE&BACK.

Spill Release Procedures:EVACUATE.REMVE SRCE IGN,VENT AREA.DIKE/IMPOUND
SPILLED MAT.NOTIFY AUTHR.CVR SPILL(SAWDUST,ETC) POUR DECONTAM
SOLUT OVR SPILL AREA LET REACT 10 MIN.COLL MAT OPEN CONT TO SAFE
PLACE.WASH W/DE- CONTAMINATION SOLUTIONS.RESP PROTECTIONRECCOMD.

Handling and Storage Precautions:TEMP:32 F(0 C)MIN /122F(50 C)
MAX.SHELF LIFE: 12 MONTHS @ 77 F (25 C).IF EXP TO HGH HEAT,CAN
PRESS & POSS RUPTURE EXPLOSIVELY.HDI REACTS SLOWLY W/WTR
Other Precautions:GAS CAN CAUSE SEALED CONT TO EXP & RUPT.AVOID
MOISTURE,HIGH TEMPS,SHOCK FROM DROPPING,OPEN FLAME.GRND CONT
DURING STORAGE/TRNSF.STORE TIGHTLY CLSD CONT.DONT RESEAL IF
CONTAMINATION.IDEAL STORE RANG E, 50-81F (10-27 C).EMPLOYEE
EDUCATION.

Respiratory Protection:EXHAUST VENT.IF AIRBORNE CONCEN UNKWN,EXCD
0.2PPM,OR OPER PERF CONFINED AREA, SUPPLIED AIR RESP MUST BE
WORN.POST PRESS SUP AIR RESP MANDATORY IF AIRBORNE ISOCYANATE
CONCTR NK,SPRAY PERF IN CONFINED SPACE,LMTD VENT.
Ventilation:EXHAUST VENTILATION SUFF TO KEEP THE AIRBORNEE CONCENT. OF
THE SOLVENT.EXHAUST AIR MAY NEED TO BE CLEANED BY SCRUBBERS.
Protective Gloves:CHEMICAL RESISTANT GLOVES.
Eye Protection:SAFETY GLASSES,SPLASH GOGGLES,FACE SHILD
Other Protective Equipment:SKIN CREAMS, PROTECTIVE CLOTHING.COVER AS
MUCH EXP SKIN AS POSS.SAFETY SHOWER&EYEWASH STATION SHOULD BE
USED.
Work Hygienic Practices:WSH HANDS THORO BEFORE EATING,USING
RESTROOMS.SMOKING IN SMOKING AREAS ONLY.
Supplemental Safety and Health
PHYSICIAN:IF CORNEA IS BURNED,INSTILL ANTIBOTIC/STEROID
PREP.FREQ.VAPORS COULD PROD REVERSIBLE CORNEAL EPITHELIAL
EDEMA.INGEST:TREAT SYMPTOMATICALLY.THERE IS NO SPECIFIC
ANTIDOTE.INDUCE VOMIT IS CON TRAINDICTED BECAUSE OF IRR
NATURE.TARGETAREAS:RESP SYS,CENT NERV SYS,EYE,GI
TRACT,BLOOD,LIVER,KIDNEYS,SKIN.

Vapor Density:>AIR
Evaporation Rate & Reference:SLOWER THAN ETHER
Solubility in Water:INSOLUBLE
Appearance and Odor:CLEAR TO PALE YELLOW LIQUID/SOLVENT ODOR.
Percent Volatiles by Volume:CA 30

Stability Indicator/Materials to Avoid:YES
WATER,AMINES,STRONG BASES,ALCOHOLS,METAL COMPOUNDS,SURFACE ACTIVE
MATERIALS.
Stability Condition to Avoid:THIS MATERIAL HAS BEEN FOUND TO BE STABLE
UNDER REASONABLE CONDITONS OF STORAGE AND USE.
Hazardous Decomposition Products:BY HIGH HEAT AND FIRE:CARBON
DIOXIDE/MONOXIDE,OXIDES OF NITROGEN,TRACES OF HNC AND HDI.
Conditions to Avoid Polymerization:MAY OCCUR IF IN CONTACT WITH
MOISTURE OR OTHER MATERIALS WHICH REACT W/ISOCYANATES.MAY OCCUR
AT TEMP OVER 400F(204C).

Waste Disposal Methods:IN ACCORD W/FED,STATE,LOCAL ENV CONTROL REGS.IN-
CINERATION IS PREF.HANDLE EMPTY CONT W/CARE.DECON-TAMINATE CONT
PRIOR TO DISPOSE.DONT HEAT OR CUT ONNEAR EMPTY CONTAINER WITH
ELECTRICAL OR GAS TORCH.

Disclaimer (provided with this information by the compiling agencies):
This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.