Product ID:MIL-C-46168 PART B 4:1 BLEND
MSDS Date:11/17/1988
FSC:8010
NIIN:01-144-9873
Kit Part:Y
MSDS Number: BHNFR

NILES CHEMICAL PAINT COMPANY

225 FORT STREET
NILES, MI 49120
US

Emergency Phone: 219-236-5856 (24 HOURS)

Info Phone: 616-683-3377 (INFORMATION)

Preparer: MIKE LICHATOWICH

Cage: 02388

NILES CHEMICAL PAINT

307 NILES, MI 49120 US

Telephone: 616-683-3377/219-236-5856

Cage: 02388

HOMOPOLYMER OF HDI

CAS: 28182-81-2

RTECS: NQ9170000

Fraction By Weight: 75%

1,6-DIISOCYANATOHEXANE (HEXAMETHYLENE DIISOCYANATE)

CAS: 822-06-0

RTECS: MO1740000

ACGIH TLV: 0.005 PPM; 9192

EPA Report Quantity: 1 LB

DOT Report Quantity: 1 LB

XYLENES (O-,M-,P- ISOMERS) (SARA III)

CAS: 1330-20-7

RTECS: ZE2100000

Fraction By Weight: 12.5%

OSHA PEL 100 PPM/150 STEL

ACGIH TLV: 100 PPM/150STEL;9192

EPA Report Quantity: 1000 LBS

DOT Report Quantity: 1000 LBS

N-BUTYL ACETATE (SARA III)

CAS: 123-86-4

RTECS: AF7350000

Fraction By Weight: 12.5%

OSHA PEL 150 PPM/200 STEL

ACGIH TLV: 150 PPM/200STEL;9192

EPA Report Quantity: 5000 LBS

DOT Report Quantity: 5000 LBS

VOC. ORGANIC CMPD 2.21 LB/GAL LESS WATER & NPRS* (NK) G/L

RTECS: 9999999VO

Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Health Hazards Acute and Chronic:INHALE:IRR MUCOUS MEMBRANES CAUSE
RUNNY NOSE,SORE THRT,COUGH,CHEST DISCOMFORT, SHRT BREATH,REDUCED
LUNG FUNC,ASTHMA ATTACK,BRONC,BRONC SPASM,PULMONARY EDEMA,
ISOCYANATE SENSI,LUNG DAM,NEUROTOXI EFFE
CTS.SKIN:IRR,RED,SWELL,RASH,SCALE,BLIST,SKIN
SENSI,DRY,DEFAT,CRACK,SAME AS
INHALE.EYES:IRR,TEAR,RED,SWELL.INGEST:IRRIT.
Effects of Overexposure:INGEST:IRR&POSS CORROSIVE,MOUTH,STOMACH,GI
TRACT.INHALE:CHEST TIGHT,WHEEZE,COUGHSHRT BREATH,ASTHMA,LUNG
SENSITIVITY,PERM BRAIN/NERVOUS DAMAGE.SKIN:RED,SWELL
RASH,SCALE,BLISTER,SKIN SENSITIZATION. C HRONIC SKIN EXPOS CAN
CAUSE SYMPTOMS TOTHOSE SAME AS INHALE. EYES: STINGING, FEELING OF
FINE DUST IN EYES.
Medical Cond Aggravated by Exposure:TARGET ORGANS:RESP SYSTEM,CENTRAL
NERVOUS SYST,EYEGI TRACT,BLOOD,LIVER,KIDNEYS,SKIN.
ASTHMA,BRONCHITIS,EMPHYSEMA,HYPERREACTIVITY,SKIN ALLERGIES,AND
ECZEMA.

First Aid:INHALE:MOVE FROM EXPOSE.GIVE OXYGEN/CPR.GET MED
ATTN.ASTHMATIC SYMP MAY BE IMMEDOR DELAYED.SKIN:REMOVE
CLOTHING.WASH AREA W/SOAP&WATER. WASH CLOTH. GET MED ATTNIF IRR
DEV. EYE: FLUSH W/LUKEWARM, WATER FOR 15 MIN. LIFTING LIDS. GET
MED ATTN.INGEST: DO NOT INDUCE VOMITING. DO NOT GIVE ANYTHING BY
MOUTH TO UNCONSCIOUS PERSON. CONSULT PHYSICIAN.

Flash Point Method:PMCC
Flash Point:91 F/ 33 C
Lower Limits:1.0
Upper Limits:7.6
Extinguishing Media:FOAM, "ALCOHOL" FOAM, CO2, DRY CHEMICAL
Fire Fighting Procedures:FULL EMERG'Y EQUIP W/SELF-CONT BREATH
APPARATUS. FULL PROT CLOTH. KEEP FROM HEATELECT EQUIP,SPARKS,OPEN
FLAME.CLSD CONT MAY EXPLODE WHEN EXPO'D TO EXTREME HEAT,
Unusual Fire/Explosion Hazard:CLSD CONT MAY BURST IF CONTAMIN'D
W/WTR.VAPORS >AIR,TRVL TO IGN SOURCE WHICH MAYRESULT IN
FLASHBACK.HDI VAPORS MAY BE GENERATED BY THERMAL DECOMP/COMBUSTION.

Spill Release Procedures:EVACUATE.REMOVE SRCE IGN,VENT.DIKE/IMPOUND
MAT. NOTIFY AUTHOR IF NEC.COVER W/SAWDUST,VERMICULITE, ETC.POUR
DECONTAM SOL OVER AREA LET REACT 10 MIN. COLLECT MATERIAL, COVER
LOOSELY, LET STAND FOR 24 TO 48 HOURS.WASH W/DECONTAM
SOLUTIONS.
Neutralizing Agent:CONCENTR'D
AMM(3-8%),DETERGENT(2%)WTR(90-95%).TERGITOL(20%)WTR(80%)AMM(3%)DET(
2)

Handling and Storage Precautions:STORE TEMPS
32F(0C)MIN/122F(50C)MAX.SELF LIFE:12 MONTHS @77F(25C).
Other Precautions:IF CONTAINER IS EXPOSED TO HIGH HEAT,IT CAN BE
PRESSURIZED AND POSSIBLY RUPTURE EXPLOSIVELY. HDI REACTS SLOWLY
WITH WATER TO FORM C02 GAS.THIS GAS CAN CAUSE SEALED CONTAINERS
TO EXPAND & POSSIBLY R UPTURE EXPLOSIVELY.

Respiratory Protection:FRESH AIR RESPIRATOR FOR ISOCYANATE ENVIR MAY BE
NEEDED.IF AIRBORNE ISOCYANATE MONOMER CONC ARE BELOW
0.2PPM/POLYISOCYANATE CONC BELOW 10MG/M3 WEAR AIR PURIFY RESP.WHEN
NOT KNOWN/SPRY IN CONFINED SPA CE,MANDATORY THAT RESPIRATOR BE
WORN.
Ventilation:EXHAUST VENT SUFF TO KEEP AIRBORNE CONC OF
SOLV,HDI,POLYISO-CYANATE BELOW TLV'S.MAY NEED TO BE CLN'D BY
SCRUBBERS/FILTER
Protective Gloves:CHEMICAL RESISTANT GLOVES.
Eye Protection:SAFETY GLASSES,SPLASH GOGGLES,FACESHIELD
Other Protective Equipment:COVER AS MUCH OF THE EXPOSED SKIN AS
POSSIBLE.SAFETY SHOWERS& EYEWASH STATION SHOULD BE AVAIL. SHOULD BE
EDUC/TRAINED.
Work Hygienic Practices:WASH HANDS THOROUGHLY BEFORE EATING AND BEFORE
USING REST- ROOMS. SMOKE ONLY IN SMOKING AREAS.
Supplemental Safety and Health
SYMP CAN BE DELAYED UP TO SEVERAL HRS.CONTACT LENSES SHOULD NOT BE
WORN.KEEP FROM HEAT,SPRK,OPN FLAME.GRND CONT DURING
STORAGE&TRANS OPER.STORE IN TIGHTLY CLSD CONT TO PREVENT MOIST
CONTAM.DONT R ESEAL IF CONTAM SUSP'D.AVOID CONTACTWITH
SKIN,EYES.EMPLOYEE EDUC&TRAIN IN SAFE USE/HANDLING OF THIS PRODUCT
REQ'D.

Vapor Density:>AIR
Viscosity:MPAS@20C 183
Evaporation Rate & Reference:SLOWER THAN ETHER
Solubility in Water:INSOLUBLE/REACT WTR
Appearance and Odor:CLEAR TO PALE YELLOW LIQUID/SOLVENT ODOR
Percent Volatiles by Volume:CA 30

Stability Indicator/Materials to Avoid:YES
WATER,AMINES,STRONG BASES,ALCOHOLS,METAL COMPOUNDS AND SUR- FACE ACTIVE
MATERIALS.
Stability Condition to Avoid:THIS MATERIAL HAS BEEN FOUND TO BE STABLE
UNDER REASONABLE CONDITONS OF STORAGE AND USE.
Hazardous Decomposition Products:HIGH HEAT FIRE:CARBON DIOXIDE,CARBON
MONOXIDE,OXIDES OF NIT-ROGEN, TRACES OF HNC AND HDI.
Conditions to Avoid Polymerization:MAY OCCUR IF IN CONTACT WITH
MOISTURE OR OTHER MAT WHICH REACT W/ISOCYANATES. MAY OCCUR AT
TEMPS OVER 400F (204C).

Waste Disposal Methods:HANDLE EMPTY CONT W/CARE.DECONT CON PRIOR TO
DISP.DISPOSE OF IN ACCORD W/FEDERAL,STATE,LOCAL ENVIR CONTROL
REGS.DO NOT HEAT,CUT,ON OR NEAR EMPTY CONTAINERS WITH ELECT/GAS
TORCH.

Disclaimer (provided with this information by the compiling agencies):
This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.