Product ID:MIL-C-46168D PART B 4:1 BLEND
MSDS Date:11/17/1988
FSC:8010
NIIN:01-260-0911
Kit Part:Y
MSDS Number: BHNGW

NILES CHEMICAL PAINT COMPANY

225 FORT STREET
NILES, MI 49120
US

Emergency Phone: 219-236-5856 (24 HOURS)

Info Phone: 616-683-3377 (INFORMATION)

Preparer: MIKE LICHATOWICH

Cage: 02388

NILES CHEMICAL PAINT

307 NILES, MI 49120 US

Telephone: 616-683-3377/219-236-5856

Cage: 02388

HOMOPOLYMER OF HDI

CAS: 28182-81-2

RTECS: NQ9170000

Fraction By Weight: 75%

1,6-DIISOCYANATOHEXANE (HEXAMETHYLENE DIISOCYANATE)

CAS: 822-06-0

RTECS: MO1740000

ACGIH TLV: 0.005 PPM; 9192

EPA Report Quantity: 1 LB

DOT Report Quantity: 1 LB

XYLENES (O-,M-,P- ISOMERS) (SARA III)

CAS: 1330-20-7

RTECS: ZE2100000

Fraction By Weight: 12.5%

OSHA PEL 100 PPM/150 STEL

ACGIH TLV: 100 PPM/150STEL;9192

EPA Report Quantity: 1000 LBS

DOT Report Quantity: 1000 LBS

N-BUTYL ACETATE (SARA III)

CAS: 123-86-4

RTECS: AF7350000

Fraction By Weight: 12.5%

OSHA PEL 150 PPM/200 STEL

ACGIH TLV: 150 PPM/200STEL;9192

EPA Report Quantity: 5000 LBS

DOT Report Quantity: 5000 LBS

Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Health Hazards Acute and Chronic:IRRITATE MUCOUS MEMBRANES, CAUSING
RUNNY NOSE, SORE THROAT, COUGHING, CHEST
DIS-COMFORT,REDDENING,SWELLING,RASH,SCALING,OR BLISTERING. CHRONIC
SKIN EXPOSURE MAY CAUSE CHEST TIGHTNESS, WHEEZING, COU GH, AND
SHORTNESS OF BREATH.
Effects of Overexposure:SORE THROAT, COUGHING, CHEST DISCOMFORT.
Medical Cond Aggravated by Exposure:RESPIRATIRY DISORDERS SUCH AS
BRONCHITIS, EMPYSEMAAND HYPERACTIVITY. SKIN ALLERGIES AND ECZEMA.

First Aid:INHAL: MOVE TO AREA FREE OF EXPOSURE, IF BREATHING HAS
STOPPED GIVE CPR.SKIN:RE-MOVED CONTAMINATED CLOTHING IMMEDIATELY.
WASH AFFECTED AREA W/SOAP AND WATRE.EYEFLUSH WITH WATER FOR ABOUT
15 MIN LIFTIN G EYELIDS OCCASIONALY.INGEST: DO NOTINDUCE VOMITIMG
CALL A DR IN ALL THE ABOVE CASES.

Flash Point Method:PMCC
Flash Point:91F/33C
Lower Limits:1.0
Upper Limits:7.6
Extinguishing Media:FOAM, "ALCOHOL" FOAM, CO2, DRY CHEMICAL
Fire Fighting Procedures:SCBA SHOULD BE WORN BY FIRE FIGHTER ALONG WITH
PROTECTIVE CLOTHING. HIGHLY TOXICGASES MAY BE GENERATED BY
DECOMPOSITION OR COMBUSTION.
Unusual Fire/Explosion Hazard:CLOSED CONTAINERS MAY EXPLODE WHEN
EXPOSED TO EXTREME HEAT. SOLVENT VAPORS MAY BE HEAVIER THAN AIR
AND MAY TRAVEL ALONG THE GROUND TO AN IGNITION SOURCE.

Spill Release Procedures:EVACUATE.REMOVE ALL SOURCES OF IGNITION.DIKE
OR IMPOUND SPILLED MATERIAL TO CONTROL FURTHER SPILLSWASH DOWN
AREA WITH DECONTAMINATION SOLUTION.

Handling and Storage Precautions:STORE AT 32F/0C MIN 122F/50C MAX.
SHELF LIFE: 12 MONTHS @ 77F/25C
Other Precautions:IF CONTAINER IS EXPOSED TO HIGH HEAT, IT CAN BE
PRESSURIZED AND POSSIBLY RUP- TURE EXPLOSIVELY.HDI REACTS SLOWLY
WITH WATER TO FORM C02 GASES.

Respiratory Protection:POSITIVE PRESSURE RESPIRATOR MANDATORY IN
CONFINED AREA. AIR PURIFYING/FRESH AIR MAY BE NECESSARY.CONSIDER
TYPE OF APPLICATION AND ENVIRONMENT CONCENTRATIONS
Ventilation:EXHAUST VENTILAION SUFFICIENT.
Protective Gloves:CHEMICAL RESISTANT GLOVES
Eye Protection:SAFETY GLASSES/SPLSH GOGS/FACESHIELD
Other Protective Equipment:COVER AS MUCH OF THE EXPOSED SKIN AS
POSSIBLE WITH APPROPRIATE CLOTHING, CREAM.SHOWERS/EYEWASH
STATIONS.
Work Hygienic Practices:WASH HANDS BEFORE EATING AND BEFORE USING
RESTROOMS.SMOKE ONLY IN SMOKING AREAS.
Supplemental Safety and Health
CONTACT LENSES SHOULD NOT BE WORN.
CURED MATERIAL IS DIFFICULT TO REMOVE.

HCC:F3
Boiling Pt:B.P. Text:NE
Decomp Temp:Decomp Text:NE
Vapor Density:>AIR
Viscosity:MPAS@20C 183
Evaporation Rate & Reference:SLOWER THEN ETHER
Solubility in Water:INSOLUBLE/REACT W/WA
Appearance and Odor:CLEAR TO PALE YELLOW LIQUID/SOLVENT ORDOR .
Percent Volatiles by Volume:CA 30

Stability Indicator/Materials to Avoid:YES
WATER, AMINES, STRONG BASES, ALCOHOLS, METAL COMPOUNDS AND SURFACE
ACTIVE MATERIAL.
Stability Condition to Avoid:MOISTURE, HIGH TEMPERATURES, SHOCK FROM
DROPPING.
Hazardous Decomposition Products:BY HIGH HEAT AND FIRE:CARBON DIOXIDE,
CARBON MONOXIDE,OXIDESOF NITROGEN, TRACES OF HNC AND HDI.
Conditions to Avoid Polymerization:IT MAY OCCUR IF IN CONTACT WITH
MOISTURE OR OTHER MATERIALS WHICH REACT WITH ISOCYANATES, MAY OCCUR
AT OVER 400F(204C).

Waste Disposal Methods:MUST BE DISPOSED OF IN ACCORDANCE WITH FEDERAL,
STATE AND LOCAL REGS.INCINERATION IS PREFERRED. EMPTY CONTAINERS
MUST BE HANDLED WITH CARE DUE TO PROUCT RESIDUE AND FLAMMABLE
SOLVENT VAPORS.

Disclaimer (provided with this information by the compiling agencies):
This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.