Product ID:MIL-C-46168D PART B 4:1 BLEND
MSDS Date:11/17/1988
FSC:8010
NIIN:01-260-0914
Kit Part:Y
MSDS Number: BHNGZ

NILES CHEMICAL PAINT COMPANY

225 FORT STREET
NILES, MI 49120
US

Emergency Phone: 219-236-5856 (24 HOURS)

Info Phone: 616-683-3377 (INFORMATION)

Preparer: MIKE LICHATOWICH

Cage: 02388

NILES CHEMICAL PAINT

307 NILES, MI 49120 US

Telephone: 616-683-3377/219-236-5856

Cage: 02388

HOMOPOLYMER OF HDI

CAS: 28182-81-2

RTECS: NQ9170000

Fraction By Weight: 75%

1,6-DIISOCYANATOHEXANE (HEXAMETHYLENE DIISOCYANATE)

CAS: 822-06-0

RTECS: MO1740000

ACGIH TLV: 0.005 PPM; 9192

EPA Report Quantity: 1 LB

DOT Report Quantity: 1 LB

XYLENES (O-,M-,P- ISOMERS) (SARA III)

CAS: 1330-20-7

RTECS: ZE2100000

Fraction By Weight: 12.5%

OSHA PEL 100 PPM/150 STEL

ACGIH TLV: 100 PPM/150STEL;9192

EPA Report Quantity: 1000 LBS

DOT Report Quantity: 1000 LBS

N-BUTYL ACETATE (SARA III)

CAS: 123-86-4

RTECS: AF7350000

Fraction By Weight: 12.5%

OSHA PEL 150 PPM/200 STEL

ACGIH TLV: 150 PPM/200STEL;9192

EPA Report Quantity: 5000 LBS

DOT Report Quantity: 5000 LBS

VOC. ORGANIC CMPD 2.21 LB/GAL LESS WATER & NPRS* 480 G/L

RTECS: 9999999VO

Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Health Hazards Acute and Chronic:ACUTE:RUNNY NOSE, SORE THROAT,
COUGHING, CHEST DISCOMFORT, SHORTNESS OF BREATH, AND REDUCED LUNG
FUNCTION.DELIBERATE CONCENTRATION AND INHALATION OF SOLVENT VAPORS
CAN RESULT IN PERMANENT BRAIN AND NE RVOUS SYSTEM DAMAGE OR
DEATH.CHRONIC: EXPOSURE TO ISOCYANATES CAN CAUSE
REDDENING,SWELLING,RASH,SCALING,OR BLISTERING.
Effects of Overexposure:REDDENING, SWELLING, RASH, SCALING, OR
BLISTERING. VOMITING MAY CAUSE ASPIRATIONOF THE LUNG, RESULTING IN
CHEMICAL PNEUMONITIS.TARGET ORGANS:RESPIRATORY SYSTEM,CENTRAL
NERVOUS SYSTEM,EYES, GASTROINTES TINAL
TRACT,BLOOD,LIVER,KIDNEYS,SKIN.
Medical Cond Aggravated by Exposure:ASTHMA, RESPIRATORY DISORDERS SUCH
AS BRONCHITIS, EMPHYSEMA, AND HYPERREACTIVITY: SKIN ALLERGIES
ANDECZEMA.

First Aid:MOVE TO AN AREA FREE OF FUTHER EXPOSURE. GIVE CPR IF
NEEDED.SKIN CONTACT:REMOVECONTAMINATED CLOTHING IMMEDIATELY. WASH
AFFECTED AREA WITH SOAP AND WATER.EYE CONTACT:FLUSH WITH CLEAN
LUKE WARM WATER FOR AT LEAST 15 MINUTES, OCCASIONALLYLIFTING
EYELIDS.INGESTION:DO NOT INDUCE VOMITING.DO NOT GIVE ANYTHING BY
MOUTH TO AN UNCONCIOUS PERSON. CONSULT PHYSICIAN IN ALL THE ABOVE
CASES.

Flash Point Method:PMCC
Flash Point:91F/33C
Lower Limits:1.0
Upper Limits:7.6
Extinguishing Media:FOAM, "ALCOHOL" FOAM, CO2, DRY CHEMICAL
Fire Fighting Procedures:SCBA AND FULL PROTECTIVE CLOTHING SHOULD BE
WORN BY FIRE FIGHTERS. HIGHLY TOXIC GASES MAY BE GENERATED BY
THERMAL DECOMBUSTION OR COMBUSTION. ISOLATE FROM HEAT.
Unusual Fire/Explosion Hazard:CLOSED CONTAINERS MAY EXPLODE WHEN
EXPOSED TO EXTREME HEAT OR CONTAMINATED W/WTRCREATING CO2. VAPORS
CAN TRAVEL ALONG THE GROUND TO THE NEAREST IGNITION SOURCE.

Spill Release Procedures:ELIMINATE ALL IGNITION SOURCES. ABSORB WITH AN
INERT MATERIAL. MINIMIZE THE BREATHING OF VAPORS AND SKIN
CONTACT. FOR LARGER SPILLS, DIKE OR IMPOUND SEWERS AND OTHER
WATERCOURSES. ADVISE THE THE PROPER AUTHORITIES.
Neutralizing Agent:TERGITOL TMN-10(20%)WATER(80%),CONCT
AMMONIA(3-8%),DETERGENT(2%),WATER(90-95%)

Handling and Storage Precautions:AVOID STORAGE IN HIGH TEMPERATURE
AREAS OR NEAR FIRE OR OPEN FLAME. KEEP CONTAINERS CLOSED WHEN
NOT IN USE. AVOID ROUGH HANDLING.
Other Precautions:CONTAINERS OF THIS MATERIAL MAY BE HAZARDOUS WHEN
EMPTY. DO NOT WELD OR FLAME CUT ON EMPTY DRUMS.STORAGE
TEMP:32F(0C)MIN/122F(50C)MAX.AVERAGE SHELF LIFE:12 MONTHS
@77F(25C).

Respiratory Protection:OBSERVE OSHA REGULATIONS FOR RESPIRATOR USE (29
CFR 1910.134).USE OF POSITIVE PRESSURE RESPIRATOR IS MANDATORY IN
CONFINED AREAS OR IF LEVELS ARE NOT KNOWN.
Ventilation:EXHAUST VENTILATION SUFFICIENT TO KEEP THE AIRBORNE CONCEN-
TRATION OF THE SOLVENT BELOW THEIR RESPECTIVE TLV UTILIZED.
Protective Gloves:CHEMICAL RESISTANT GLOVES
Eye Protection:SAFTETY GLASSES, SPLASH GOGGLES
Other Protective Equipment:ANYTHING TO PREVENT SKIN CONTACT.SAFETY
SHOWERS AND EYEWASH STATIONS,EMPLOYEE EDUCATION ON SAFE USE OF
PRODUCT.
Work Hygienic Practices:WASH HANDS THOROUGHLY BEFORE EATING AND BEFORE
USING THE RESTROOMS.SMOKE ONLY IN SMOKING AREAS.
Supplemental Safety and Health
CHRONIC SKIN EXPOSURE MAY CAUSE SIMILAR EFFECTS TO THOSE IDENTIFIED
UNDER CHRONIC INHALATION EFFECTS.
IF CONTAINER IS EXPOSED TO HIGH HEAT,IT
CAN BE PRESSURIZED AND POSS RUPTUREEXPLOSIVELY.

Vapor Density:>AIR
Viscosity:MPAS@20C 183
Evaporation Rate & Reference:SLOWER THEN ETHER
Solubility in Water:INSOLUBLE/REACTS WTR
Appearance and Odor:CLEAR TO PALE YELLOW LIQUID/SOLVENT ODOR
Percent Volatiles by Volume:CA 30

Stability Indicator/Materials to Avoid:YES
WATER, AMINES, STRONG BASES, ALCOHOLS, METAL COMPOUNDS, AND SURFACE
ACTIVE MATERIALS.
Stability Condition to Avoid:MOISTURE, HIGH TEMPERATURES, SHOCK FROM
DROPPING
Hazardous Decomposition Products:BY HEAT AND BY FIRE:CARBON DIOXIDE,
CARBON MONOXIDE, OXIDES OF NITROGEN.TRACES OF HNC AND HDI.
Conditions to Avoid Polymerization:MAY OCCUR IF CONTACT WITH
MOISTURE/OTHER MATERIAL THAT WILL REACT WITH ISOCYANATES.MAY OCCUR
AT TEMP OVER 400F(204C).

Waste Disposal Methods:DISPOSE OF IN ACCORDANCE WITH APPLICABLE LOCAL,
STATE AND FEDERAL REGULATIONS. INCINERATION IS PREFERRED.EMPTY
CONTAINER MUST BE HANDLED WITH CARE DUE TO PRODUCT
RESIDUE/FLAMMABLE SOLVENT VAPOR.

Disclaimer (provided with this information by the compiling agencies):
This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.