Product ID:F THINNER
MSDS Date:04/19/1990
FSC:8010
NIIN:00N011923
MSDS Number: BJKLP

MARKEM CORPORATION

150 CONGRESS STREET
KEENE, NH 03431
US

Emergency Phone: 603-352-1130

Info Phone: 603-352-1130

Cage: 38360

MARKEM CORPORATION

KEENE, NH 03431 US

Telephone: 603-352-1130

Cage: 38360

METHYL ISOBUTYL KETONE (SARA III)

CAS: 108-10-1

RTECS: SA9275000

Fraction By Weight: 0-2%

OSHA PEL 100 PPM/75 STEL

ACGIH TLV: 50 PPM/75 STEL; 9293

EPA Report Quantity: 5000 LBS

DOT Report Quantity: 5000 LBS

ETHYL ACETATE (SARA III)

CAS: 141-78-6

RTECS: AH5425000

Fraction By Weight: 0-2%

OSHA PEL 400 PPM

ACGIH TLV: 400 PPM; 9192

EPA Report Quantity: 5000 LBS

DOT Report Quantity: 5000 LBS

METHYL ALCOHOL (METHANOL) (SARA III)

CAS: 67-56-1

RTECS: PC1400000

Fraction By Weight: 0-5%

OSHA PEL S,200PPM/250STEL

ACGIH TLV: S,200PPM/250STEL; 93

EPA Report Quantity: 5000 LBS

DOT Report Quantity: 5000 LBS

ETHYL ALCOHOL (ETHANOL)

CAS: 64-17-5

RTECS: KQ6300000

Fraction By Weight: >90%

OSHA PEL 1000 PPM

ACGIH TLV: 1000 PPM; 9192

BALANCE OF FORMULATION IS CONSIDERED TO BE NONHAZARDOUS

OSHA PEL N/K

ACGIH TLV: N/K

LD50 LC50 Mixture:N/K
Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:NO IARC:NO OSHA:NO
Health Hazards Acute and Chronic:DERMAT POSS.REPEATED ETHANOL INGEST BY
PREGNANT MOTHERS ADVERSELY AFFECTS FETAL CENTRAL NERVOUS SYSTEM
(FETAL ALCOHOL SYNDROME) INCLUDING MENTAL & PHYSICAL
RETARDATION,LEARNING DISTURBANCES,MOTOR & LA NGUAGE
DEFICIENCIES,BEHAVIORAL DISORDERS,AND SMALL SIZE HEAD.INGEST MAY
CAUSE BLINDNESS,DEATH.TARGET ORGANS:CNS,SKIN.
Explanation of Carcinogenicity:NONE
Effects of
Overexposure:EYES:IRRIT,DISCOMFORT,TEARING,REDNESS,STINGING.SKIN:IR
RIT,DEFAT,DERMAT.INGEST:IRRIT,NAUSEA,VOMIT,DIARR,INTOXICATION,BLIND
NESS,DEATH.INHAL:NASAL & RESP IRRIT,BURNING SENSATION IN NOSE &
THROAT,DIZZ,WEA K,FATIGUE,NAUSEA,HEADACHE,VOMIT,POSS UNCON.CONC
>1000 PPM FOR >1 HR:DROW,LASS,APPETITE LOSS,INABILITY TO
CONCENTRATE.
Medical Cond Aggravated by Exposure:REPEATED ETHANOL EXPOSURE MAY
EXACERBATE PRIOR LIVER INJURIES.

First Aid:EYES:FLUSH W/ WATER FOR AT LEAST 15 MIN.CALL MD
IMMED.SKIN:WASH W/ SOAP & WATER.GET MED ATTN.INGEST:IF
CONSCIOUS,GIVE 2 GLASSES OF WATER & INDUCE VOMIT.NEVER GIVE
ANYTHING BY MOUTH TO UNCON PERSON.GET MED ATTN IMMED.MD
NOTE:EMESIS INDICATED UNLESS PATIENT IS/MAY BECOME
OBTUNDED,COMATOSE,CONVULSING.MOST EFFECTIVE W/IN 30 MIN.DOSE IPECAC
SYRUP,ADULT:30 ML.INHAL:REMOVE TO FRESH AIR.IF BRTHG (SEE SUP)

Flash Point:55F,13C
Lower Limits:3.3%
Upper Limits:19%
Extinguishing Media:CARBON DIOXIDE,ALCOHOL FOAM,DRY CHEMICAL,WATER
SPRAY,HALON.
Fire Fighting Procedures:USE NIOSH/MSHA APPROVED SCBA & FULL PROTECTIVE
EQUIPMENT .
Unusual Fire/Explosion Hazard:VAPORS ARE HEAVIER THAN AIR & MAY TRAVEL
ALONG GROUND & BE IGNITED AT DISTANT LOCATIONS & FLASH BACK.HAZ
DECOMP PROD:CO,CO*2.AUTOIGNIT TEMP:363C,685F.

Spill Release Procedures:ELIMINATE ALL SOURCES OF IGNITION.ABSORB
SPILLED MATERIAL WITH VERMICULITE OR FLOOR ABSORBENT.DISPOSE OF
CONTAMINATED MATERIALS PROPERLY.USE SAFETY GOGGLES OR GLASSES WITH
SIDE SHIELDS,APPROPRIATE MAS K AND GLOVES.
Neutralizing Agent:N/K

Handling and Storage Precautions:STORE IN TIGHTLY CLOSED CONTAINERS IN
A COOL,DRY,WELL-VENTILATED,FIRE-RESISTANT AREA AWAY FROM OXIDIZING
AGENTS & SOURCES OF HEAT OR IGNITION.
Other Precautions:ELECTRICALLY BOND AND GROUND METAL CONTAINERS TO
ELIMINATE STATIC SPARKS.CONTAINERS MAY BE HAZARDOUS WHEN
EMPTIED.EMPTIED CONTAINERS RETAIN RESIDUES WHICH CAN GENERATE
VAPORS W/IN FLAMM LIMITS;OBSERVE ALL HAZARD PRECAUTIONS.

Respiratory Protection:SUFFICIENT TO MAINTAIN EXPOSURE BELOW
OCCUPATIONAL EXPOSURE STANDARDS.ENGINEERING OR ADMINISTRATIVE
CONTROLS OR NIOSH/MSHA APPROVED RESPIRATORS CAN BE USED TO REDUCE
EXPOSURE.ENGINEERING CONTROLS PREF ERRED.
Ventilation:SUFF TO MAINTAIN EXPOS BELOW OCCUP STD.LOC EXHAUST HOODS-AT
LEAST 100 LFM FACE VELOCITY.USE EXPLO-PROOF EQUIP.(SEE SUP)
Protective Gloves:NATURAL RUBBER,NEOPRENE,NITRILE,VITRON.
Eye Protection:SAFETY GLASSES W/ SIDE SHIELDS/GOGGLES.
Other Protective Equipment:EYEWASH STATIONS AND SAFETY SHOWERS SHOULD
BE AVAILABLE IN AREAS OF HANDLING AND USE.
Work Hygienic Practices:LAUNDER CONTAMINATED CLOTHING BEFORE REUSE.
Supplemental Safety and Health
ROUTES OF ENTRY:INGESTION ;SKIN CONTACT (MFR).FIRST AID PROC:IS
DIFFICULT,GIVE O*2.IF BRTHG STOPS,GIVE ARTF RESP.KEEP
WARM,QUIET,GET MED ATTN IMMED.VENT:MAY REQ SUPP VENT FOR PERS PROT
& CONTROL OF FIRE/EXPLO HAZ.QUALIFIED INDEPENDENT TESTING COMPANY
CAN DETERMINE IF EXISTING CONC W/IN REC/PERMISSIBLE LEVELS.

HCC:F3
Boiling Pt:B.P. Text:N/K
Melt/Freeze Pt:M.P/F.P Text:N/K
Decomp Temp:Decomp Text:N/K
Vapor Pres:47 MMHG
Vapor Density:N/K
Spec Gravity:0.79
Evaporation Rate & Reference:3.30,N-BUTYL ACETATE=1.0
Solubility in Water:COMPLETE
Appearance and Odor:CLEAR,COLORLESS LIQUID;ALCOHOL ODOR.
Percent Volatiles by Volume:100

Stability Indicator/Materials to Avoid:YES
STRONG OXIDIZING AGENTS SUCH AS CHLORINE,NITRIC ACID,PERMANGANATE OR
CHROMATE IN ACID SOLUTIONS.
Stability Condition to Avoid:HEAT AND FLAME.
Hazardous Decomposition Products:CO,CO*2.
Conditions to Avoid Polymerization:HAZARDOUS POLYMERIZATION WILL NOT
OCCUR.

Waste Disposal Methods:DISPOSAL MUST BE IN ACCORDANCE W/ FEDERAL,STATE
& LOCAL REGULATIONS .UNDER RCRA,WASTE MATERIAL GENERATOR MUST
DETERMINE IF WASTE IS HAZ.USES,TRANSFORMATIONS,MIXS,PROCESSES,ETC
MAY RENDER MATL HA Z.CONTACT FEDERAL,STATE,LOCAL AUTH FOR DISP
INFO.

Disclaimer (provided with this information by the compiling agencies):
This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.