Product ID:COATING, ALIPH POLYUR.1 COMP, BLACK 37030
MSDS Date:09/10/1990
FSC:8010
NIIN:00-229-7540
MSDS Number: BJLDN

PRATT & LAMBERT INC. INDUSTRIAL COATINGS DIVISION

16116 E. 13TH ST.
WICHITA, KS 67201
US

Emergency Phone: 316-733-1361

Info Phone: 316-733-1361

Preparer: W.A. ELLISON

Cage: PRATT

PRATT AND LAMBERT INC

2153 CLEVELAND, OH 44101-1027 US

Telephone: 216-566-2902

Cage: 61196

METHYL ISOBUTYL KETONE (SARA III)

CAS: 108-10-1

RTECS: SA9275000

Fraction By Weight: 5 - 10%

OSHA PEL 100 PPM/75 STEL

ACGIH TLV: 50 PPM/75 STEL; 9293

EPA Report Quantity: 5000 LBS

DOT Report Quantity: 5000 LBS

XYLENES (O-,M-,P- ISOMERS) (SARA III)

CAS: 1330-20-7

RTECS: ZE2100000

Fraction By Weight: 10 - 20%

OSHA PEL 100 PPM/150 STEL

ACGIH TLV: 100 PPM/150STEL;9192

EPA Report Quantity: 1000 LBS

DOT Report Quantity: 1000 LBS

ETHYL BENZENE (SARA III)

CAS: 100-41-4

RTECS: DA0700000

Fraction By Weight: <5%

OSHA PEL 100 PPM/125 STEL

ACGIH TLV: 100 PPM/125STEL 9192

EPA Report Quantity: 1000 LBS

DOT Report Quantity: 1000 LBS

TOLUENE (SARA III)

CAS: 108-88-3

RTECS: XS5250000

Fraction By Weight: 5 - 10%

OSHA PEL 200 PPM/150 STEL

ACGIH TLV: 50 PPM; 9293

EPA Report Quantity: 1000 LBS

DOT Report Quantity: 1000 LBS

N-BUTYL ACETATE (SARA III)

CAS: 123-86-4

RTECS: AF7350000

Fraction By Weight: 10%

OSHA PEL 150 PPM/200 STEL

ACGIH TLV: 150 PPM/200STEL;9192

EPA Report Quantity: 5000 LBS

DOT Report Quantity: 5000 LBS

SILICA, CRYSTALLINE - CRISTOBALITE

CAS: 14464-46-1

RTECS: VV7325000

Fraction By Weight: 10 -13%

OSHA PEL SEE TABLE Z3

ACGIH TLV: 0.05 MG/M3 RDUST9293

SILICA, AMORPHOUS, DIATOMACEOUS EARTH, CONTAINING LESS THAN

CAS: 61790-53-2

RTECS: HL8600000

Fraction By Weight: 5%

OSHA PEL 20 MPPCF

ACGIH TLV: 10 MG/M3 TDUST; 9293

SILICA, CRYSTALLINE - QUARTZ

CAS: 14808-60-7

RTECS: VV7330000

Fraction By Weight: <1%

OSHA PEL SEE TABLE Z3

ACGIH TLV: 0.1 MG/M3 RDUST;9293

SILICA, CRYSTALLINE - QUARTZ

CAS: 14808-60-7

RTECS: VV7330000

Fraction By Weight: 15 - 25%

OSHA PEL SEE TABLE Z3

ACGIH TLV: 0.1 MG/M3 RDUST;9293

CARBON BLACK

CAS: 1333-86-4

RTECS: FF5800000

Fraction By Weight: 5 - 10%

OSHA PEL 3.5 MG/M3

ACGIH TLV: 3.5 MG/M3; 9192

ISOPHORONE DIISOCYANATE (VP 1 MMHG @ 20C) (SKIN)

CAS: 4098-71-9

RTECS: NQ5400000

Fraction By Weight: <5%

OSHA PEL S 0.005PPM/0.02STEL

ACGIH TLV: 0.005 PPM; 9394

DIBUTYL TIN DILAURATE (SKIN)

CAS: 77-58-7

RTECS: WH7000000

Fraction By Weight: <1%

OSHA PEL .1000 PPM

ACGIH TLV: .1000 PPM

POLYMERIC HEXAMETHYLENE DIISOCYANATE

CAS: 28182-81-2

RTECS: HQ9170000

Fraction By Weight: 20%

OSHA PEL 1 PPM

SOLVENT NAPTHA, LIGHT AROMATIC

CAS: 64742-95-6

Fraction By Weight: <5%

1,6-DIISOCYANATOHEXANE (HEXAMETHYLENE DIISOCYANATE)

CAS: 822-06-0

RTECS: MO1740000

Fraction By Weight: <100%

ACGIH TLV: 0.005 PPM; 9192

EPA Report Quantity: 1 LB

DOT Report Quantity: 1 LB

VOC 3.48 LB/GAL LESS WATER & NPRS* 418 G/L LESS WATER

RTECS: 9999999VO

VOC 6.77 LB/GAL SOLIDS 812 G/L SOLIDS CALCULATED

RTECS: 9999999VO

Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:NO IARC:YES OSHA:NO
Health Hazards Acute and Chronic:REPEATED EXPOS TO CRYSTALLINE SILICA
MAY CAUSE PNEUMON, A PROGRESS DISABLING LUNG DISEASE. XYLENE-INJURY
TO LIVER,KIDNEYS,BLOOD. TOLUENE-LIVER DAMAGE. DIISOCYANATES-RSPRTRY
SENSITIZ. REPORTS ASSOCIATE OVEREXP TO SOLVENTS W/PERMANENT BRAIN
& NERV SYST DAMAGE. MISUSE BY DELIBERATE CONCENTRATE/INHALE MAY BE
HARMFUL/FATAL
Explanation of Carcinogenicity:IARC CONSIDERS CRYSTALLINE SILICA TO
HAVE LIMITED EVIDENCE OF CARCINOGENICITY IN HUMANS & SUFFICIENT
EVIDENCE IN ANIMALS
Effects of Overexposure:SWALLOWED:MAY BE FATAL. GASTRO
IRRIT,NAUSEA,VOMIT.ASPIRATION INTO LUNG MAY CAUSE CHEM PNEUMON
WHICH CAN BE FATAL. INHALE:LUNG IRRIT & ALLERGIC RSPRTRY REACTION,
RSPRTRY SENSIZ, NOSE OR THROAT IRRIT. A CUTE CENTRAL NERV SYST
DEPRESS, HEADACHES, DIZZ, NAUSE & CONFUSION. EYE:IRRIT. SKIN:IRRIT,
ALLERGIC REACT, DEFATT/IRRIT
Medical Cond Aggravated by Exposure:PREXISTING RESPIRATORY CONDITIONS
MAY BE AGGRAVATED BY EXPOSURE TO CRYSTALLINE SILICA.

First Aid:SWALLOW:DO NOT INDUCE VOMIT. CALL PCC/HOSPITAL/PHYSICIAN
IMMED. INHALED:REMOVE TO FRESH AIR IMMED. IF BREATH STOPPED, GIVE
CPR. KEEP WARM/QUIET. GET MED ATTN IMMED. EYES:FLUSH W/H2O, LIFTING
LIDS FOR 15 MINS. GET MED ATTN. SKIN:REMOVE CONTAM CLOTHES. WASH
AFFECTED AREA W/SOAP & H2O. OBTAIN MED ATTN IF IRRIT PERSIST. NOTE
TO PHYSICIAN:DIRECT TREATMENT AT CONTROL OF SYMPTOMS & CLINICAL
CONDITIONS.

Flash Point:40 F/4 C
Extinguishing Media:USE NFPA CLASS B FIRE EXTINGUISHERS DESIGNED FOR
FLAMMABLE LIQUID FIRES. POLYMER FOAM IS PREFERRED FOR LARGE FIRES.
Fire Fighting Procedures:USE WATER TO COOL EXPOSED CONTAINERS TO
PREVENT PRESSURE BUILD-UP/AUTO-IGNITE/EXPLOSION FROM EXTREME HEAT.
IF WATER USED, FOG NOZZLES ARE PREFERRABLE.
Unusual Fire/Explosion Hazard:OVEREXPOSURE TO DECOMPOSITION PRODUCTS
MAY CAUSE A HEALTH HAZARD. SYMPTOMS MAY NOT BE IMMEDIATELY
APPARENT. OBTAIN MEDICAL ATTENTION. WARNING! FLAMMABLE!

Spill Release Procedures:KEEP SPECTATORS AWAY. ELIM IGNITE SOURCES.
DIKE & CONTAIN W/INERT MATERIAL(SAND)TRANSFER LIQ TO COVERED METAL
CONTAIN FOR RECOVERY/DISPOSAL. REMOVE W/INERT ABSORB. USE ONLY
NON-SPARK TOOLS. PREVENT CO NTAM OF SEWER,GROUNDWATERS
W/MATERIAL/ABSORB**
Neutralizing Agent:N/K.**WEAR RSPRTRS,EYE,HAND,BODY PROTECT APPROPRIATE
FOR SIZE OF SPILL/EXPOSURE.

Handling and Storage Precautions:DON'T STORE ABOVE 95F. STORE LG AMOUNT
IN COMPLIANCE W/OSHA 29CFR1910.106. DO NOT TAKE INTERNALLY. CLOSE
CONTAINER AFTER EACH USE. DO NOT BREATH DUST.
Other Precautions:PERSONS WHO HAVE/HAD CHRONIC(LONG TERM)BREATH
PROBLEMS OR REACT TO ISOCYANATE. DON'T BREATH VAPOR/MIST. DON'T GET
IN EYES,SKIN,CLOTHES. WASH THORO AFTER HANDLING. USE ONLY
W/ADEQUATE VENT. EMPTY CONTA IN MUST NOT BE WASH & REUSED AT ALL***

Respiratory Protection:WEAR APPROPRIATE PROPERLY FITTED POSITIVE
PRESSURE AIR SUPPLIED RSPRTR(TC 19C NIOSH/MSHA)WHEN EXPOSED. OR
VAPOR PARTICULATE(PAINT SPRAY)RSPRTR MFR RECOMMENDED EFFECTIVE FOR
ISOCYANATE VAPORS/MISTS. US E POSITIVE PRESSURE AIR-SUPPLIED
RSPRTR.
Ventilation:GEN DILUTE/LOCAL EXHAUST IN VOL/PATTERN TO KEEP CONCENTRATE
OF HAZARD INGRED BELOW LOWEST LIMITS. REMOVE DECOMP PRODUCTS
Protective Gloves:WEAR APPROPRIATE IMPERMEABLE GLOVES
Eye Protection:SAFETY SPECTACLES & CHEM SPLASH GOGGLES
Other Protective Equipment:EYEWASH FACILITY, SAFETY SHOWER. AS REQUIRED
TO PREVENT SKIN CONTACT.
Work Hygienic Practices:WASH THOROUGHLY AFTER HANDLING AND BEFORE
EATING OR DRINKING. LAUNDER CONTAMINATED CLOTHING BEFORE REUSE.
Supplemental Safety and Health
***CONTAINERS SHOULD BE GROUNDED & BONDED TO RECEIVING CONTAINER. DO
NOT WELD, BRAZE OR CUT ON EMPTY CONTAINER. NEVER USE PRESSURE TO
EMPTY. DRUM IS NOT A PRESSURE VESSEL. PRODUCT IF DISCARDED DIRECTL
Y WOULD BE CLASSIFIED A HAZARD WASTE BASED ON IGNITE CHARACTER I.E.
FLASH POINT 140F. PROPER RCRA CLASS WOULD BE D001.

Boiling Pt:B.P. Text:139 TO 419F
Vapor Density:> THAN AIR
Spec Gravity:1.2
Evaporation Rate & Reference:SLOWER THAN ETHER
Percent Volatiles by Volume:48

Stability Indicator/Materials to Avoid:YES
STRONG ACIDS OR ALKALINE MATERIALS. OXIDIZING MATERIALS.
Stability Condition to Avoid:AVOID EXCESSIVE HEAT AND SOURCES OF
IGNITION.
Hazardous Decomposition Products:BURNING, INCLUDING WHEN HEATED BY
WELD/CUTTING, WILL PRODUCT SMOKE/CO/CO2/OXIDES OF NITROGEN.
ISOCYANATES W/H2O MAY *
Conditions to Avoid Polymerization:KEEP AWAY FROM HEAT, SPARKS, FLAME.
*PRODUCE HYDROGEN GAS WHICH MAY FORM FLAMMABLE/EXPLOSIVE MIXTURES
WITH AIR.

Waste Disposal Methods:DISPOSE IN ACCORDANCE WITH FEDERAL, STATE &
LOCAL LAWS. INCINERATE ONLY EPA PERMITTED FACILITY. DO NOT
INCINERATE CLOSED CONTAINERS. OBSERVE PRECAUTIONS FOR DISPOSAL OF
FLAMMABLE MATERIALS. CONTAMINAT ED ABSORB MAY BE DISPOSED IN HAZARD
WASTE LANDFILL

Disclaimer (provided with this information by the compiling agencies):
This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.