Product ID:12
MSDS Date:03/01/1990
FSC:3439
NIIN:00-204-3592
MSDS Number: BJXHY

HOBART BROTHERS CO

600 WEST MAIN STREET
TROY, OH 45373
US

Emergency Phone: 513-332-4000

Info Phone: 513-332-4000

Cage: 28835

HOBART BROTHERS CO

TROY, OH 45373 US

Telephone: 513-339-6000

Cage: 28835

IRON

CAS: 7439-89-6

RTECS: NO4565500

Fraction By Weight: 70-90%

OSHA PEL 5 MG/M3

MANGANESE (SARA III)

CAS: 7439-96-5

RTECS: OO9275000

Fraction By Weight: 1-6%

OSHA PEL (C) 5 MG/M3 DUST

ACGIH TLV: 5 MG/M3 DUST 9293

TITANIUM DIOXIDE

CAS: 13463-67-7

RTECS: XR2275000

Fraction By Weight: 2-10%

OSHA PEL 15 MG/M3 TDUST

ACGIH TLV: 10 MG/M3 TDUST; 9293

POTASSIUM SILICATE

CAS: 1312-76-1

Fraction By Weight: <5%

SODIUM SILICATE

CAS: 1344-09-8

Fraction By Weight: 3-15%

LD50 LC50 Mixture:UNCLASSIFIED WELDING FUMES=5MG/M3 PEL
Routes of Entry: Inhalation:YES Skin:YES Ingestion:NO
Reports of Carcinogenicity:NTP:NO IARC:NO OSHA:NO
Health Hazards Acute and Chronic:SHORT TERM EXPOSURE TO WELDING FUMES,
GASES OR DUST MAY RESULT IN DISCOMFORT SUCH AS DIZZINESS, NAUSEA,
FEVER, DRYNESS AND/OR IRRITATION OF NOSE, THROAT AND EYES. SKIN
SENSITIVITY MAY ALSO BE NOTED. A CUTE EXPOSURE FROM SOME TOXIC
GASES MAYCAUSE PULMONARY EDEMA, ASPHYXIATION AND EXCESSIVE EXPOSURE
CAN BE FATAL.
Explanation of Carcinogenicity:THIS COMPOUND CONTAINS NO INGREDIENTS AT
CONCENTRATIONS OF 0.1% OR GREATER THAT ARE CARCINOGENS OR SUSPECT
CARCINOGENS.
Effects of Overexposure:EXPOSURE TO WELDING FUMES MAY RESULT IN
DISCOMFORT SUCH AS DIZZINESS, NAUSEA, FEVER, DRYNESS AND/OR
IRRITATION OF NOSE, THROAT AND EYES. SKIN SENSITIVITY MAY ALSO BE
NOTED. WATERY EYES, HEADACHE, BREA THING DIFFICULTY, FREQUENT
COUGHING AND/OR CHEST PAINS MAY OCCUR FROM ACUTE EXPOSURE. TOXIC
GASES CAN BE FATAL.
Medical Cond Aggravated by Exposure:SOME WORKERS MAY BE AFFECTED BY A
PRE-EXISTING CONDITION OR OTHER OCCUPATIONAL ILLNESS BECAUSE OF THE
WIDE VARIATION IN INDIVIDUAL SUSCEPTIBILITIES.

First Aid:IN CASE OF ELECTRICAL SHOCK, TURN OFF POWER PRIOR TO REMOVAL
FROM EXPOSURE AREA AND ADMINISTRATION OF FIRST AID. REMOVE FROM
EXPOSURE AREA AND CALL FOR MEDICAL AID. ADMINISTER OXYGEN IF
BREATHING IS D IFFICULT. IF NOT BREATHING, BEGIN ARTIFICIAL
RESPIRATION. IF NO DETECTABLE PULSE, BEGIN EXTERNAL HEART MASSAGE.
EMPLOY FIRST AID TECHNIQUES RECOMMENDED BY THE AMERICAN RED CROSS.

Flash Point:NONE
Autoignition Temp:Autoignition Temp Text:NONE
Extinguishing Media:USE MEDIA APPROPRIATE FOR SURROUNDING FIRE.
Fire Fighting Procedures:WEAR FIRE FIGHTING PROTECTIVE EQUIPMENT AND A
FULL FACED SELF CONTAINED BREATHING APPARATUS. EVACUATE AREA. COOL
FIRE EXPOSED CONTAINERS WITH WATER SPRAY.
Unusual Fire/Explosion Hazard:WELDING ARC AND SPARKS CAN IGNITE
COMBUSTIBLES. SEE Z49.1 REFERENCED IN SECTION 7.

Spill Release Procedures:CLEAN UP ANY GRINDING DUST OR WASTE RESIDUES
AND PLACE IN SUITABLE DOT APPROVED CONTAINERS AND DISPOSE OF IN
FULL COMPLIANCE WITH FEDERAL, STATE AND LOCAL REGULATIONS. AVOID
INHALATION AND SKIN EXPOSU RE.

Handling and Storage Precautions:WEAR GLOVES AND FLAME RETARDANT
CLOTHING WHEN CUTTING, GRINDING OR WELDING. DO NOT EXPOSE SKIN TO
RADIATION WHEN HOT CUTTING OR WELDING.
Other Precautions:PROVIDE PROTECTIVE SCREENS TO SHIELD OTHERS. WHEN
ELECTRODES AND FLUXES ARE CONSUMED, THE FUME AND GAS DECOMPOSITION
PRODUCTS GENERATED ARE DIFFERENT IN FORM FROM THE INGREDIENTS
LISTED. NEW COMPOUNDS NOT IN THE ELECTRODES MAY FORM.

Respiratory Protection:USE WELD FUME RESPIRATOR OR AIR SUPPLIED
RESPIRATOR WHEN CUTTING, GRINDING OR WELDING IN A CONFINED SPACE OR
WHERE LOCAL EXHAUST OR GENERAL VENTILATION DOES NOT KEEP EXPOSURE
BELOW RECOMMENDED LIMITS. USE ONLY NIOSH APPROVED RESPIRATORS.
Ventilation:USE ENOUGH VENTILATION WHEN CUTTING, GRINDING OR WELDING TO
KEEP THE DUST, FUMES & GASES FROM THE WORKERS BREATHING ZONE
Protective Gloves:WELDERS LEATHER GLOVES
Eye Protection:OSHA APPROVED GOGGLES/FACE SHIELD W/LENS
Other Protective Equipment:FLAME RETARDANT CLOTHING WHEN CUTTING,
GRINDING OR WELDING. DO NOT EXPOSE SKIN TO RADIATION WHEN HOT
CUTTING OR WELDING.
Work Hygienic Practices:WASH THOROUGHLY BEFORE EATING OR SMOKING.
LAUNDER CONTAMINATIED CLOTHING BEFORE REUSE.
Supplemental Safety and Health
WELDING AND HOT CUTTING FUMES & GASES CANNOT BE CLASSIFIED SIMPLY.
THEIR COMPOSITION AND QUANTITY ARE DEPENDENT ON THE METAL BEING
WELDED, THE PROCEDURES, PROCESSES AND THE TYPE OF WIRE OR
ELECTRODES USED. OTHER INFLUENCING FACTORS ARE THEPRESENCE OF
CONTAMINANTS. CHLORINATED SOLVENTS MAY DECOMPOSE TO TOXIC GASES.

HCC:N1
Evaporation Rate & Reference:0
Solubility in Water:NEGLIGIBLE
Appearance and Odor:0.125 INCH DIAMETER BY 18 INCH LONG STEEL WELDING
ROD
Percent Volatiles by Volume:0

Stability Indicator/Materials to Avoid:YES
STRONG MINERAL ACIDS
Hazardous Decomposition Products:WELDING AND CUTTING OPERATION MAY
INCLUDE OXIDES OF THE METALS, CHROMATES, FLUORIDES, COMPLEX
METALLICS, AND OZONE.

Waste Disposal Methods:DISPOSE I/A/W FEDERAL, STATE & LOCAL REGULATIONS

Disclaimer (provided with this information by the compiling agencies):
This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.