Product ID:MIDGRADE-89 OCTANE GASOLINE
MSDS Date:06/13/1989
FSC:9130
NIIN:01-272-0983
MSDS Number: BKMZD

CITGO PETROLEUM CORP

6100 S YALE BLDG 1 WARREN PL
TULSA, OK 74102
US

Emergency Phone: 318-491-6215, CHEMTREC 800-424-9300

Info Phone: 918-495-5933

Cage: 7X110

CITGO PETROLEUM CORP

3758 TULSA, OK 74102 US

Telephone: 918-495-5933

Cage: 7X110

BENZENE (SARA III)

CAS: 71-43-2

RTECS: CY1400000

Fraction By Weight: <5.0%

OSHA PEL 1PPM/5STEL;1910.1028

ACGIH TLV: 10 PPM; A2; 9192

EPA Report Quantity: 10 LBS

DOT Report Quantity: 10 LBS

PETROLEUM DISTILLATE MIXTURE

Fraction By Weight: 85-98%

OSHA PEL 400 PPM

ACGIH TLV: 300 PPM

ALIPHATIC ALCOHOLS

Fraction By Weight: 0-11%

LOWER ALIPHATIC ETHERS

Fraction By Weight: 0-15%

OSHA PEL 400 PPM

ACGIH TLV: 400 PPM

TOLUENE (SARA III)

CAS: 108-88-3

RTECS: XS5250000

Fraction By Weight: 0-25%

OSHA PEL 200 PPM/150 STEL

ACGIH TLV: 50 PPM; 9293

EPA Report Quantity: 1000 LBS

DOT Report Quantity: 1000 LBS

1,2,4-TRIMETHYLBENZENE (SARA III)

CAS: 95-63-6

RTECS: DC3325000

Fraction By Weight: 0-5%

OSHA PEL 25 PPM

ACGIH TLV: 25 PPM; 9192

XYLENES (O-,M-,P- ISOMERS) (SARA III)

CAS: 1330-20-7

RTECS: ZE2100000

Fraction By Weight: 0-25%

OSHA PEL 100 PPM/150 STEL

ACGIH TLV: 100 PPM/150STEL;9192

EPA Report Quantity: 1000 LBS

DOT Report Quantity: 1000 LBS

Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:YES IARC:YES OSHA:YES
Health Hazards Acute and Chronic:ACUTE-INHALATION:CENTRAL NERVOUS
SYSTEM DEPRESSION, HEADACHE, NAUSEA, DIZZINESS, FATIGUE, NARCOSIS,
UNCONSCIOUSNESS, ASPHYXIATION. EYE:IRRITATION. SKIN:DEFATING,
IRRITATION/DERMATITIS. INGESTION: GI D ISTURBANCES, NAUSEA,
VOMITING. CHRONIC:DERMATITIS, PNEUMOTITIS, PULMONARY EDEMA, AND
KIDNEY DAMAGE.
Explanation of Carcinogenicity:BENZENE IS LISTED AS A CARCINOGEN BY
NTP, IARC, OSHA AND EPA.
Effects of Overexposure:OVEREXPOSURE MAY LEAD TO RESPIRATORY
IRRITATION, NAUSEA, FATIGUE, DIZZINESS, HEADACHES, UNCONSCIOUSNESS,
AND EYE IRRITATION.
Medical Cond Aggravated by Exposure:PERSONS WITH A SKIN DISORDER SHOULD
USE CAUTION WHEN HANDLING OR USING THIS PRODUCT.

First Aid:SKIN: REMOVE CONTAMINATED CLOTHING. WASH WITH SOAP AND WATER.
GET MEDICAL ATTENTION IF IRRITATION PERSISTS. INHALATION: REMOVE TO
FRESH AIR & RESTORE BREATHING IF NECESSARY. GET MEDICAL ATTENTION.
EYE : IMMEDIATELY FLUSH WITH WATER FOR 15 MINUTES WHILE HOLDING
EYELIDS OPEN. GET MEDICAL ATTENTION. INGESTION: GET IMMEDIATE
MEDICAL ATTENTION. DO NOT INDUCE VOMITING. NOTHING BY MOUTH IF
UNCONSCIOUS.

Flash Point Method:TCC
Flash Point:<-45F,<-43C
Autoignition Temp:Autoignition Temp Text:495F
Lower Limits:1.4%
Upper Limits:7.6%
Extinguishing Media:USE CARBON DIOXIDE, FOAM, OR DRY CHEMICAL. USE
WATER FOG TO COOL SRROUNDING CONTAINERS.
Fire Fighting Procedures:WEAR FIRE FIGHTING PROTECTIVE EQUIPMENT AND A
FULL FACED SELF CONTAINED BREATHING APPARATUS. EVACUATE AREA. COOL
FIRE EXPOSED CONTAINERS WITH WATER SPRAY.
Unusual Fire/Explosion Hazard:VAPORS HEAVIER THAN AIR AND MAY TRAVEL A
CONSIDERABLE DISTANCE TO SOURCE OF IGNITION AND FLASH BACK.

Spill Release Procedures:MINOR: ABSORB MATERIAL WITH CLAY, VERMICULITE,
OR SIMILAR ABSORBENT MATERIAL. PLACE IN DISPOSAL CONTAINERS. MAJOR:
DIKE & CONTAIN SPILL. ELIMINATE SOURCES OF IGNITION. SHUT OFF
LEAKS. REMOVE LIQUID BY VACUUM OR ABSORBENT.

Handling and Storage Precautions:STORE IN A COOL, VENTILATED WORK AREA.
KEEP CONTAINERS CLOSED WHEN NOT IN USE. FLAMMABLE LIQUID; EMPTY
CONTAINERS CAN BE HAZARDOUS.
Other Precautions:THE SELECTION OF PERSONAL PROTECTIVE EQUIPMENT SHOULD
BE MADE BY THE MATERIAL USER BASED ON THE PARTICULAR CONDITIONS
WHERE THE MATERIAL IS TO BE USED TOGETHER WITH INFORMATION
CONTAINED IN THIS MSDS.

Respiratory Protection:USE NIOSH/MSHA APPROVED RESPIRATOR. AIR-SUPPLIED
OR FILTERING TYPE WITH ORGANIC VAPOR CARTRIDGES ARE RECOMMENDED.
Ventilation:LOCAL AND MECHANICAL EXHAUST RECOMMENDED. AVOID OPEN
ELECTRICAL SOURCES NEAR PRODUCT VAPOR AREAS.
Protective Gloves:NEOPRENE, NITRILE, OR POLYVINYL ALCOHOL
Eye Protection:USE CHEMICAL SAFETY GOGGLES & FACESHIELD
Other Protective Equipment:EYE WASH STATION & SAFETY SHOWER.
Work Hygienic Practices:DO NOT TAKE INTERNALLY. AVOID SKIN CONTACT.
WASH SKIN AFTER USING PRODUCT. DO NOT EAT, DRINK OR SMOKE IN WORK
AREA.
Supplemental Safety and Health
NONE

HCC:F2
Boiling Pt:B.P. Text:95.0F,35.0C
Vapor Pres:510-760MM
Vapor Density:3-4
Spec Gravity:0.75
Evaporation Rate & Reference:<1 (BU AC=1)
Solubility in Water:NEGLIGIBLE
Appearance and Odor:LIGHT YELLOW OR CLEAR LIQUID WITH CHARATERISTIC
GASOLINE ODOR
Percent Volatiles by Volume:100

Stability Indicator/Materials to Avoid:YES
STRONG OXIDIZING AGENTS
Stability Condition to Avoid:HIGH HEAT, OPEN FLAMES AND OTHER SOURCES
OF IGNITION
Hazardous Decomposition Products:CARBON MONOXIDE, CARBON DIOXIDE AND
OTHER HYDROCARBON COMPOUNDS DURING COMBUSTION.

Waste Disposal Methods:WASTE MAY BE BURNED IN AN APPROVED INCINERATOR
OR DISPOSED OF IN ACCORDANCE WITH ALL APPLICABLE LOCAL, STATE AND
FEDERAL LAWS AND REGULATIONS.

Disclaimer (provided with this information by the compiling agencies):
This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.