Product ID:CLEANING SOLVENT 565
MSDS Date:09/01/1988
FSC:3439
NIIN:00N014730
MSDS Number: BKPBW

ALPHA METALS

600 ROUTE 440
JERSEY CITY, NJ 07304
US

Emergency Phone: 800-424-9300 (CHEMTREC)

Info Phone: 201-434-6778

Cage: 96613

FRYS METALS INC (FORMER ALPHA METALS)

JERSEY CITY, NJ 07304 US

Telephone: 201-434-6778

Cage: 96613

METHYL CHLOROFORM (1,1,1-TRICHLOROEHANE) (SARA III)

CAS: 71-55-6

RTECS: KJ2975000

Fraction By Weight: >90%

OSHA PEL 350 PPM/450 STEL

ACGIH TLV: 350 PPM/450STEL;9192

EPA Report Quantity: 1000 LBS

DOT Report Quantity: 1000 LBS

N-PROPYL ALCOHOL

CAS: 71-23-8

RTECS: UH8225000

Fraction By Weight: <5%

OSHA PEL 200 PPM/250 STEL

ACGIH TLV: S,200PPM/250STEL9192

1,4-DIOXANE (DIETHYLENE DIOXIDE) (SARA III)

CAS: 123-91-1

RTECS: JG8225000

Fraction By Weight: <5%

OSHA PEL S, 100 PPM

ACGIH TLV: S, 25 PPM; 9293

EPA Report Quantity: 100 LBS

DOT Report Quantity: 100 LBS

THREE

RTECS: 9999999ZZ

EFFECTS OF 1,1,1 TRICHLOROETHANE ON REPRODUCTION &

RTECS: 9999999ZZ

REPRO TOXICITY. THE THIRD STUDY NOTED DELAYS IN

RTECS: 9999999ZZ

CHLOROCARBON/CHLOROFLUOROCARBON (CFC) MATLS HAVE

RTECS: 9999999ZZ

IN LAB ANIMALS & COULD HAVE A SIMILAR EFFECT IN

RTECS: 9999999ZZ

CONTRAINDICATED EXCEPT FOR LIFE-SUSTAINING USES IN

RTECS: 9999999ZZ

USE IN GENERAL VICINITY OF ARC

RTECS: 9999999ZZ

AND/OR UV RADIATION MAY CAUSE THE FORMATION OF HCL

RTECS: 9999999ZZ

LD50 LC50 Mixture:NONE SPECIFIED BY MANUFACTURER.
Routes of Entry: Inhalation:YES Skin:NO Ingestion:NO
Reports of Carcinogenicity:NTP:YES IARC:YES OSHA:NO
Health Hazards Acute and Chronic:INHAL:CAN CAUSE DIZZINESS, DROWSINESS
& THROAT IRRIT. UNCON & DEATH POSSIBLE AT EXPOSURES ABOVE 10,000
PPM. INGEST: SMALL AMTS ARE NOT LIKELY TO BE TOXIC. MAY CAUSE
VOMITING. SKIN:PRLNGD/RPTD CONTACT CAN CAUSE DERMATITIS THROUGH
DEFATTING.EYES:LIQUID/VAPORS CAN IRRIT. MAY CAUSE CONJUNCTIVITIS,
(SEE EFTS OF OVEREXP)
Explanation of Carcinogenicity:DIETHYLENE ETHER:NTP AND IARC ANIMAL
CARCINOGEN.
Effects of Overexposure:HLTH HAZ:NO PERM INJURY EXPECTED. CHRONIC:
OVEREXPOS TO 1,1,1-TRICHLOROETHANE HAS CAUSED LIVER TOXIC EFFECTS
IN EXPERIMENTAL ANIMALS. 1,1,1-TRICHLOROETHANE STABILIZED
W/DIETHYLENE ETHER HAS BEEN TESTE D IN LAB ANIMALS & WAS NOT FOUND
TO CAUSE CANCER. NOTE TO MD: ADRENALIN SHOULD NEVER BE GIVEN TO
PERSONS (SEE SUPP DATA)
Medical Cond Aggravated by Exposure:NONE SPECIFIED BY MANUFACTURER.

First Aid:INHAL:REMOVE TO FRESH AIR. GIVE ARTF RESP IF NOT BRTHG. CALL
MD. INGEST:DO NOT INDUCE VOMITING. CONTACT MD OR EMERGENCY MEDICAL
FACILITY IMMEDIATELY. SKIN:WASH W/SOAP & WATER. REMOVE CONTAMINATED
CLTH G. GET MD IF IRRITATION PERSISTS. EYE:FLUSH IMMEDIATELY
W/WATER FOR AT LEAST 15 MINUTES.IF IRRITATION PERSISTS, CALL MD.

Flash Point Method:TCC
Flash Point:NONE
Lower Limits:3.0
Upper Limits:15.0
Extinguishing Media:CARBON DIOXIDE OR DRY CHEMICAL.
Fire Fighting Procedures:USE NIOSH/MSHA APPROVED PRESSURE DEMAND SCBA
AND FULL PROTECTIVE EQUIPMENT .
Unusual Fire/Explosion Hazard:EXTING ALL NEARBY SOURCES OF IGNIT SINCE
VAPORS CAN DECOMPOSE TO HAZ SUBSTANCES AT HIGH TEMPERATURES.
THERMAL DECOMP PRODS MAY INCLUDE HCL & PHOSGENE .

Spill Release Procedures:EVACUATE AREA. WEAR NIOSH/MSHA APPRVD RESP
PROT & GLOVES. EXTINGUISH ALL IGNITION SOURCES, CLEAN BY MOPPING OR
W/ ABSORBENT MATL & TRANSFER TO APPROP CLOSED CNTNRS. KEEP AWAY
FROM SEWERS & SURFACE WAT ERS.
Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER.

Handling and Storage Precautions:STORE LABELED CNTNRS IN COOL, DRY,
WELL VENT AREA. KEEP CNTNR CLOSED WHEN NOT IN USE. VENT CNTNR OFTEN
IN WARM WEATHER. READ ALL CNTNR (SEE SUPP DATA)
Other Precautions:CNTNRS:SINCE EMPTY CNTNRS MAY RETAIN PROD RESIDUES
(VAP, LIQ, SOLID) ALL LABELED HAZ PREC MUST BE OBSERVED. FOR
INDUSTRIAL USE ONLY. KEEP OUT OF REACH OF CHILDREN. DO NOT TAKE
INTERNALLY. NO SMOKING I N AREA OF USE. DO NOT (SEE INGRED 10)

Respiratory Protection:WHERE EXPOSURE LIMITS MAY BE EXCEEDED, USE
NIOSH/ MSHA APPROVED ORGANIC VAPOR TYPE RESPIRATOR (MFR). WEAR
NIOSH/MSHA APPROVED PRESSURE DEMAND SELF-CONTAINED BREATHING
APPARATUS AND FULL PROTECTIVE EQU IPMENT .
Ventilation:DO NOT USE IN CLOSED/CONFINED SPACES. PROVIDE SUFFICIENT
MECH (GEN &/OR LOCAL EXHST) VENT TO MAINTAIN (SEE SUPP DATA)
Protective Gloves:VITON, PVA OR NITRILE RUBBER GLOVES.
Eye Protection:CHEMICAL WORKERS GOGGLES .
Other Protective Equipment:PROVIDE EYE BATH NEAR WORK SITE.
Work Hygienic Practices:CONTACT LENSES SHOULD NOT BE WORN. WASH AFTER
HANDLING.
Supplemental Safety and Health
HNDLG/STOR PREC:LABELING. VAPS ARE HEAVIER THAN AIR & WILL COLLECT IN
LOW PLACES SUCH AS PITS/DEGREASERS. DO NOT GET IN EYES, ON SKIN OR
CLTHG. DO NOT REMOVE LABELS. DO NOT EAT, DRINK, SMOKE IN WORK A
REA. DO NOT STORE IN ALUMINUM CNTNRS. VENT:EXPOS LEVELS BELOW EXPOS
LIMITS. EFTS OF OVEREXP:EXPOSED TO (SEE INGRED 4)

HCC:T4
Boiling Pt:B.P. Text:165F,74C
Vapor Pres:100
Vapor Density:4.6
Spec Gravity:1.275
Evaporation Rate & Reference:<1.0 (BUTYL ACETATE = 1)
Solubility in Water:SLIGHT.
Appearance and Odor:CLEAR, COLORLESS LIQUID, MILDLY SWEET ODOR.
Percent Volatiles by Volume:100 WT

Stability Indicator/Materials to Avoid:YES
STRONG ALKALIES, OXIDIZING MATERIALS.
Stability Condition to Avoid:CONTACT W/OPEN FLAME, ELECTRIC ARCS, OR
OTHER HOT SURFACES WHICH CAN CAUSE THERMAL DECOMPOSITION.
Hazardous Decomposition Products:HYDROGEN CHLORIDE, PHOSGENE (SMALL
AMOUNTS)

Waste Disposal Methods:RECOVERED LIQUID MAY BE SENT TO LICENSED
RECLAIMER OR MAY BE INCINERATED. ABSORBED MATERIAL CAN BE DISPOSED
OF IN PERMITTED WASTE MANAGEMENT FACILITY. MUST BE I/A/W FEDERAL,
STATE AND LOCAL LAWS AND R EGULATIONS.

Disclaimer (provided with this information by the compiling agencies):
This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.