Product ID:PR-1440, PART A
MSDS Date:12/06/1989
FSC:8030
NIIN:00-753-5009
MSDS Number: BLLVY

COURTAULDS AEROSPACE INC

757 CALIFORNIA ST
GLENDALE, CA 91203
US

Emergency Phone: 818-549-7973

Info Phone: 818-549-7973

Preparer: AS

Cage: 83574

PRC-DESOTO INTERNATIONAL, INC. A PPG INDUSTRIES COMPANY

1800 GLENDALE, CA 91209 US

Telephone: 818-240-2060

Cage: 83574

MANGANESE DIOXIDE (EXPOS LIM BASED ON AIRBORNE PARTICLES.

CAS: 1313-13-9

RTECS: OP0350000

Fraction By Weight: 60%

OSHA PEL 5 MG/M3 STEL CEILING

ACGIH TLV: 5 MG/M3

1,3 DIPHENYL GUANIDINE (DPG)

CAS: 102-06-7

RTECS: MF0875000

Fraction By Weight: < 5%

Routes of Entry: Inhalation:YES Skin:YES Ingestion:NO
Reports of Carcinogenicity:NTP:NO IARC:NO OSHA:NO
Health Hazards Acute and Chronic:EYES/SKIN: IRRITATION. INHALATION:
ALTHOUGH THE MAIN HAZARD OF MANGANESE COMPOUNDS IS BY BREATHING
DUST, INGESTION SHOULD BE AVOIDED AS A PRECAUTION AGAINST MANGANESE
POISONING. SYMPTOMS OF MANGANESE POISONING ARE WEAKNESS AND
SLEEPINESS.

First Aid:EYES: FLUSH WITH LUKEWARM WATER FOR 15 MINUTES. IF SYMPTOMS
PERSIST, CONSULT PHYSICIAN. SKIN: WASH WITH SOAP AND WATER. IF
SYMPTOMS PERSIST, CONSULT A PHYSICIAN. INHALATION: REMOVE TO FRESH
AIR. IF SY MPTOMS ARE PRESENT, CONSULT A PHYSICIAN. INGESTION:
CONSULT A PHYSICIAN.

Flash Point:NONE
Lower Limits:NA
Upper Limits:NA
Extinguishing Media:CO2, DRY CHEMICAL, FOAM, WATER.
Fire Fighting Procedures:USE AIR SUPPLIED RESPIRATOR. USE WATER TO COOL
HEAT EXPOSED CONTAINERS.
Unusual Fire/Explosion Hazard:EXCESSIVE HEAT MAY CAUSE DECOMPOSITION OF
MANGANESE DIOXIDE, RESULTING IN OXIDIZATION AND POSSIBLE IGNITION
OF HYDROCARBON VEHICLE.

Spill Release Procedures:SCOOP INTO CONTAINERS. CLEAN-UP RESIDUE WITH
1,1,1-TRICHLOROETHANE.

Ventilation:GENERAL VENTILATION
Protective Gloves:SOLVENT RESISTANT GLOVES
Eye Protection:SAFETY GLASSES
Work Hygienic Practices:WASH THOROUGHLY AFTER HANDLING AND BEFORE
SMOKING OR EATING. AVOID INGESTION.
Supplemental Safety and Health
KEY1:N1. THIS PRODUCT CONTAINS A TOXIC CHEMICAL OR CHEMICALS SUBJECT TO
THE REPORTING REQUIREMENTS OF SECTION 313 OF TITLE III OF THE
SUPERFUND AMENDMENTS AND REAUTHORIZATION ACT OF 1986 AND 40 CFR PA
RT 372 (SARA 313).

HCC:F2
Boiling Pt:B.P. Text:NA
Vapor Pres:NA
Vapor Density:NA
Spec Gravity:1.95
Evaporation Rate & Reference:UNK
Solubility in Water:NEGLIGIBLE

Stability Indicator/Materials to Avoid:YES
EASILY OXIDIZABLE MATERIALS.
Hazardous Decomposition Products:OXIDES OF CARBON AND NITROGEN,
MANGANESE COMPOUNDS.

Waste Disposal Methods:NOT A HAZARDOUS WASTE ACCORDING TO EPA
REGULATIONS. CONSULT STATE REGULATIONS PRIOR TO DISPOSAL OF
SPILLAGE.

Disclaimer (provided with this information by the compiling agencies):
This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.