Product ID:DIPHENYLCARBAZONE-BROMOPHENOL BLUE INDICATO
MSDS Date:10/21/1987
FSC:6810
NIIN:00N022470
MSDS Number: BLSKY

MALLINCKRODT

PARIS, KY 40361
US

Emergency Phone: 314-982-5000

Info Phone: 314-982-5000

Cage: ZA916

MALLINCKRODT SPECIALTY CHEMICALS CO

PHILLIPSBURG, NJ 08865 US

Telephone: 908-859-2151

Cage: 62910

ISOPROPYL ALCOHOL (SARA III)

CAS: 67-63-0

RTECS: NT8050000

OSHA PEL 400 PPM/500 STEL

ACGIH TLV: 400 PPM/500STEL;9192

RECLAIMATION WHEN POSS. LARGER SPILLS & LOT

RTECS: 9999999ZZ

RCRA APPRVD COMBUST CHAMBER/ABSORBED W/VERMICULITE,

RTECS: 9999999ZZ

FROM HEAT, SPKS & FLAME. KEEP CNTNR CLSD. USE

RTECS: 9999999ZZ

BECAUSE IT CAN CONTROL EMISSIONS OF CONTAM @ ITS

RTECS: 9999999ZZ

PLEASE REFER TO ACGIH DOCUMENT, "INDUS VENT, MANUAL

RTECS: 9999999ZZ

QUICK-DRENCH FACILITIES IN WORK AREA.

RTECS: 9999999ZZ

LD50 LC50 Mixture:LD50:ORAL(RAT)5840 MG/KG.
Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:NO IARC:NO OSHA:NO
Health Hazards Acute and Chronic:ACUTE:INHAL:MAY CAUSE IRRIT OF NOSE &
THROAT. EXPOS TO HIGH CONC HAS NARC EFT, PRODUCING SYMPS OF DROW,
HDCH, STAG, UNCON & POSS DEATH. INGEST:MAY CAUSE DROW, UNCON &
DEATH. GI PAIN, CRAMPS, NAUS, VOM IT & DIARR MAY ALSO RESULT.
SINGLE LETHAL DOSE FOR HUMAN ADULT = ABOUT 250 MLS. SKIN
CONTACT:HAS DEFAT (EFTS OF OVEREXP)
Explanation of Carcinogenicity:NOT RELEVANT
Effects of Overexposure:HLTH HAZ:ACTION THAT CAN CAUSE IRRIT. MAY CAUSE
IRRIT W/STINGING EFT & BURNING SENSATION. EYE CONTACT:VAPS MAY
IRRITATE EYES. SPLASHES MAY CAUSE SEVERE IRRIT, POSS CORNEAL BURNS
& EYE DMG. CHRONIC:PRL NG CONTACT W/SKIN MAY CAUSE MILD
IRRIT,DRYING, CRACKING/CONTACT DERM MAY DEVELOP.
Medical Cond Aggravated by Exposure:PERSONS W/PRE-EXISTING SKIN
DISORDERS OR EYE PROBLEMS OR IMPAIRED RESPIRATORY FUNCTION MAY BE
MORE SUSCEPTIBLE TO EFTS OF SUBSTANCE.

First Aid:INHAL:REMOVE TO FRESH AIR. IF NOT BRTHG, GIVE ARTF RESP. IF
BRTHG IS DFCLT, GIVE O*2. CALL MD. INGEST:GIVE H*2O TO DRINK.
INDUCE VOMIT IF MED HELP IS NOT IMMED AVAIL. NEVER GIVE ANYTHING BY
MOUTH TO U NCON PERS. GET MD IMMED. SKIN:REMOVE ANY CONTAM CLTHG.
WASH W/SOAP OR MILD DETERGENT & H*2O FOR @ LST 15 MIN. GET MD IF
IRRIT DEVELOPS/PERSISTS. EYE:WASH W/PLENTY OF H*2O FOR @ LST 15
MIN, (SUPP DATA)

Flash Point Method:CC
Flash Point:53.6F,12.0C
Lower Limits:2%
Upper Limits:12%
Extinguishing Media:WATER SPRAY, DRY CHEMICAL, ALCOHOL FOAM OR CO*2.
WATER SPRAY MAY BE USED TO KEEP FIRE EXPOSED CONTAINERS COOL.
Fire Fighting Procedures:WEAR NIOSH/MSHA APPRVD PRESS DEMAND SCBA &
FULL PROT EQUIP . H*2O MAY BE USED TO FLUSH SPILLS AWAY FROM EXPOS
& TO DILUTE SPILLS TO NON-FLAMM (SUPP DATA)
Unusual Fire/Explosion Hazard:ABOVE FLASH POINT, VAP-AIR MIXTS ARE
EXPLO W/IN FLAMM LIMITS NOTED. CONTACT W/STRONG OXIDIZERS MAY CAUSE
FIRE OF EXPLOSION.

Spill Release Procedures:REMOVE ALL SOURCES OF IGNIT. VENT AREA OF
LEAK/SPILL. CLEAN-UP PERS REQ PROT CLTHG & RESP PROT FROM VAPS. SM
SPILLS MAY BE ABSORBED ON PAPER TOWELS & EVAP IN FUME HOOD. ALLOW
ENOUGH TIME FOR FUMES TO CLEAR HOOD. CONTAIN & RECOVER LIQ FOR
(SEE ING 2)
Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER.

Handling and Storage Precautions:PROTECT AGAINST PHYSICAL DMG. STORE IN
COOL, DRY WELL-VENTED LOCATION, AWAY FROM ANY AREA WHERE FIRE HAZ
MAY BE ACUTE. OUTSIDE/DETACHED STOR IS PREF.
Other Precautions:SEPARATE FROM OXIDIZING MATLS. CNTNRS SHOULD BE
BONDED & GROUNDED FOR TRANSFERS TO AVOID STATIC SPKS. STOR & USE
AREAS SHOULD BE NO SMOKING AREAS. USE NON-SPKING TYPE TOOLS &
EQUIP. FLAMM LIQ, HARMFUL IF SWALLOWED/INHALED. KEEP AWAY (ING 4)

Respiratory Protection:IF TLV IS EXCEEDED A NIOSH/MSHA APPRVD FULL
FACEPIECE CHEM CARTRIDGE RESP MAY BE WORN, IN GEN, UP TO MAX USE
CONC SPECIFIED BY RESP SUPPLIER. ALTERNATIVELY, A NIOSH/MSHA APPRVD
SUPPLIED AIR FULL FACEP IECE RESP/AIRLINED HOOD MAY BE WORN.
Ventilation:LOC &/OR GEN EXHST IF RECOM TO KEEP EMPLOYEE EXPOS BELOW
AIRBORNE EXPOS LIMITS. LOC EXHST VENT IS GENERALLY PREF (ING 5)
Protective Gloves:IMPERVIOUS GLOVES.
Eye Protection:CHEM WORK GOGG/FULL LENGTH FCSHLD.
Other Protective Equipment:WEAR IMPERVIOUS PROT CLTHG, INCL BOOTS, LAB
COAT, APRON/COVERALLS TO PVNT SKIN CNTCT. MAINT EYE WASH FOUNTAIN &
(ING 7)
Work Hygienic Practices:WASH THOROUGHLY AFTER HANDLING. CONTACT LENSES
SHOULD NOT BE WORN WHEN WORKING W/THIS MATERIAL.
Supplemental Safety and Health
FIRE FIGHT PROC:MIXTS. VAPS CAN FLOW ALONG SURFS TO DIST IGNIT SOURCE &
FLASH BACK. MATLS TO AVOID:SULFURIC ACID COMBINATION, POTASSIUM
TERT-BUTOXIDE, HYPOCHLOROUS ACID, ISOCYANATES, NITROFORM, PHOSGE
NE, OLEUM & PERCHLORIC ACID. FIRST AID PROC:LIFTING LOWER & UPPER
EYELIDS OCCAS. GET MD IMMED.

Boiling Pt:B.P. Text:180F,82C
Melt/Freeze Pt:M.P/F.P Text:-128F,-89C
Vapor Pres:33 @ 20C
Vapor Density:2.1
Spec Gravity:0.79
Solubility in Water:INFINITELY SOLUBLE
Appearance and Odor:CLEAR, REDDISH PURPLE SOLUTION.

Stability Indicator/Materials to Avoid:YES
STRONG OXIDIZERS, ACETALDEHYDE, CHLORINE, ETHYLENE OXIDE,
HYDROGEN-PALLADIUM COMBINATION, HYDROGEN PEROXIDE- (SUPP DATA)
Stability Condition to Avoid:HEAT, FLAME & SUNLIGHT CAN CONTRIBUTE TO
INSTABILITY.
Hazardous Decomposition Products:TOXIC GASES & VAPORS SUCH AS CO MAY BE
RELEASED IN FIRE INVOLVING ISOPROPYL ALCOHOL.

Waste Disposal Methods:DISPOSE AS HAZARDOUS WASTE IN RCRA APPROVED
FACILITY. ENSURE COMPLIANCE W/LOCAL, STATE & FEDERAL REGULATIONS.

Disclaimer (provided with this information by the compiling agencies):
This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.