Product ID:D-111, ACTIVATOR #159 FOR ACRA-CLAD
MSDS Date:01/15/1987
FSC:8030
NIIN:00N030318
MSDS Number: BNQPQ

BRINER PAINT MFG CO INC

3713 AGNES
CORPUS CHRISTI, TX 78405-3097
US

Emergency Phone: 512-884-4804

Info Phone: 512-884-4804

Preparer: P.D. ZIEGLER

Cage: 97341

BRINER PAINT MFG CO INC

CORPUS CHRISTI, TX 78405 US

Telephone: 512-884-4804

Cage: 97341

IRRIT & POSS CORR

RTECS: 9999999ZZ

MAY CAUSE ASPIR OF SOLV RSLTG IN CHEM PNEUM.

RTECS: 9999999ZZ

FLUSH W/CLEAN,

RTECS: 9999999ZZ

MED SUPERVISION OF ALL

RTECS: 9999999ZZ

RECOM. THIS SHOULD INCL PREEMPLOYMENT & PERIODIC MED

RTECS: 9999999ZZ

MINIMUM). PERSONS W/ASTHMATIC-TYPE CNDTNS, CHRONIC

RTECS: 9999999ZZ

ECZEMA/SENSIT SHOULD BE EXCLUDED FROM WORK

RTECS: 9999999ZZ

ISOCYANATE, NO FURTHER EXPOSURE CAN BE PERMITTED.

RTECS: 9999999ZZ

SOLN OVER SPILL AREA & ALLOW TO REACT FOR @ LST

RTECS: 9999999ZZ

AMTS OF DECONTAM SOLN. REMOVE CONTRS TO SAFE PLACE,

RTECS: 9999999ZZ

DOWN SPILL AREA W/DECONTAM SOLN. DECONTAM SOLN

RTECS: 9999999ZZ

& H*2O (90-95%). RESP PROT IS RECOM DURING CLEANUP.

RTECS: 9999999ZZ

ISOCYANIC ACID, HEXAMETHYLENE ESTER, POLYMERS; (HOMOPOLYMER

CAS: 28182-81-2

RTECS: NQ9170000

Fraction By Weight: 75%

HEXANE, 1,6-DIISOCYANATO-; (HEXAMETHYLENE DIISOCYANATE)

CAS: 822-06-0

RTECS: MO1740000

EPA Report Quantity: 1 LB

DOT Report Quantity: 1 LB

7.0%

CAS: 1330-20-7

RTECS: ZE2100000

Fraction By Weight: 12.5%

OSHA PEL 100 PPM;150 PPM STEL

ACGIH TLV: 100 PPM;150 PPM STEL

EPA Report Quantity: 1000 LBS

DOT Report Quantity: 1000 LBS

15@20C.

CAS: 123-86-4

RTECS: AF7350000

Fraction By Weight: 12.5%

OSHA PEL 150 PPM;200 PPM STEL

ACGIH TLV: 150 PPM;200 PPM STEL

EPA Report Quantity: 5000 LBS

DOT Report Quantity: 5000 LBS

PREVIOUS RPTD

RTECS: 9999999ZZ

ISOCYANATE SENSIT (CHEM ASTHMA), CHEST TIGHTNESS,

RTECS: 9999999ZZ

DELAYED SEVERAL HRS, & INCR LUNG SENSITIVITY. CHRONIC

RTECS: 9999999ZZ

CHRONIC EXPOS TO ORG SOLV HAS BEEN ASSOC W/NEUROTOX

RTECS: 9999999ZZ

LOSS OF INTELLECTUAL ABILITY, & INCOORD.

RTECS: 9999999ZZ

SOME PERSONS MAY DEVELOP SKIN SENSIT. RPTD/PRLNG CONT

RTECS: 9999999ZZ

INCR SUSCEPTIBILITY TO INFECTION. DERM & RASH & RED.

RTECS: 9999999ZZ

LIQ/AEROSOLS/VAP ARE IRRITATING & CAN CAUSE

RTECS: 9999999ZZ

LD50 LC50 Mixture:LD50:(ORAL,RAT)20 G/KG
Routes of Entry: Inhalation:YES Skin:NO Ingestion:YES
Reports of Carcinogenicity:NTP:NO IARC:NO OSHA:NO
Health Hazards Acute and Chronic:ACUTE: HDI VAP/MIST ABOVE TLV CAN
IRRITATE (BURNING SENSATION) MUC MEMB IN RESP TRACT
(NOSE/THROAT/LUNGS) CAUSING RUNNY NOSE, SORE THROAT, COUGH, CHEST
DISCOMFORT, SHORT OF BRTH & REDUCED LUNG FUNC (B RTHG OBSTRUCTION).
EXPOS ABOVE TLV MAY LEAD TO BRONCH, BRONCHIAL SPASM & PULM EDEMA
(FLUID IN LUNGS). (EFTS OF OVEREXP)
Explanation of Carcinogenicity:NOT RELEVANT
Effects of Overexposure:HLTH HAZ:EFTS ARE USUALLY REVERSIBLE. CHEM/
HYPERSENS PNEUM, W/FLU-LIKE SYMP (FEVER, CHILLS), HAS BEEN RPTD.
BUTYL ACETATE & XYLENE VAP IRRITATE EYES/NOSE/THROAT & RESP TRACT.
200PPM OF EITHER SOLV HA VE CAUSED RED, ITCHY EYES, DRY THROAT
&TIGHTNESS IN CHEST, HDCH, NAUS, NARC, FATG & APPETITE LOSS. DELIB
(SUPP DATA)
Medical Cond Aggravated by Exposure:BRONCHITIS, EMPHYSEMA,
HYPERREACTIVITY, SKIN ALLERGIES, ECZEMA.

First Aid:SKIN:REMOVE CONTAMD CLTHG. WASH AFFECTED AREA THORO
W/SOAP/H2O. WASH CONTAMD CLTHG THORO BEFORE REUSE. INHAL: MOVE TO
AN AREA FREE FROM RISK OF FURTHER EXPOS. ADMINISTER O2/ARTF RESP AS
NEEDED. OBTAIN MED ATTN. ASTHMATIC-TYPE SYMP MAY DEVELOP & MAY BE
IMMED/ DELAYED UP TO SEVERAL HRS. TRTMT IS ESSENTIALLY SYMPTOMATIC.
INGEST:DO NOT INDUCE VOMIT. DO NOT GIVE ANYTHING BY MOUTH TO AN
UNCON (ING 15)

Flash Point Method:PMCC
Flash Point:91.0F,32.8C
Lower Limits:SEE INGRED
Upper Limits:SEE INGRED
Extinguishing Media:DRY CHEM (E.G. MONOAMMONIUM PHOSPHATE, POTASSIUM
SULFATE, & POTASSIUM CHLORIDE), CO2, HIGH EXPANSION (SUPP DATA)
Fire Fighting Procedures:NIOSH/MSHA APPRVD SCBA & FULL PROT EQUIP.
DURING FIRE, HDI VAP& OTHER IRRITATING, HIGHLY TOX GASES MAY BE
GENERATED BY THERMAL DECOMP OR (SUPP DATA)
Unusual Fire/Explosion Hazard:ISOLATE FROM HEAT/ELEC EQUIP/SPARKS &
OPEN FLAME. SOLV VAP MAY BE HVR/AIR. STAGNANT AIR MAY CAUSE VAP TO
BUILD UP & TRAVEL ALONG GROUND TO AN IGNIT (SUPP DATA)

Spill Release Procedures:EVACUATE NONESSENTIAL PERS. REMOVE ALL IGNIT
SOURCE & VENT AREA. DIKE/IMPOUND SPILLED MATL & CTRL FURTHER
SPILLAGE OF FEASIBLE. NOTIFY APPROP AUTH IF NEC. COVER SPILL
W/SAWDUST, VERMICULITE, FULLER'S EARTH/OTHER ABSORB MATL. POUR
DECONTAM (ING 21)
Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER.

Handling and Storage Precautions:KEEP AWAY FROM HEAT/SPARKS/OPEN FLAME.
GROUND CONTR DURING STOR & TRANSFER OPERATIONS. STORE IN TIGHTLY
CLSD CONTR TO PVNT MOISTURE CONTAMINATION.
Other Precautions:DO NOT RESEAL IF CONTAMD. @ MAX STOR TEMP, MATL MAY
SLOWLY POLYMERIZE W/OUT HAZ. IDEAL STOR TEMP RANGE IS 50-81F
(10-27C). AVOID CONT W/SKIN/EYES. DO NOT BREATHE VAPORS.

Respiratory Protection:NIOSH/MSHA APPRVD RESP FOR USE IN ISOCYANATE
CNTNG ENVIRONMENTS (AIR PURIFYING/FRESH AIR SUPPLIED) MAY BE NEC.
CONSIDER TYPE OF APPLICATN & ENVIRONMENTAL CONC. OBSERVE REGS FOR
RESP USE (29 CFR 1910.1 34). FOR MORE SPEC INFO CONT NEHC.
Ventilation:EXHAUST VENT TO KEEP AIRBORNE CONC BELOW TLV'S. EXHAUST AIR
CLEANED BY SCRUBBER/FILTER.
Protective Gloves:CHEMICAL RESISTANT GLOVES.
Eye Protection:CHEM WORK GOG OR FULL LNGTH FSHLD.
Other Protective Equipment:COVER EXPOS SKIN W/APPROP CLTHG. IF SKIN
CREAM USED, KEEP AREA PROTECTED BY SKIN CREAM TO MIN. SFTY SHOWER,
EYEWASH.
Work Hygienic Practices:CONTACT LENSES MUST BE WORN. EDUCATE & TRAIN
EMPLOYEES IN SAFE USE.
Supplemental Safety and Health
EXTING MEDIA: (PROTEINIC) CHEM FOAM/H2O SPRAY FOR LG FIRES. FIRE FIGHT
PROC: COMBUSTION. CLSD CONTR MAY EXPLODE WHEN EXPOS TO EXTREME
HEAT/BURST WHEN CONTAMD W/H2O(CO2 EVOLVED). EXPLO HAZ: SOURCE WHIC
H MAY FLASH BACK TO SOURCE OF VAP. EFTSOF OVEREXP: BRTHG
CONCENTRATED SOLV VAP CAN RSLT IN PERM BRAIN & (ING 5)

HCC:F4
Vapor Pres:SEE INGRED
Spec Gravity:1.06@68F
Solubility in Water:INSOLUBLE
Appearance and Odor:LIQUID, CLEAR/PALE YELLOW, SOLVENT ODOR.
Percent Volatiles by Volume:30

Stability Indicator/Materials to Avoid:YES
H2O, AMINES, STRONG BASES, ALCOHOLS, METAL CMPDS & SURF ACTIVE MATL.
Stability Condition to Avoid:NONE SPECIFIED BY MANUFACTURER.
Hazardous Decomposition Products:BY HIGH HEAT & FIRE: CO2, CO, NOX,
TRACES OF HCN, HDI.
Conditions to Avoid Polymerization:CONT W/MOISTURE OR OTHER MATL WHICH
REACT W/ ISOCYANATES; TEMP OVER 400F.

Waste Disposal Methods:DISPOSE I/A/W FED, ST, & LOC ENVIRONMENTAL CTRL
REGS. INCIN IS PREFERRED METH, EMPTY CONTR MUST BE HNDLD W/CARE DUE
TO PROD RESIDUE & FLAMM SOLV VAP. DECONTAM CONTR PRIOR TO DISP. DO
NOT HEAT/CUT EMPT Y CONTR W/ELEC OR GAS TORCH.

Disclaimer (provided with this information by the compiling agencies):
This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.