Product ID:MIL E 480 BLACK, 210-011
MSDS Date:02/22/1990
FSC:8010
NIIN:00N034863
MSDS Number: BRDPL

D J SIMPSON CO

111 SOUTH MAPLE AVE
SOUTH SAN FRANCISCO, CA 94080
US

Emergency Phone: 800-424-9300(CHEMTREC)

Info Phone: 415-873-5990

Cage: HO834

SIMPSON D J CO INC

2265 SOUTH SAN FRANCISCO, CA 94080-6303 US

Telephone: 415-873-5990

Cage: 33244

4.12 LB/GL (494 G/L)

RTECS: 9999999VO

<0.1% BY WT OF CADMIUM (CAS # 7440-43-9), A NTP

RTECS: 9999999ZZ

CRYSTALLINE SILICA (CAS # 14464-46-1) WHICH HAS

RTECS: 9999999ZZ

TOXIC EFFECT ON THE HUMAN BODY.

RTECS: 9999999ZZ

SYNDROME). TOLUENE, 108-88-3, APPEARS ON NAVY

RTECS: 9999999ZZ

APPROP HLTH PROFESSIONALS CONCERNING LATEST HAZ

RTECS: 9999999ZZ

2 @ 68F.

CAS: 8052-41-3

RTECS: WJ8925000

Fraction By Weight: 5%

OSHA PEL 500 PPM

ACGIH TLV: 100 PPM; 9293

5.1 @ 68F.

CAS: 1330-20-7

RTECS: ZE2100000

Fraction By Weight: 5%

OSHA PEL 100 PPM;150 PPM STEL

ACGIH TLV: 100 PPM;150 PPM STEL

EPA Report Quantity: 1000 LBS

DOT Report Quantity: 1000 LBS

15 @ 100F.

CAS: 8030-30-6

RTECS: DE3030000

Fraction By Weight: 25%

4.4 @ 68F.

CAS: 71-36-3

RTECS: EO1400000

Fraction By Weight: <5%

OSHA PEL 100 PPM

ACGIH TLV: S, C 50 PPM; 9293

EPA Report Quantity: 5000 LBS

DOT Report Quantity: 5000 LBS

22 @ 68F.

CAS: 108-88-3

RTECS: XS5250000

Fraction By Weight: 9%

OSHA PEL 200 PPM/150 STEL

ACGIH TLV: 50 PPM; 9293

EPA Report Quantity: 1000 LBS

DOT Report Quantity: 1000 LBS

38 @ 68F.

CAS: 64742-89-8

Fraction By Weight: <5.0%

LD50 LC50 Mixture:NONE SPECIFIED BY MANUFACTURER.
Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:NO IARC:NO OSHA:NO
Health Hazards Acute and Chronic:ACUTE: INHAL: ANESTHETIC. IRRIT OF
RESP TRACT W/HDCH, NAUS, DIZZ, UNCON/COMA. INGEST OF
PROD/SUBSEQUENT VOMIT CAN RSLT IN ASPIR OF LIGHT HYDROCARBON LIQ
INTO LUNGS WHICH CAN CAUSE FATAL CHEM PNEUM. RP TD & PRLNGD OCCUP
OVEREXP TO SOLV IN PROD MAY LEAD TO PERM BRAIN/NERV SYS DMG (ALSO
KNOWN AS PAINTER'S OR SOLV (ING 11)
Explanation of Carcinogenicity:NOT RELEVANT.
Effects of Overexposure:INHAL: CHRONIC EXPOS TO DUST OF SOLID RAW MATLS
& TO FUMES OF LIQ RAW MATLS MAY CAUSE RESP PROBLEMS. SKIN: IRRIT,
DRYING/CRACKING. EYES: IRRIT/EYE BURN. SKIN ABSORP: SEV
IRRIT/BURNING SENSATION, CRACK ING, DEFAT & DERM MAY OCCUR ON
PRLNGD EXPOS. INGEST: DIZZINESS, NAUSEA. NOT EXPECTED TO HAVE ACUTE
SYS TOX BY INGESTION.
Medical Cond Aggravated by Exposure:PRE-EXISTING HEART, LUNG, KIDNEY,
LIVER, SKIN DISORDERS.

First Aid:INHALATION: REMOVE FROM EXPOSURE, RESTORE BREATHING.
ADMINISTER OXYGEN IF NEEDED. SEEK MEDICAL HELP IMMEDIATELY. EYE:
FLUSH WITH LRG AMTS OF WATER FOR AT LST 15 MINS W/EYELIDS OPEN. SEE
PHYS IMMED. SK IN: WASH WITH SOAP AND WATER. REMOVE CONTAMINATED
CLOTHING. INGESTION: DO NOT INDUCE VOMITING. DRINK ONE OR TWO
GLASSES OF WATER TO DILUTE. SEEK MED HELP IMMED. KEEP PATIENT
QUIET, WARM & COMFORTABLE.

Flash Point Method:TCC
Flash Point:105F,41C
Lower Limits:1%
Upper Limits:11.2%
Extinguishing Media:FOAM, CARBON DIOXIDE, DRY CHEMICAL, WATER FOG.
Fire Fighting Procedures:WEAR NIOSH/MSHA APPRVD SCBA & FULL PROT
EQUIP.FIGHT AS VOLATILE LIQ FIRE.USE WATER TO COOL FIRE EXPOS
CNTNRS.AVOID SPREADING FIRE W/COOLING WATER.(SUPDAT)
Unusual Fire/Explosion Hazard:CLSD CNTNRS MAY EXPLO WHEN EXPOS TO
EXTREME HEAT.VAPS MAY TRAVEL TO SOURCES OF IGNIT & CAUSE FLASH
FIRE.ISOLATE FROM ALL SOURCES OF HEAT.EMPTY CNTNRS (SUPDAT)

Spill Release Procedures:VENTILATE AREA. REMOVE ALL SOURCES OF
IGNITION. CONTAIN AND REMOVE WITH INERT ABSORBENT AND NON-SPARKING
TOOLS. WEAR PROTECTIVE EQUIPMENT DURING CLEANUP. CONTAIN LIQUID TO
PREVENT CONTAMINATION OF SOI L AND GROUND WATER.
Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER.

Handling and Storage Precautions:KEEP CLOSURE TIGHT & CNTNR IN UPRIGHT
POSITION. STORE AWAY FROM HEAT/OTHER SOURCES OF IGNIT. CNTNRS MUST
BE GROUNDED &/OR BONDED DURING LIQ TRANSFER.
Other Precautions:HNDL WHERE VENT IS ADEQ & AWAY FROM SOURCES OF IGNIT.
EMPTIED CNTNR MAY STILL CONTAIN HAZ MATL HENCE IT IS ADVISED TO
OBSERVE MSDS WHEN HNDLG THEM. AVOID PRLNGD BRTHG OF VAPS, SKIN/EYE
CONT, WASH THOR O W/SOAP & WATER.THIS PROD ALSO (SUPDAT)

Respiratory Protection:NIOSH/MSHA APPROVED CHEMICAL MECHANICAL FILTER
RESPIRATOR.
Ventilation:REQUIRED, 200 CFM MINIMUM.
Protective Gloves:PLASTIC OR RUBBER GLOVES.
Eye Protection:CHEMICAL WORKERS GOGGLES .
Other Protective Equipment:EYE WASH AND SAFETY SHOWERS IN WORK AREA
RECOMMENDED. USE PROT HAND CREAMS TO PREVENT DEFATTING OF SKIN UPON
EXPOSURE.
Work Hygienic Practices:WASH WITH SOAP AND WATER, REMOVE CONTAMINATED
CLOTHING BEFORE HANDLING FOOD OR SMOKING. DAILY SHOWERS
RECOMMENDED.
Supplemental Safety and Health
FIRE FIGHT PROC: FOG NOZZ FOR WATER RECOM. EXPLO HAZ: MAY EXPLO DUE TO
RESIDUES. OBSERVE MSDS. ALL METAL CNTNRS MUST BE GROUNDED &/OR
BONDED DURING LIQ TRANSFER. OTHER PREC: CONTAINS <1% WT OF LEAD CM
PDS (CAS # 70084-67-2), ZIRCONIUM CMPDS(CAS # 22464-99-9), ETHANOL
(CAS # 64-17-5), METHANOL (CAS # 67-56-1) & (ING 8)

HCC:F4
Boiling Pt:B.P. Text:>185F,>85C
Vapor Pres:SEE INGS
Vapor Density:HVR/AIR
Spec Gravity:1.0 (H*2O=1)
Evaporation Rate & Reference:SLOWER THAN ETHER
Appearance and Odor:VISCOUS LIQUID WITH DISTINCT SOLVENT ODOR.

Stability Indicator/Materials to Avoid:YES
STRONG OXIDIZING AGENTS, ACIDS AND BASES.
Stability Condition to Avoid:HEAT, ELECTRICAL EQUIPMENT, SPARKS, OPEN
FLAME.
Hazardous Decomposition Products:USUAL PRODUCTS OF COMBUSTION: CARBON
DIOXIDE, CARBON MONOXIDE, OTHER OXIDES, SMOKE, FUMES, ETC.

Waste Disposal Methods:DISPOSE OF IN ACCORDANCE WITH LOCAL, STATE AND
FEDERAL REGULATIONS.

Disclaimer (provided with this information by the compiling agencies):
This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.