Product ID:BELT DRESSING, 50-78-1/13
MSDS Date:03/24/1992
FSC:8030
NIIN:00N045678
MSDS Number: BSJNG

MIDCO PRODUCTS CO INC

11697 FAIRGROVE IND BLVD
MARYLAND HEIGHTS, MO 63043
US

Emergency Phone: 800-235-1765;800-424-9300(CHEMTREC)

Info Phone: 800-235-1765

Cage: 0BTA6

MIDCO PRODUCTS CO INC

MARYLAND HEIGHTS, MO 63043 US

Telephone: 314-567-1710

Cage: 0BTA6

NAVY LISTING OF OCCUP CHEM REPRO HAZS. SEEK

RTECS: 9999999ZZ

HAZARD LIST INFORMATION & SAFE HANDLING & EXPOSURE

RTECS: 9999999ZZ

LUNGS, THORAX ENDOCRINE

RTECS: 9999999ZZ

METHANE, DICHLORO-; (DICHLOROMETHANE) (SARA III)

CAS: 75-09-2

RTECS: PA8050000

Fraction By Weight: 70-80%

OSHA PEL 500 PPM, 1000, C

ACGIH TLV: 50 PPM

EPA Report Quantity: 1000 LBS

DOT Report Quantity: 1000 LBS

TOLUENE (SARA III)

CAS: 108-88-3

RTECS: XS5250000

Fraction By Weight: 10-15%

OSHA PEL 100 PPM; 150 STEL

ACGIH TLV: 50 PPM, S

EPA Report Quantity: 1000 LBS

DOT Report Quantity: 1000 LBS

CARBON DIOXIDE (PROPELLANT)

CAS: 124-38-9

RTECS: FF6400000

OSHA PEL 10000PPM; 30000 STEL

ACGIH TLV: 5000 PPM; 30000 STEL

LIFE-SUSTAINING USES IN HUMANS ACUTELY/CHRONICALLY

RTECS: 9999999ZZ

LD50 LC50 Mixture:NONE SPECIFIED BY MANUFACTURER.
Routes of Entry: Inhalation:YES Skin:NO Ingestion:NO
Reports of Carcinogenicity:NTP:YES IARC:YES OSHA:NO
Health Hazards Acute and Chronic:HLTH HAZS BASED ON COMPONENT
INFO.OVEREXP TO ING 1 CAN RAISE LEVEL OF CO IN BLOOD CAUSING
CARDIOVASCULAR STRESS. RSLTS OF LAB ANIMAL TESTS SHOW ING 1
PRDCD:BENIGN TUMORS IN RATS EXPOS TO 500 PPM; CANC ER IN RATS &
MICE EXPOSED TO 1500 PPM &HIGHER, BUT NOT IN HAMSTERS. IT INCR RATE
OF SPONT OCCURING (EFTS OF OVEREXP)
Explanation of Carcinogenicity:DICHLOROMETHANE:IARC MONOGRAPHS SUPP,
VOL 7, PG 194, 1987:GRP 2B. NTP 6TH ANNUAL REPORT ON CARCINS,
1991:ANTIC TO(ING 7)
Effects of Overexposure:HLTH HAZ:MALIGNANT TUMORS IN THE B6C3F1 MOUSE.
EPIDEMIOLOGY STUDIES FAILED TO SHOW TUMORIGENIC RESPONSE IN PLANT
WORKERS: OVEREXP TO ING 1 APPARENTLY BEEN FOUND TO CAUSE FOLLOWING
EFFTS IN LAB ANIMALS :LIVER ABNORM, LUNG DAM. EYES:MOD TO SEV
IRRIT. SKIN:IRRIT DUE TO DEFAT OF TISS. INGEST:NAUS, HDCH, (SUPDAT)
Medical Cond Aggravated by Exposure:SKIN SENSITIVITY, CHEMICAL
ALLERGIES.

First Aid:EYES:FLUSH WITH LARGE AMTS OF WATER FOR AT LEAST 15 MINUTES &
GET MED ATTN. SKIN:WASH W/SOAP & WATER. REMOVE CONTAMINATED
CLOTHING. INGEST:DO NOT INDUCE VOMIT. GET MEDICAL ATTENTION.
INHAL:REMOVE TO F RESH AIR. GIVE OXYGEN IF BREATHING IS DIFFICULT.
GET MEDICAL ATTENTION.

Flash Point Method:TOC
Extinguishing Media:CO2, STANDARD FOAM, DRY CHEMICAL, HALON.
Fire Fighting Procedures:WEAR NIOSH/MSHA APPROVED PRESSURE DEMAND SCBA
AND FULL PROTECTIVE EQUIPMENT .
Unusual Fire/Explosion Hazard:EXPOS TO TEMP >120F. MAY CAUSE BURSTING/
VENTING. HEAT/FIRE MAY CAUSE HAZ FUMES:CARBON MONOXIDE, PHOSGENE,
CHLORINE & HYDROGEN CHLORIDE. THERMAL DECOMP (SUPDAT)

Spill Release Procedures:MOP UP, SOAK UP IMMEDIATELY. REMOVE OUT OF
DOORS. LGE SPILLS: EVACUATE AREA. CONTAIN LIQUID; TRANSFER TO
CLOSED METAL CONTAINERS. KEEP OUT OF WATER SUPPLY.
Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER.

Handling and Storage Precautions:DO NOT STORE WHERE TEMPERATURES EXCEED
120F. KEEP OUT OF REACH OF CHILDREN.
Other Precautions:NO SMOKING IN AREA OF USE. DO NOT USE IN GENERAL
VICINITY OF ARC WELDING, OPEN FLAMES OR HOT SURFACES. HEAT AND/OR
UV RADIATION MAY CAUSE FORMATION OF HCL AND/OR PHOSGENE .

Respiratory Protection:NIOSH/MSHA APPROVED RESPIRATOR APPROPRIATE FOR
EXPOSURE OF CONCERN .
Ventilation:GENERAL VENT RECOMMENDED TO MAINTAIN LEV OF HAZ INGREDIENTS
TO LESS THAN HALF OF THE TLV.
Protective Gloves:RUBBER GLOVES.
Eye Protection:SAFETY GOGGLES.
Other Protective Equipment:NONE.
Work Hygienic Practices:NONE SPECIFIED BY MANUFACTURER.
Supplemental Safety and Health
EXPLO HAZ:PRODS MAY INCL HCL & PHOSGENE . EFTS OF OVEREXP:VOMIT.
INHAL:NAUS, DIZZ, COORD IMPAIRMENT ON LONG EXPOS. CHLOROCARBON MATL
HAVE PROD SENSIT OF MYOCARDIUM TO EPINEPHRINE IN LAB ANIMALS &
COULD HAVE SIMILAR EFT IN HUMANS. ADRENOMIMETIC (E.G., EPINEPHRINE)
MAY BE CONTRAINDICATED EXCEPT FOR (ING 4)

Vapor Pres:90PSIG@25C
Vapor Density:>1
Spec Gravity:1.21 (H2O=1)
Evaporation Rate & Reference:>1(BUTYL ACETATE=1)
Solubility in Water:INSOLUBLE
Appearance and Odor:AMBER-ETHEREAL ODOR

Stability Indicator/Materials to Avoid:YES
OXIDIZING MATERIALS. POSSIBLY SODIUM, POTASSIUM, & MAGNESIUM.
Stability Condition to Avoid:SOURCES OF HEAT.
Hazardous Decomposition Products:OPEN FLAMES CAN CAUSE THERMAL
DEGRADATION WITH THE EVOLUTION OF HYDROGEN CHLORIDE, PHOSGENE, &
CHLORINE.

Waste Disposal Methods:DISPOSE OF IN MANNER APPROVED BY LOCAL, STATE,
AND FEDERAL REGULATIONS AS WELL AS EPA STANDARDS.

Disclaimer (provided with this information by the compiling agencies):
This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.