Product ID:PHTHALO GREEN PAINT, TY6467
MSDS Date:02/15/1989
FSC:8010
NIIN:00N043182
MSDS Number: BTFYP

DEERE & CO

JOHN DEERE RD
MOLINE, IL 61265
US

Emergency Phone: 309-765-2767; 309-765-4292

Info Phone: 309-765-2767

Cage: 4X159

DEERE AND CO

MOLINE, IL 61265 US

Telephone: 309-765-8000

Cage: 75160

ANTIMONY OXIDE; (ANTIMONY TRIOXIDE) (SARA III)

CAS: 1309-64-4

RTECS: CC5650000

Fraction By Weight: <10%

OSHA PEL 0.5 MG/M3 (SB)

ACGIH TLV: 0.5 MG/M3 (SB)

EPA Report Quantity: 1000 LBS

DOT Report Quantity: 1000 LBS

ALUMINUM SILICATE

CAS: 14504-95-1

Fraction By Weight: <10%

OSHA PEL 5 MG/M3 (AL) (MFR)

ACGIH TLV: 5 MG/M3 (AL) (MFR)

0.05 MG/M3

CAS: 1344-37-2

Fraction By Weight: <5%

OSHA PEL SEE INGREDIENT NAME

ACGIH TLV: SEE INGREDIENT NAME

1); (LEAD CHROMATE)

CAS: 7758-97-6

RTECS: GB2975000

Fraction By Weight: <5%

OSHA PEL 0.05 MG/M3 (MFR)

ACGIH TLV: 0.05 MG/M3 (MFR)

1) (SARA III)

CAS: 7446-14-2

RTECS: OG4375000

Fraction By Weight: <5%

OSHA PEL 0.05 MG/M3 (MFR)

ACGIH TLV: 0.05 MG/M3 (MFR)

EPA Report Quantity: 100 LBS

DOT Report Quantity: 100 LBS

0.7%

CAS: 8052-41-3

RTECS: WJ8925000

Fraction By Weight: <30%

OSHA PEL 100 PPM

ACGIH TLV: 100 PPM

KEROSENE (PETROLEUM), HYDROTREATED; (HYDROTREATED LIGHT

CAS: 64742-47-8

RTECS: OA5504000

Fraction By Weight: <15%

OSHA PEL 100 PPM (MFR)

ACGIH TLV: 100 PPM (MFR)

0.9%

CAS: 8032-32-4

RTECS: OI6180000

Fraction By Weight: <10%

OSHA PEL 300 PPM; 400 STEL

ACGIH TLV: 300 PPM

1.3%

CAS: 108-88-3

RTECS: XS5250000

Fraction By Weight: <5%

OSHA PEL 100 PPM; 150 STEL, S

ACGIH TLV: 50 PPM, S

EPA Report Quantity: 1000 LBS

DOT Report Quantity: 1000 LBS

2.

CAS: 111-15-9

RTECS: KK8225000

Fraction By Weight: <5%

OSHA PEL 100 PPM, S

ACGIH TLV: 5 PPM, S

1.1

CAS: 1330-20-7

RTECS: ZE2100000

Fraction By Weight: <5%

OSHA PEL 100 PPM; 150 STEL

ACGIH TLV: 100 PPM; 150 STEL

EPA Report Quantity: 1000 LBS

DOT Report Quantity: 1000 LBS

0.9%

CAS: 64742-89-8

Fraction By Weight: <5%

OSHA PEL 300 PPM (MFR)

ACGIH TLV: 300 PPM (MFR)

LD50 LC50 Mixture:NONE SPECIFIED BY MANUFACTURER.
Routes of Entry: Inhalation:YES Skin:YES Ingestion:NO
Reports of Carcinogenicity:NTP:YES IARC:YES OSHA:NO
Health Hazards Acute and Chronic:NOTE: TOLUENE (108-88-3) & LEAD APPEAR
ON NAVY LISTING OF OCCUP CHEM REPROD HAZARDS. SEEK CONSULTATION
FROM APPROP HLTH PROFESSIONALS CONCERNING LATEST HAZ LIST INFO &
SAFE HNDLG & EXPOS INFO . INHAL:ANESTH. IRRIT OF RESP TRACT OR
ACUTE NERV SYS DEPRESS CHARACT BY HDCH, DIZZ, STAG GAIT, CONFUSN,
(EFTS OF OVEREXP)
Explanation of Carcinogenicity:LEAD CHROMATE:IARC MONOGRAPHS ON THE
EVALUATION OF CARCINOGENIC RISK OF CHEMS TO MAN, VOL 49, PG 49,
1990: (SUPP DATA)
Effects of Overexposure:HLTH HAZ:UNCON OR COMA. PRLNGD/RPTD OVEREXPOS
TO SOLVS HAS BEEN ASSOC W/CNS, KIDNEY & LIVER DAM. LEAD POISONING
CHARACT BY METALLIC TASTE, LOSS OF APPETITE, INDIGESTION, NAUS,
VOM, CONSTIP, ABDOM CRAM PS, SLEEP DISTURB & WEAK. SKIN/EYE
CONT:IRRIT. MAY CAUSE DERM. RED, PIMPLY ERUPTIONS WHICH CAN RSLT
FROM ANTIMONY.
Medical Cond Aggravated by Exposure:PRE-EXISTING SKIN, EYE, RESPIRATORY
CONDITIONS & CNS DISORDERS MAY BE AGGRAVATED BY EXPOSURE TO THIS
PRODUCT.

First Aid:INHAL:REMOVE FROM EXPOSURE. RESTORE BREATHING. KEEP WARM &
QUIET. EYE:IMMEDIATELY FLUSH W/WATER FOR AT LEAST 15 MINS.
SKIN:WASH W/SOAP & WATER ONLY. INGEST:DO NOT INDUCE VOMITING.
NOTIFY MD IN ALL CAS ES.

Flash Point:45.0F,7.2C
Lower Limits:SEE INGREDS
Extinguishing Media:CARBON DIOXIDE, DRY CHEMICAL OR FOAM.
Fire Fighting Procedures:WEAR NIOSH/MSHA APPROVED SCBA & FULL
PROTECTIVE EQUIPMENT . WATER MAY BE INEFFECTIVE. WATER MAY BE USED
TO KEEP FIRE EXPOSED CHEMICALS COOL.
Unusual Fire/Explosion Hazard:KEEP CONTRS TIGHTLY CLSD. ISOLATE FROM
HEAT, ELEC EQUIP, SPARKS & OPEN FLAME. CLSD CONTRS MAY EXPLODE WHEN
EXPOSED TO EXTREME HEAT. DO NOT APPLY TO HOT SURF.

Spill Release Procedures:REMOVE ALL IGNITION SOURCES. AVOID BREATHING
VAPORS. VENTILATE AREA. CLEAN UP W/INERT ABSORBENT & NON-SPARKING
TOOLS.
Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER.

Handling and Storage Precautions:DO NOT STORE ABOVE 120F. DO NOT EXPOSE
TO DIRECT SUNLIGHT OR OTHER HEAT SOURCE. DO NOT PUNCTURE OR
INCINERATE. CONTRS SHOULD BE GROUNDED WHEN POURING.
Other Precautions:DO NOT FLAME CUT, BRAZE OR WELD PARTS COATED W/PAINT.
DO NOT TAKE INTERNALLY. KEEP AWAY FROM CHILDREN.

Respiratory Protection:NIOSH/MSHA APPROVED RESPIRATOR.
Ventilation:LOCAL EXHAUST TO KEEP TLV, PEL & LEL BELOW ACCEPTABLE
LEVELS.
Protective Gloves:IMPERVIOUS GLOVES .
Eye Protection:ANSI APPR CHEMICAL WORKERS GOGGLES
Other Protective Equipment:NONE SPECIFIED BY MANUFACTURER.
Work Hygienic Practices:NONE SPECIFIED BY MANUFACTURER.
Supplemental Safety and Health
EXPLAN OF CARCIN:GROUP 1. NTP 6TH ANNUAL REPORT ON CARCINOGENS,
1991:KNOWN TO BE CARCINOGENIC. ANTIMONY TRIOXIDE, IARC GROUP 2B

HCC:F3
Vapor Pres:SEE INGRED
Vapor Density:HVR/AIR
Evaporation Rate & Reference:<1 (ETHER=1)
Solubility in Water:NOT APPICABLE
Appearance and Odor:GREEN; SOLVENT ODOR.
Percent Volatiles by Volume:70

Stability Indicator/Materials to Avoid:YES
STRONG OXIDIZING AGENTS.
Stability Condition to Avoid:NONE SPECIFIED BY MANUFACTURER.
Hazardous Decomposition Products:CARBON DIOXIDE, CARBON MONOXIDE,
OXIDES OF ANTIMONY, ALUMINUM, LEAD AND CHROME.

Waste Disposal Methods:IN ACCORDANCE W/LOCAL, STATE & FEDERAL
REGULATIONS.

Disclaimer (provided with this information by the compiling agencies):
This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.