BXGJD - WATER METHANOL 33%
- MSDS: BXGJD
- Manufacturer: ASHLAND CHEMICAL INC
- Product Name: WATER METHANOL 33%
- National Stock Number: 6850-00N058948
Product Identification
Product ID:WATER METHANOL 33%
MSDS Date:12/22/1988
FSC:6850
NIIN:00N058948
MSDS Number: BXGJD
Responsible Party
US
Emergency Phone: 800-274-5263
Info Phone: 614-889-3333
Cage: 34897
Contractor
Telephone: 614-790-3333/800-274-5263
Cage: 34897
Ingredients
147F,
CAS: 67-56-1
RTECS: PC1400000
Fraction By Weight: 33%
OSHA PEL S, 200 PPM
ACGIH TLV: S,200PPM/250STEL; 95
EPA Report Quantity: 5000 LBS
DOT Report Quantity: 5000 LBS
NEVER GIVE ANYTHING BY MOUTH TO AN UNCON
RTECS: 9999999ZZ
METHANOL. METHANOL IS METABOLIZED TO FORMALDEHYDE &
RTECS: 9999999ZZ
ACIDOSIS, VISUAL DISTURB & BLINDNESS. SINCE
RTECS: 9999999ZZ
TO 30 HOURS FOLLOWING INGEST. ETHANOL COMPETES FOR
RTECS: 9999999ZZ
METHANOL IS EFFECTIVELY REMOVED BY HEMODIALYSIS.
RTECS: 9999999ZZ
BRTHG IS DFCLT, ADMIN OXYGEN. IF BRTHG HAS STOPPED
RTECS: 9999999ZZ
OVEREXP TO THIS MATL (/ITS COMPONENTS) HAS
RTECS: 9999999ZZ
SPARKS). PERS NOT WEARING PROT EQUIP SHOULD BE
RTECS: 9999999ZZ
COMPLETED. STOP SPILL AT SOURCE. PVNT FROM ENTERING
RTECS: 9999999ZZ
FROM SPREADING. IF RUNOFF OCCURS, NOTIFY AUTHS AS
RTECS: 9999999ZZ
FOR RECOVERY. ABSORB UNRECOVERABLE PROD. TRANSFER
RTECS: 9999999ZZ
PREVENT RUN-OFF TO SEWERS, STREAMS/OTHER BODIES OF
RTECS: 9999999ZZ
THAT A SPILL HAS OCCURED.
RTECS: 9999999ZZ
ON PROLONGED EXPOSURE TO METHANOL.
RTECS: 9999999ZZ
IMPERVIOUS CLOTHING AND BOOTS.
RTECS: 9999999ZZ
STATE AND FEDERAL REGULATIONS.
RTECS: 9999999ZZ
CONDITIONS (SEE YOUR SAFETY EQUIPMENT SUPPLIER).
RTECS: 9999999ZZ
IMPLEMENTED TO REDUCE EXPOSURE.
RTECS: 9999999ZZ
Hazards
LD50 LC50 Mixture:NONE SPECIFIED BY MANUFACTURER.
Routes of Entry: Inhalation:YES Skin:YES Ingestion:NO
Reports of Carcinogenicity:NTP:NO IARC:NO OSHA:NO
Health Hazards Acute and Chronic:ACUTE:EYES:CAN CAUSE SEVERE
IRRITATION, REDNESS, TEARING, BLURRED VISION. SKIN:PROLONGED OR
REPEATED CONTACT CAN CAUSE MODERATE IRRITATION, DEFATTING,
DERMATITIS. INHAL:EXCESSIVE INHALATION OF VAPORS CAN CAUSE NASAL &
RESPIRATORY IRRITATION, CNS EFFECTS INCLUDING DIZZINESS, WEAKNESS,
FATIGUE, NAUSEA,(EFTS OF OVEREXP)
Explanation of Carcinogenicity:NOT RELEVANT.
Effects of Overexposure:HLTH HAZ:HEADACHE & POSS UNCON, & EVEN DEATH.
INGEST:CAN CAUSE GI IRRIT, NAUSEA, VOMIT, DIARR, BLINDNESS & DEATH.
CHRONIC:OVEREXPOS TO THIS MATL (OR ITS COMPONENTS) HAS APPARENTLY
BEEN FOUND TO CAUSE FOLLOWING EFTS IN LAB ANIMALS:, LIVER ABNORM,
KIDNEY DMG, EYE DMG, LUNG DMG, BRAIN DMG, NERV SYS DMG, SPLEEN
DMG.(ING 8)
Medical Cond Aggravated by Exposure:NONE SPECIFIED BY MANUFACTURER.
First Aid
First Aid:SKIN:THORO WASH EXPOSED AREA W/SOAP & H*2O. REMOVE CONTAM
CLTHG. LAUNDER CONTAM CLTHG BEFORE RE-USE. REMOVE CONTAM SHOES
PROMPTLY. DISCARD SHOES SATURATED W/THIS PROD. EYE:FLUSH W/LARGE
AMT OF H*2O FO R AT LEAST 15 MIN, LIFTING UPPER & LOWER LIDS
OCCASNLY. GET MD ATTN. INGEST:IMMED DRINK TWO GLASSES OF H*2O &
INDUCE VOMIT BY EITHER GIVING IPECAC SYRUP/BY PLACING FINGER AT
BACK OF THROAT. (ING 2)
Fire Fighting
Flash Point:>20.0F,>-6.7C
Lower Limits:6.0%
Extinguishing Media:WATER FOG OR CARBON DIOXIDE OR DRY CHEMICAL.
Fire Fighting Procedures:USE NIOSH/MSHA APPROVED SCBA & FULL PROT EQUIP
.
Unusual Fire/Explosion Hazard:VAPORS ARE HVR/AIR & MAY TRAVEL ALONG
GROUND/MAY BE MOVED BY VENT & IGNITED BY PILOT LIGHTS, OTHER
FLAMES, SPARKS, HEATERS, SMOKING, ELECTRIC MOTORS, (SUPDAT)
Accidental Release
Spill Release Procedures:SMALL:ELIM ALL SOURCES OF IGNITION SUCH AS
FLARES, FLAMES (INCL PILOT LIGHTS), & ELEC SPARKS. ABSORB LIQ ON
VERMICULITE, FLOOR ABSORB,/OTHER ABSORB MATL & TRANSFER TO HOOD.
LRG:ELIM ALL IGNITION SOURC ES (FLARES, FLAMES INCL PILOT LIGHTS,
ELEC (ING 9)
Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER.
Handling
Handling and Storage Precautions:CONTAMINATED ABSORBENT MAY BE
DEPOSITED IN A LANDFILL I/A/W LOCAL, STATE & FEDERAL REGULATIONS.
Other Precautions:CNTNRS OF THIS MATL MAY BE HAZ WHEN EMPTIED SINCE
EMPTIED CNTNRS RETAIN PROD RESIDUES (VAP, LIQ, &/OR SOLID), ALL
HAZARD PRECS GIVEN MUST BE OBSERVED. CNTNS METHANOL. CANNOT BE MADE
NON-POISONOUS. ALU MINUM MAY FORM AN OXIDE SCALE (ING 15)
Exposure Controls
Respiratory Protection:IF WORKPLACE EXPOS LIMIT(S) OF PROD/ANY
COMPONENT IS EXCEEDED, NIOSH/MSHA APPRVD AIR SUPPLIED RESP IS
ADVISED IN ABSENCE OF PROPER ENVIRON CTL. OSHA REGS ALSO PERMIT
OTHER NIOSH/MSHA RESP (NEGATIVE PR ESSURE TYPE) UNDER SPECIFIED
(ING 18)
Ventilation:PROVIDE SUFFICIENT MECHANICAL (GENERAL AND/OR LOCAL
EXHAUST) VENTILATION TO MAINTAIN EXPOSURE BELOW TLV(S).
Protective Gloves:WEAR RESISTANT GLOVES SUCH AS; NEOPRENE.
Eye Protection:ANSI APPRVD CHEM WORKERS GOGGLES .
Other Protective Equipment:EYE WASH FOUNTAIN & DELUGE SHOWER WHICH MEET
ANSI DESIGN CRITERIA . TO PVNT RPTD/PRLNG SKIN CONT, WEAR (ING 16)
Work Hygienic Practices:NONE SPECIFIED BY MANUFACTURER.
Supplemental Safety and Health
EXPLO HAZ:STATIC DISCHARGE,/OTHER IGNIT SOURCES AT LOCATION DISTANT
FROM MATL HNDLG POINT. NEVER USE WELDING/CUTTING TORCH ON/NEAR DRUM
(EVEN EMPTY) BECAUSE PROD (EVEN JUST RESIDUE) CAN IGNITE EXPLOS.
ALL 5 GAL PAILS & LRGR METAL CNTNRS INCLG TANK CARS & TANK TRUCKS
SHOULD BE GROUNDED &/BONDED WHEN MATL IS TRANSFERRED.
Chemical Properties
Boiling Pt:B.P. Text:SEE ING 1
Vapor Pres:SEE ING 1
Vapor Density:HVR/AIR
Spec Gravity:LESS THAN H*2O
Evaporation Rate & Reference:SLOWER THAN ETHER
Appearance and Odor:NONE SPECIFIED BY MANUFACTURER.
Percent Volatiles by Volume:100
Stability
Stability Indicator/Materials to Avoid:YES
AVOID CONTACT WITH: STRONG OXIDIZING AGENTS.
Stability Condition to Avoid:NONE SPECIFIED BY MANUFACTURER.
Hazardous Decomposition Products:MAY FORM TOXIC MATERIALS: CARBON
DIOXIDE AND CARBON MONOXIDE, VARIOUS HYDROCARBONS, ETC.
Disposal
Waste Disposal Methods:SMALL:ALLOW VOLATILE PORTION TO EVAP IN HOOD.
ALLOW SUFFICIENT TIME FOR VAP TO COMPLETELY CLEAR HOOD DUCT WORK.
DISP OF REMAINING MATL I/A/W APPLIC RES. LRG:DESTROY BY LIQ
INCINERATION. CONTAMD ABSORB MAY BE DISPOSITED IN A LANDFILL I/A/W
(ING 17)
Disclaimer (provided with this information by the compiling agencies):
This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.