TCLP, TOXICITY CHARACTERISTICS LEACHATE (SUPP DATA)

MSDS Number

BXGPV

National Stock Number

6810-00N059220

Product Name

TCLP, TOXICITY CHARACTERISTICS LEACHATE (SUPP DATA)

Manufacturer

SPEX INDUSTRIES INC

Product Identification

Product ID:TCLP, TOXICITY CHARACTERISTICS LEACHATE (SUPP DATA)
MSDS Date:04/09/1991
FSC:6810
NIIN:00N059220
MSDS Number: BXGPV

Responsible Party

SPEX INDUSTRIES INC

Emergency Phone: 800-424-9300(CHEMTREC)

Info Phone: 908-549-7144

Cage: 07977

Contractor

SPEX CERTIPREP INC

732-549-7144

Cage: 07977

Ingredients

NITRIC ACID; (HNO*3) (SARA 302/313) (CERCLA) (CONTAINING

CAS: 7697-37-2

RTECS: QU5775000

Fraction By Weight: 2-5%

OSHA PEL2 PPM

ACGIH TLV: 2 PPM;4 STEL

EPA Report Quantity: 1000 LBS

DOT Report Quantity: 1000 LBS

500 PPM.

CAS: 7440-39-3

RTECS: CQ8370000

Fraction By Weight: <0.1%

OSHA PEL0.5 MG/M3

ACGIH TLV: N/K

25 PPM.

CAS: 7440-38-2

RTECS: CG0525000

Fraction By Weight: <0.1%

OSHA PELSEE 1910.1018

ACGIH TLV: 0.01 MG/M3

EPA Report Quantity: 1 LB

DOT Report Quantity: 1 LB

25 PPM.

CAS: 7440-47-3

RTECS: GB4200000

Fraction By Weight: <0.1%

OSHA PEL1 MG/M3

ACGIH TLV: 0.5 MG/M3

EPA Report Quantity: 1 LB

DOT Report Quantity: 1 LB

25 PPM.

CAS: 7439-92-1

RTECS: OF7525000

Fraction By Weight: <0.1%

OSHA PELSEE 1910.1025

ACGIH TLV: 0.15 MG/M3 DUST

EPA Report Quantity: 1 LB

DOT Report Quantity: 1 LB

25 PPM.

CAS: 7440-22-4

RTECS: VW3500000

Fraction By Weight: <0.1%

OSHA PEL0.01 MG/M3

ACGIH TLV: 0.1 MG/M3

EPA Report Quantity: 1 LB

DOT Report Quantity: 1 LB

5 PPM.

CAS: 7440-43-9

RTECS: EU9800000

Fraction By Weight: <0.1%

OSHA PEL0.2 MG/M3 DUST

ACGIH TLV: 0.01 MG/M3 DUST

EPA Report Quantity: 10 LBS

DOT Report Quantity: 10 LBS

5 PPM.

CAS: 7782-49-2

RTECS: VS7700000

Fraction By Weight: <0.1%

OSHA PEL0.2 MG/M3

ACGIH TLV: 0.2 MG/M3

EPA Report Quantity: 1 LB

DOT Report Quantity: 1 LB

WILL CAUSE VIOLENT SPLATTERING.

RTECS: 9999999ZZ

INGEST OF LIQ WILL CAUSE IMMED PAIN & BURNS

RTECS: 9999999ZZ

CAUSING SPASM, INFLAMM & EDEMA OF LARYNX & BRONCHI,

RTECS: 9999999ZZ

SENSATION, COUGH, WHEEZING, LARYNGITIS, SHORTNESS OF

RTECS: 9999999ZZ

NAVY LIST OF OCCUP CHEM REPRO HAZS. SEEK

RTECS: 9999999ZZ

HAZARD LIST INFO & SAFE HANDLING & EXPOSURE INFO .

RTECS: 9999999ZZ

& FULL LENGTH FACESHIELD .

RTECS: 9999999ZZ

EYE WASH IN CASE OF EMERGENCY.

RTECS: 9999999ZZ

Hazards

LD50 LC50 Mixture:NONE SPECIFIED BY MANUFACTURER.
Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:NO IARC:NO OSHA:NO
Health Hazards Acute and Chronic:SYMPS & HLTH HAZS FOR DILUTE NITRIC
ACID ARE EXPECTED TO BE LESS SEV THAN EXPOS TO CONC NITRIC ACID.
HOWEVER, SINCE NITRIC ACID IS IN SOLN AT 1%/GREATER, HLTH HAZS FOR
CONC NITRIC ACID ARE GIVEN. CONC NITRIC ACID MAY BE FATAL IF TOO
MUCH IS INHALED/ABSORBED THRU SKIN. CONC NITRIC ACID VAP/MIST IS
IRRIT(EFTS OF OVEREXP)
Explanation of Carcinogenicity:NOT RELEVANT
Effects of Overexposure:HLTH HAZ:OF EYES, MUC MEMBS & SKIN. IN CONT
W/EYES, IT PRDCES SEV BURNS WHICH MAY RSLT IN PERM DMG & VISUAL
IMPAIRMENT. ON SKIN, LIQ/CONC VAP PRDCES IMMED, SEV & PENETRATING
BURNS; CONC SOLNS CAUSE DE EP ULCERS & STAIN SKIN BRIGHT
YELLOW/YELLOWISH BROWN COLOR. VAP & MIST MAY ERODE EXPOS TEETH
W/PRLNG EXPOS. (ING 10)
Medical Cond Aggravated by Exposure:NONE SPECIFIED BY MANUFACTURER.

First Aid

First Aid:EYES:FLUSH W/WATER FOR AT LEAST 15 MINUTES OCCASIONALLY
LIFTING UPPER & LOWER EYELIDS. SKIN:REMOVE CONTAM CLTHG, THEN FLUSH
W/WATER FOR AT LEAST 15 MINUTES. WASH CLTHG THORO BEFORE REUSE.
INHAL:MOVE T O FRESH AIR. INGEST:DO NOT INDUCE VOMIT. IMMED OBTAIN
MED HELP. SEND TO HOSPITAL. ONLY IF PATIENT CONSCIOUS, GIVE LG QTYS
OF WATER OR MILK. IF IRRIT CONTINUES, GET MED ATTN IMMEDIATELY.

Fire Fighting

Extinguishing Media:APPROPRIATE TO SURROUNDING FIRE CONDITIONS.
Fire Fighting Procedures:USE NIOSH/MSHA APPROVED SCBA & FULL PROTECTIVE
EQUIPMENT .
Unusual Fire/Explosion Hazard:CONC HNO*3 IS NOT COMBUST, BUT IS STRONG
OXIDIZER & ITS HEAT OF RXN W/REDUCING AGENTS/COMBUSTS MAY CAUSE
IGNIT. CAN REACT W/METALS TO RELS FLAMM (SUPP DATA)

Accidental Release

Spill Release Procedures:VENT AREA. DILUTE SPILL W/WATER & NEUT W/SODA
ASH, LIMESTONE, ETC. WIPE UP & PUT INTO SEALED CNTNR FOR PROPER
DISP. WASH SPILL SITE OFF W/WATER AFTER MATL PICK UP IS COMPLETE.
WEAR CHEM RESIST GLASSES , GLOVES & CLTHG. WEAR NIOSH/MSHA APPRVD
RESP.
Neutralizing Agent:SODA ASH, LIMESTONE, ETC.

Handling

Handling and Storage Precautions:CONCENTRATED NITRIC ACID WILL ATTACK
SOME FORMS OF PLASTICS, RUBBER & COATINGS. STORE AT ROOM
TEMPERATURE. KEEP TIGHTLY SEALED WHEN NOT IN USE.
Other Precautions:IRRITANT, OXIDIZER & CORROSIVE LIQUID. AVOID
INHALATION, INGESTION & CONTACT W/EYES & SKIN.

Exposure Controls

Respiratory Protection:WEAR NIOSH/MSHA APPROVED RESPIRATOR.
Ventilation:USE IN A CHEMICAL FUME HOOD.
Protective Gloves:CHEMICAL RESISTANT GLOVES.
Eye Protection:ANSI APPROVED CHEM WORKERS GOGGS(ING 15)
Other Protective Equipment:DELUGE SHOWER WHICH MEETS ANSI DESIGN
CRITERIA . WEAR CHEM RESIST CLTHG. HAVE IMMEDIATE AVAILABILITY OF
AN(ING 16)
Work Hygienic Practices:WASH CAREFULLY AFTER USE.
Supplemental Safety and Health
MFR'S TRADE NAME/PART NO:PROCEDURE STANDARD. EXPLO HAZ:HYDROGEN GAS.
CONC HNO*3 REACTS EXPLOSIVELY W/COMBUST ORG/READILY OXIDIZABLE
MATLS SUCH AS; ALCOHOL, WOOD, TURPENTINE, METAL POWDERS, HYDROGEN
SU LFIDE, ETC. MATLS TO AVOID:ALCOHOL, WOOD, TURPENTINE, METAL
POWDERS, HYDROGEN SULFIDE, ETC. CONT W/STRONG BASES (ING 9)

Chemical Properties

Spec Gravity:1
Solubility in Water:SOLUBLE
Appearance and Odor:TRANSPARENT W/ACRID ODOR.

Stability

Stability Indicator/Materials to Avoid:YES
CONC HNO*3 IS POWERFUL OXIDIZING AGENT. IT REACTS EXPLOSIVELY W/COMBUST
ORG/READILY OXIDIZABLE MATLS SUCH AS; (SUPDAT)
Stability Condition to Avoid:ELEVATED TEMPERATURES MAY CAUSE CONTAINERS
TO BURST & LIBERATE TOXIC OXIDES OF NITROGEN.
Hazardous Decomposition Products:WILL RELEASE TOXIC NITROGEN OXIDE
FUMES & VAPORS.

Disposal

Waste Disposal Methods:DISPOSAL MUST BE I/A/W FEDERAL, STATE & LOCAL
REGULATIONS . CONTACT LOCAL HAZARDOUS OR CHEMICAL WASTE DISPOSAL
AGENCY FOR REGULATIONS.

Disclaimer (provided with this information by the compiling agencies):
This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.