Product ID:CYGON 400 SYSTEMIC INSECTICIDE-MITICIDE
MSDS Date:04/26/1990
FSC:6840
NIIN:00N065929
MSDS Number: BZRQM

AMERICAN CYANAMID

1 CYANAMID PLAZZA
WAYNE, NJ 07470
US

Emergency Phone: 201-835-3100

Info Phone: 201-835-3100

Cage: 06404

AMERICAN CYANAMID CO LEDERLE LABORATORIES DIV

PARSIPPANY, NJ 07054-4404 US

Telephone: 973-683-2000

Cage: 06404

PHOSPHORODITHIOIC ACID, O,O-DIMETHYL ESTER, S-ESTER WITH

CAS: 60-51-5

RTECS: TE1750000

Fraction By Weight: 43.5%

OSHA PEL N/K

ACGIH TLV: N/K

EPA Report Quantity: 10 LBS

DOT Report Quantity: 10 LBS

313F,156C

CAS: 108-94-1

RTECS: GW1050000

Fraction By Weight: 35-40%

OSHA PEL 50 PPM, S

ACGIH TLV: 25 PPM, S

EPA Report Quantity: 5000 LBS

DOT Report Quantity: 5000 LBS

GASOLINE; (PETROLEUM DISTILLATE)

CAS: 8006-61-9

RTECS: LX3300000

Fraction By Weight: 8.5%

OSHA PEL 300 PPM

ACGIH TLV: 300 PPM; 500 STEL

EQUIP AS SPECIFIED. DECONTAM EMER PERS

RTECS: 9999999ZZ

DUSTS, VAPS & FUMES FROM BURNING MATLS. ALERT MED

RTECS: 9999999ZZ

RUN-OFF WATER - IF WATER ENTERS DRAINAGE SYS, ADVISE

RTECS: 9999999ZZ

TO KEEP CNTNRS COOL. FIGHT FIRE FROM MAX DISTANCE.

RTECS: 9999999ZZ

INTAKE FROM TEST GROUP; REDUCTION IN

RTECS: 9999999ZZ

EGG SHELL THICKNESS; & REDUCTION IN BODY WT OF TEST

RTECS: 9999999ZZ

BY INTUBATION. IF SIGNS/SYMPS OF

RTECS: 9999999ZZ

EVERY 10 MIN UNTIL FULLY ATROPINIZED. OBSERVE FOR AT

RTECS: 9999999ZZ

ARE CONTRAINDICATED. PRALIDOXIME CHLORIDE (2 PAM

RTECS: 9999999ZZ

ATROPINE. USE ACCDG TO LABEL DIRECTIONS. BECAUSE OF

RTECS: 9999999ZZ

OF CHLORINATED OR AROMATIC HYDROCARBS, VOMITING

RTECS: 9999999ZZ

COMBUST LIQS. TO PVNT FREEZING, DO NOT STORE

RTECS: 9999999ZZ

LAUNDER CLTHG BEFORE REUSE. ESTABLISH WHOLE

RTECS: 9999999ZZ

PLACES. FOR END-USERS, PLEASE REFER TO PRODUCT

RTECS: 9999999ZZ

LD50 LC50 Mixture:LD50: (ORAL, RAT) 714.6 MG/KG
Routes of Entry: Inhalation:NO Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:NO IARC:YES OSHA:NO
Health Hazards Acute and Chronic:ACUTE: HARMFUL OR FATAL IF SWALLOWED.
CONCENTRATED MATERIAL CAUSES EYE IRRITATION. VAPOR HARMFUL. PROD IS
CONSIDERED MOD TO SLIGHTLY TOX BY INGEST IN SINGLE DOSES & SLIGHTLY
TOX BY SINGLE SKIN APPLICA TNS. CHRONIC TOX: NO TERATOGENIC/FETOTOX
EFTS FOUND AT ALL DOSE LEVELS TESTED IN RATS & RABBITS. IN (EFTS OF
OVEREXP)
Explanation of Carcinogenicity:GASOLINE: IARC MONOGRAPH ON EVALUATION
OF CARCINOGENIC RISK OF CHEMICALS TO MAN, VOL 45, PG 159, 1989:
GROUP 2B.
Effects of Overexposure:HLTH HAZ: SIMILAR STUDY W/CATS THERE WAS INCR
IN OCCURRENCE OF POLYDACTYL @ 12 MG/KG/DAY. NO OBSERVABLE EFT LIM
ESTAB BY STUDY IS 6 MG/KG/DAY. ONE GENERATION REPRO STUDY
W/BOBWHITE QUAIL SHOWED NO CAR CIN LESIONS BUT DID SHOW EFTS FROM
DIMETHOATE:DECR IN SURVIVAL RATE IN FIRST 14 DAYS; REDUCTION OF
FOOD (ING 8)
Medical Cond Aggravated by Exposure:NONE SPECIFIED BY MANUFACTURER.

First Aid:EYES: HOLD LIDS OPEN & FLUSH W/STEADY, GENTLE STREAM OF WATER
FOR AT LEAST 15 MIN. GET MED ATTN. SKIN: WASH IMMED W/PLENTY OF
SOAP & WATER. GET MED ATTN. INGEST: DO NOT INDUCE VOMIT. GET MED
ATTN. INH AL: REMOVE TO FRESH AIR. IF BRTHG IS DFCLT, ADMIN OXYGEN
& SEE MD PROMPTLY. NOTE TO MD: PROD MAY CAUSE CHOLINESTERASE
INHIBITION. ATROPINE IS ANTIDOTAL. IF RECENTLY INGESTED EVACUATE
STOM (ING 10)

Flash Point Method:CC
Flash Point:129F,54C
Extinguishing Media:USE WATER, ALCOHOL FOAM, DRY CHEMICAL OR CARBON
DIOXIDE TO EXTINGUISH FIRES.
Fire Fighting Procedures:USE NIOSH/MSHA APPRVD SCBA & FULL PROT EQUIP.
KEEP UNNEC PEOPLE AWAY. USE AS LITTLE WATER AS POSS. DIKE AREA OF
FIRE TO PVNT PESTICIDE RUN-OFF. (SUPDAT)
Unusual Fire/Explosion Hazard:NONE SPECIFIED BY MANUFACTURER.

Spill Release Procedures:WEAR PROTECTIVE EQUIPMENT. ABSORB SPILL WITH
CLAY OR SAWDUST. SHOVEL INTO METAL CONTAINER FOR DISPOSAL. FLUSH
AREA WITH LIQUID CHLORINE BLEACH AND WATER.
Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER.

Handling and Storage Precautions:DO NOT CONTAM WATER, FOOD/FEED BY
STORAGE/DISP. STORE IN SECURE, DRY, WELL-VENT SEPARATE ROOM,
BLDG/COVERED AREA. NOT FOR USE/STORAGE IN/AROUND HOME.
Other Precautions:KEEP AWAY FROM SOURCES OF IGNIT & PROTECT FROM EXPOS
TO FIRE & HEAT. SEGREGATE FROM OXIDIZERS & INCOMPAT MATLS. BECAUSE
OF MATL'S FL PT, AREAS CONTAINING THIS MATL SHOULD CONFORM TO CODES
SUCH AS NFPA 30 & 70, GOVERNING CLASS II (ING 15)

Respiratory Protection:WEAR A NIOSH/MSHA APPROVED PESTICIDE RESPIRATOR
WHEN EXPOSURE TO VAPOR OR MIST COULD OCCUR.
Ventilation:HANDLE THIS MATERIAL IN A WELL VENTILATED AREA.
Protective Gloves:RUBBER GLOVES.
Eye Protection:ANSI APPRVD CHEM WORKERS GOGGLES .
Other Protective Equipment:ANSI APPROVED EYE WASH & DELUGE SHOWER .
WEAR PROTECTIVE COVERALL CLOTHING TO PREVENT EXPOSURE.
Work Hygienic Practices:WASH THORO W/SOAP & WATER BEFORE EATING &
SMKNG. SHOWER AT END OF EACH WORKING DAY & CHANGE OUTER CLTHG. (ING
16)
Supplemental Safety and Health
PH: 2.6 (3% DISPERSION). FIRE FIGHT PROC: USE SPRAY/FOG - SOLID STREAM
MAY CAUSE SPREADING. CONDUCT FIRE FIGHT & RESCUE OPERATIONS FROM
UPWIND OF FIRE AREA. EVACUATE PEOPLE DOWNWIND WHO MAY COME IN CN
TCT W/SMOKE, FUMES OR CONTAMD SURFS. DONOT DECONTAM PERS/EQUIP OR
HANDLE BROKEN PACKAGES/CNTNRS W/OUT PROT (ING 4)

Boiling Pt:B.P. Text:SEE ING 2
Vapor Pres:26 @ 25C
Vapor Density:4
Spec Gravity:1.1
pH:SUPDAT
Evaporation Rate & Reference:0.13 (BUTYL ACETATE=1)
Solubility in Water:EMULSIFIES
Appearance and Odor:CLEAR, COLORLESS TO LIGHT-YELLOW LIQUID; SLIGHT
MERCAPTAN ODOR.
Percent Volatiles by Volume:50

Stability Indicator/Materials to Avoid:YES
THIS PRODUCT IS UNSTABLE IN ALKALINE MEDIA.
Stability Condition to Avoid:PH <4 AND PH >7. DO NOT STORE AT
TEMPERATURES GREATER THAN 48C (120F) OR LESS THAN 7.2C (45F).
Hazardous Decomposition Products:COMBUSTION MAY PRODUCE OXIDES OF
CARBON, NITROGEN, PHOSPHORUS AND SULFUR.

Waste Disposal Methods:DISPOSE IN ACCORD WITH LOCAL, STATE AND FEDERAL
REGULATIONS.

Disclaimer (provided with this information by the compiling agencies):
This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.