Product ID:FLEXANE FL-20 PRIMER, 15985
MSDS Date:06/15/1990
FSC:8010
NIIN:01-343-4809
MSDS Number: CBQXY

ITW DEVCON

30 ENDICOTT ST
DANVERS, MA 01923
US

Emergency Phone: 800-424-9300 (CHEMTREC)

Info Phone: 508-777-1100

Cage: 0RZG3

ITW DEVCON

DANVERS, MA 01923-3712 US

Telephone: 978-777-1100

Cage: 0RZG3

ISOCYANIC ACID, METHYLENEDI-P-PHENYLENE ESTER; (METHYLENE

CAS: 101-68-8

RTECS: NQ9350000

Fraction By Weight: <2%

OSHA PEL C 0.02 PPM

ACGIH TLV: 0.005 PPM

EPA Report Quantity: 1 LB

DOT Report Quantity: 1 LB

METHYLENE DIPHENYL DIISOCYANATE, POLYPROPYLENE GLYCOL

CAS: 9048-57-1

Fraction By Weight: 1-5%

OSHA PEL N/K

ACGIH TLV: N/K

ETHANE, 1,1,1-TRICHLORO-; (1,1,1-TRICHLOROETHANE) (SARA

CAS: 71-55-6

RTECS: KJ2975000

Fraction By Weight: >60%

OSHA PEL 350 PPM

ACGIH TLV: 350 PPM/450 STEL

EPA Report Quantity: 1000 LBS

DOT Report Quantity: 1000 LBS

P-DIOXANE; (1,4-DIOXANE) (SARA 313) (CERCLA)

CAS: 123-91-1

RTECS: JG8225000

Fraction By Weight: 1-5%

OSHA PEL S, 100 PPM

ACGIH TLV: S, 25 PPM

EPA Report Quantity: 100 LBS

DOT Report Quantity: 100 LBS

0

RTECS: 9999999VO

OSHA PEL N/K

ACGIH TLV: N/K

OF THE MYOCARDIUM TO EPINEPHRINE IN LAB ANIMALS &

RTECS: 9999999ZZ

EPINEPHRINE) MAY BE CONTRAINDICATED EXCEPT FOR

RTECS: 9999999ZZ

TO CHLOROCARBONS

RTECS: 9999999ZZ

VENTILATION IS USUALLY SUFFICIENT.

RTECS: 9999999ZZ

KID, LIV.

RTECS: 9999999ZZ

LD50 LC50 Mixture:LD50:(ORAL,RAT) 10,300 MG/KG
Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:NO IARC:YES OSHA:NO
Health Hazards Acute and Chronic:EYES:SEV IRRIT; MAY CAUSE TRANSIENT
CORNEAL INJURY. SKIN:MAY CAUSE IRRIT;ON PRLNGD CONT, THE SOLV CAN
CAUSE DERM BY DEFAT SKIN. INHAL:HIGH TCA CONC (>1000 PPM) CAN CAUSE
DIZZ & OTHER CNS EFTS; SEE "PR ECAUTIONS", BELOW. INGEST:MAY CAUSE
GASTRIC IRRIT & SYMPS LIKE THOSE OF INHAL; LIQ TCA DRAWN INTO
LUNGS(EFTS OF OVEREXP)
Explanation of Carcinogenicity:P-DIOXANE:IARC MONO, SUPP. VOL 7, PG
201, 1987:GROUP 2B. NTP 7TH ANNUAL RPT ON CARCINS, 1994:ANTIC TO BE
CARCIN.(ING 10)
Effects of Overexposure:HLTH HAZ:CAN CAUSE SEV DMG. CHRONIC:ISOCYANATES
CAN CAUSE RESP AND/OR SKIN SENSIT IN SOME PEOPLE, ESPECIALLY AFTER
PRLNGD/RPTD OVEREXP. CHRONIC OVEREXP TO TCA MAY HARM THE LIVER.
NOTE ON INHAL EFTS:DI ZZ, DROW, & THROAT IRRIT CAN BE CAUSED BY TCA
VAP CONC ABOVE 1000 PPM (1/10 OF 1%). UNCON & DEATH ARE POSS FROM
(SUPDAT)
Medical Cond Aggravated by Exposure:ACUTE AND CHRONIC LIVER DISEASE &
HEART RHYTHM DISORDERS ARE REPORTED AGGRAVATED BY TCA.

First Aid:EYES:FLUSH W/CLEAN WATER FOR @ LEAST 15 MINS WHILE GENTLY
HOLDING EYELIDS OPEN. GET IMMED MED ATTN. SKIN:WASH THORO W/SOAP &
WARM WATER. CONSULT PHYS IF IRRIT DEVELOPS. INHAL:REMOVE PATIENT TO
FRESH A IR; GIVE OXYG IF BRTHG IS DFCLT. GET MED ATTN IF SYMPS
PERSIST. INGEST:GET MED ATTN. DO NOT INDUCE VOMIT; IF PATIENT
VOMITS, KEEP HEAD BELOW HIPS TO PREVENT DRAWING FLUID INTO LUNGS.

Flash Point Method:TCC
Flash Point:NONE
Lower Limits:7.5%
Upper Limits:15%(TCA)
Extinguishing Media:WATER, CO*2, DRY CHEMICAL.
Fire Fighting Procedures:WEAR NIOSH/MSHA APPROVED PRESSURE DEMAND SCBA
& FULL PROTECTIVE EQUIPMENT .
Unusual Fire/Explosion Hazard:THERMAL DECOMPOSITION PRODUCTS MAY
INCLUDE HCL & PHOSGENE . HEAT OF A FIRE CAN CAUSE CLOSED CONTAINERS
TO BURST VIOLENTLY.

Spill Release Procedures:ABSORB SPILL ON INERT MATERIAL SUCH AS
VERMICULITE; TRANSFER TO IMPERVIOUS CONTAINER.
Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER.

Handling and Storage Precautions:ISOCYANATES REACT SLOWLY W/WATER TO
RELEASE CARBON DIOXIDE, & BUILDUP OF GAS PRESS COULD BURST CLSD
CNTNRS. STORE WELL CLSD IN COOL, DRY PLACE.
Other Precautions:NO SMOKING IN AREA OF USE. DO NOT USE IN GEN VICINITY
OF ARC WELDING, OPEN FLAMES OR HOT SURFACES. HEAT &/OR UV RADIA MAY
CAUSE FORMATION OF HCL &/OR PHOSGENE .

Respiratory Protection:NONE REQD IN NORMAL USE W/GOOD VENT. IN CASES OF
USE IN POORLY VENTILATED AREAS AND/OR AT ELEVATED TEMPS A
NIOSH/MSHA APPRVD AIR SUPPLYING RESPIRATOR SHOULD BE WORN.
Ventilation:PROVIDE VENT SUFFICIENT TO KEEP ISOCYANATE VAP BELOW TLV.
LOC EXHAUST IS REC FOR CONFINED AREAS. GENERAL MECH (ING 9)
Protective Gloves:CHEMICAL RESISTANT RUBBER GLOVES.
Eye Protection:ANSI APPRVD CHEM WORK GOGG & FSHLD
Other Protective Equipment:NONE SPECIFIED BY MANUFACTURER.
Work Hygienic Practices:NONE SPECIFIED BY MANUFACTURER.
Supplemental Safety and Health
PH:7 (5% BY WT IN WATER). EFTS OF OVEREXP:EXPOS ABOVE 10,000 PPM. BLOOD
PRESS DEPRESS, CARD SENSIT, & VENTRICULAR ARRHYTHMIA (IRREGULAR
HEARBEAT) CAN RSLT FROM EXPOS TO NEAR-ANESTH LEV. NOTE:THIS FORM
ULATION WAS TESTED IN LONG-TERM ANIMAL STUDIES & DID NOT CAUSE
CANCER. CHLOROCARBON MATLS HAVE PRODUCED SENSIT (ING 6)

Boiling Pt:B.P. Text:165F,74C
Vapor Pres:100 @ 68F
Vapor Density:4.5
Spec Gravity:1.32
pH:SUPDAT
Evaporation Rate & Reference:>1 (BUAC =1)
Solubility in Water:<1%
Appearance and Odor:MOBILE, ORANGE LIQUID WITH ETHER-LIKE SOLVENT ODOR.
Percent Volatiles by Volume:10

Stability Indicator/Materials to Avoid:YES
STRONG BASES, ALCOHOLS. CONTAM W/WATER MAY CAUSE PRESS BUILDUP. DO NOT
STORE IN ALUMINUM.
Stability Condition to Avoid:OPEN FLAMES/HIGH TEMPS, WHICH MAY INDUCE
THERMAL DECOMPOSITION.
Hazardous Decomposition Products:HCL & PHOSGENE . HYDROGEN CHLORIDE,
OXIDES OF CARBON & NITROGEN, TRACES OF PHOSGENE, CHLORINE, HCN.

Waste Disposal Methods:TCA IS A RCRA-LISTED HAZ WASTE. DISPOSE OF AS
HAZARDOUS WASTE IN COMPLIANCE WITH FEDERAL, STATE & LOCAL REGS.
APPLIC CERCLA/RCRA HAZ WASTE CODES:U226 (TCA); U108 (1,4-DIOXANE).
REPORTABLE QTY UNDER CE RCLA, IN POUNDS: 60.

Disclaimer (provided with this information by the compiling agencies):
This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.