Product ID:CUPRIC CARBONATE,BASIC,37 W 2216
MSDS Date:03/01/1993
FSC:6810
NIIN:00-490-4000
MSDS Number: CDYWB

Emergency Phone: 716-226-6177/800-424-9300(CHEMTREC)

Info Phone: 716-359-2502

Preparer: ALEXANDER A. PICCIRILLI

Cage: EO227

Telephone: (716) 359-2502

Cage: 63759

COPPER (II) CARBONATE HYDROXIDE/CUPRIC CARBONATE, BASIC

CAS: 12069-69-1

RTECS: GL6910000

Fraction By Weight: 95% MIN.

LD50 LC50 Mixture:TLV: 0.2 MG/M3 (AS COPPER FUME)
Routes of Entry: Inhalation:YES Skin:NO Ingestion:NO
Reports of Carcinogenicity:NTP:NO IARC:NO OSHA:NO
Health Hazards Acute and Chronic:TARGET ORGANS:EYES, SKIN, RESPIRATORY
& GI TRACTS. ACUTE- INHALE:AIRBORNE DUST IRRITATING TO UPPER
RESPIRATORY TRACT. EYE/SKIN:CAUSES IRRITATION & PAIN. MAY CAUSE
ALLERGIC SKIN REACTION. ORAL:TOXIC. M AY CAUSE GASTRIC PAIN,
DIARRHEA. CHRONIC- UNKNOWN.
Explanation of Carcinogenicity:NONE
Effects of Overexposure:IRRITATION, CHILLS, PAIN, NAUSEA, VOMITING,
METALLIC TASTE, DIARRHEA, REDNESS, ALLERGIC SKIN REACTION
Medical Cond Aggravated by Exposure:PERSONS WITH PRE-EXISTING SKIN
DISORDERS, EYE PROBLEMS, IMPAIRED RESPIRATORY FUNCTION OR PERSONS
WITH WILSON'S DISEASE MAY BE MORE SUSCEPTIBLE TO THE EFFECTS OF
THIS PRODUCT.

First Aid:CALL A DOCTOR IF SYMPTOMS PERSIST. EYE:IMMEDIATELY FLUSH WITH
WATER FOR 15 MINUTES, HOLDING EYELIDS OPEN. SKIN:WASH WITH SOAP &
WATER. INHALED:REMOVE TO FRESH AIR. PROVIDE CPR/OXYGEN IF NEEDED.
ORAL:I F CONSCIOUS, DRINK 1 - 2 GLASSES OF WATER & INDUCE VOMITING.
CALL A PHYSICIAN/POISON CONTROL CENTER IMMEDIATELY.

Flash Point:NOT RELEVANT
Lower Limits:NOT RELEVANT
Upper Limits:NOT RELEVANT
Extinguishing Media:WATER SPRAY, CARBON DIOXIDE, FOAM OR DRY CHEMICAL
FOR SURROUNDING FIRE. USE WATER SPRAY TO COOL FIRE EXPOSED
CONTAINERS.
Fire Fighting Procedures:WEAR PROTECTIVE CLOTHING AND NIOSH-APPROVED
SELF-CONTAINED BREATHING APPARATUS. HAZARDOUS DECOMPOSITION
PRODUCTS MAY BE FORMED. KEEP WATER-RUNOFF FROM STREAMS.
Unusual Fire/Explosion Hazard:MAY EMIT HAZARDOUS MATERIALS.

Spill Release Procedures:SWEEP, SCOOP OR PICK UP. DO NOT RAISE DUST.
PACKAGE FOR RECLAMATION OR RECOVERY. WHATEVER CANNOT BE SAVED FOR
RECLAMATION MAY BE PLACED IN SUITABLE CONTAINER FOR DISPOSAL.
Neutralizing Agent:NOT RELEVANT

Handling and Storage Precautions:STORE MATERIAL IN A DRY, VENTILATED
AREA AWAY FROM ACIDS. KEEP CONTAINER TIGHTLY CLOSED. PROTECT
AGAINST PHYSICAL DAMAGE.
Other Precautions:DO NOT RAISE DUST. AVOID CONTACT WITH EYES AND SKIN.
AVOID BREATHING DUST. WASH THOROUGHLY AFTER HANDLING MATERIAL. KEEP
OUT OF REACH OF CHILDREN.

Respiratory Protection:NONE NORMALLY REQUIRED. IN DUSTY CONDITIONS OR
FOR SYMPTOMS OF OVER EXPOSURE, WEAR NIOSH-APPROVED DUST RESPIRATOR
OR MASK.
Ventilation:USE GENERAL OR LOCAL EXHAUST VENTILATION TO KEEP FUME OR
DUST LEVELS AS LOW AS POSSIBLE.
Protective Gloves:RUBBER/PLASTIC
Eye Protection:DUST-RESISTANT SAFETY GOGGLES
Other Protective Equipment:EYE WASH STATION, EMERGENCY SHOWER,
APPROPRIATE LABORATORY COAT TO COVER EXPOSED SKIN
Work Hygienic Practices:OBSERVE GOOD INDUSTRIAL HYGIENE PRACTICES AND
RECOMMENDED PROCEDURES. WASH THOROUGHLY BEFORE EATING,
DRINKING/SMOKING.
Supplemental Safety and Health

HCC:N1
NRC/State Lic Num:NOT RELEVANT
Boiling Pt:B.P. Text:DECOMPOSES
Melt/Freeze Pt:M.P/F.P Text:DECOMPOSES
Decomp Temp:Decomp Text:392F,200C
Spec Gravity:3.7 - 4.0
Viscosity:NOT RELEVANT
Evaporation Rate & Reference:NOT RELEVANT
Solubility in Water:INSOLUBLE
Appearance and Odor:GREEN TO BLUE AMORPHOUS POWDER - ODORLESS

Stability Indicator/Materials to Avoid:YES
ACIDS
Stability Condition to Avoid:EXCESSIVE HEAT (200C/392F)
Hazardous Decomposition Products:CARBON MONOXIDE, CARBON DIOXIDE

Waste Disposal Methods:DISPOSE OF IN ACCORDANCE WITH LOCAL, STATE AND
FEDERAL REGULATIONS. CONTACT AN APPROVED/LICENSED DISPOSAL AGENCY.

Disclaimer (provided with this information by the compiling agencies):
This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.