Product ID:T BASE F63TL LEAD CUSTOM COLORS, POLANE (SUP DAT)
MSDS Date:11/01/1995
FSC:8010
NIIN:00N087168
MSDS Number: CHGMV

SHERWIN-WILLIAMS CO

101 PROSPECT AVE NW
CLEVELAND, OH 44115
US

Emergency Phone: 216-566-2917

Info Phone: 216-566-2902

Cage: 54636

SHERWIN-WILLIAMS CO THE

CLEVELAND, OH 44115-1042 US

Telephone: 800-251-2486/216-566-2242

Cage: 54636

22.0

CAS: 108-88-3

RTECS: XS5250000

Fraction By Weight: 3-8%

OSHA PEL 200 PPM

ACGIH TLV: 50 PPM, S

EPA Report Quantity: 1000 LBS

DOT Report Quantity: 1000 LBS

5.9

CAS: 1330-20-7

RTECS: ZE2100000

Fraction By Weight: 2-4%

OSHA PEL 100 PPM

ACGIH TLV: 100 PPM/150 STEL

EPA Report Quantity: 1000 LBS

DOT Report Quantity: 1000 LBS

METHYL ETHYL KETONE (2-BUTANONE) (MEK) (SARA 313) (CERCLA)

CAS: 78-93-3

RTECS: EL6475000

Fraction By Weight: 0-23%

OSHA PEL 200 PPM

ACGIH TLV: 200 PPM/300 STEL

EPA Report Quantity: 5000 LBS

DOT Report Quantity: 5000 LBS

2.0

CAS: 108-94-1

RTECS: GW1050000

Fraction By Weight: 10-30%

OSHA PEL 50 PPM, S

ACGIH TLV: 25 PPM, S

EPA Report Quantity: 5000 LBS

DOT Report Quantity: 5000 LBS

10.0

CAS: 123-86-4

RTECS: AF7350000

Fraction By Weight: 5-28%

OSHA PEL 150 PPM

ACGIH TLV: 150 PPM/200 STEL

EPA Report Quantity: 5000 LBS

DOT Report Quantity: 5000 LBS

TALC (POWDER), CONTAINING NO ASBESTOS FIBERS; (TALC)

CAS: 14807-96-6

RTECS: WW2710000

Fraction By Weight: 6-12%

OSHA PEL 20 MPPCF

ACGIH TLV: 2 MG/M3 RDUST

TITANIUM OXIDE; (TITANIUM DIOXIDE)

CAS: 13463-67-7

RTECS: XR2275000

Fraction By Weight: 0-30%

OSHA PEL 15 MG/M3 TDUST

ACGIH TLV: 10 MG/M3 TDUST

C.I. PIGMENT YELLOW 34; (LEAD CHROMATE)

CAS: 1344-37-2

RTECS: GE4599900

Fraction By Weight: <25%

OSHA PEL N/K

ACGIH TLV: N/K

MOLYBDATE ORANGE

CAS: 12656-85-8

RTECS: QA4660000

Fraction By Weight: <25%

OSHA PEL N/K

ACGIH TLV: N/K

4.4-5.4

RTECS: 9999999VO

OSHA PEL N/K

ACGIH TLV: N/K

PRESSURE IN, AND POSSIBLE BURSTING OF

RTECS: 9999999ZZ

SYMPS INCL ABDOM DISCOMFORT/PAIN, CONSTIP,

RTECS: 9999999ZZ

IRRITABILITY, WEAK, MUSC & JOINT PAINS, HDCH &

RTECS: 9999999ZZ

STUDIES HAVE ASSOC EXPOS TO CHROMIUM VI CMPDS

RTECS: 9999999ZZ

LEAD CHROMATE (CHROME YELLOW, MOLYBDATE ORANGE)

RTECS: 9999999ZZ

MAY CAUSE ADVERSE EFTS TO LIVER, URINARY,

RTECS: 9999999ZZ

ISOCYANATES WILL EXPER INCRD ALLERGIC RXN ON RPTD

RTECS: 9999999ZZ

OTHER SOLVS. RATS EXPOSED TO TITANIUM DIOXIDE DUST

RTECS: 9999999ZZ

EXPOS LEVELS ARE NOT ATTAINABLE IN WORKPLACE. RPTS

RTECS: 9999999ZZ

& NERV SYS DMG. TOLUENE & LEAD APPEAR ON THE NAVY

RTECS: 9999999ZZ

APPROP HEALTH PROFESSIONALS CONCERNING LATEST

RTECS: 9999999ZZ

(HOUSEHOLD AMMONIA). AFTER 10 MIN, COLLECT IN

RTECS: 9999999ZZ

WASH SPILL AREA WITH SOAP AND WATER.

RTECS: 9999999ZZ

LD50 LC50 Mixture:NONE SPECIFIED BY MANUFACTURER.
Routes of Entry: Inhalation:YES Skin:YES Ingestion:NO
Reports of Carcinogenicity:NTP:YES IARC:YES OSHA:NO
Health Hazards Acute and Chronic:ACUTE: IRRIT OF EYES, SKIN & RESP SYS.
MAY CAUSE NERV SYS DEPRESS. EXTREME OVEREXP MAY RSLT IN UNCON &
POSS DEATH. CERTAIN COLORS CONTAIN LEAD. ACUTE OCCUP OVEREXP TO
LEAD IS UNCOMMON, BUT RSLTS IN SY MPS SIMILAR TO CHRONIC OVEREXP
DESCRIBED BELOW. SIGNS & SYMPS OF OVEREXP: HDCH, DIZZ, NAUS & LOSS
OF (EFTS OF OVEREXP)
Explanation of Carcinogenicity:MOLYBDATE ORANGE AND LEAD CHROMATE: IARC
GRP 1, VOL 49, P 49, 1990; KNOWN CARCIN, NTP 7TH ANN RPT, 1994.
Effects of Overexposure:HLTH HAZ: COORD ARE INDICATIONS OF EXCESS EXPOS
TO VAPS/SPRAY MISTS. REDNESS & ITCH/BURNING SENSATION MAY INDICATE
EYE/EXCESS SKIN EXPOS. CHRONIC: CERTAIN COLORS CONTAIN LEAD &/OR
CHROMATE. CHRONIC OV EREXP TO LEAD MAY RSLT IN DMG TO
BLOOD-FORMING, NERV, URINARY & REPRO SYS (INCL EMBRYOTOX EFTS).
(ING 12)
Medical Cond Aggravated by Exposure:MAY CAUSE ALLERGIC RESPIRATORY
AND/OR SKIN REACTION IN SUSCEPTIBLE PERSONS OR SENSITIZATION. THIS
EFFECT MAY BE DELAYED SEVERAL HOURS AFTER EXPOSURE.

First Aid:INHALATION: IF ANY BREATHING PROBLEMS OCCUR DURING USE, LEAVE
AREA AND GET FRESH AIR. IF PROBLEMS REMAIN OR OCCUR LATER,
IMMEDIATELY GET MEDICAL ATTENTION. SKIN: WASH AFFECTED AREA
THOROUGHLY WITH SOA P AND WATER. REMOVE CONTAMINATED CLOTHING AND
LAUNDER BEFORE REUSE. EYES: FLUSH WITH LARGE AMOUNTS OF WATER FOR
AT LEAST 15 MINUTES. GET MEDICAL ATTENTION. INGESTION: GET MEDICAL
ATTENTION.

Flash Point:41.0F,5.0C
Lower Limits:0.7%
Upper Limits:13.3%
Extinguishing Media:CARBON DIOXIDE, DRY CHEMICAL, FOAM.
Fire Fighting Procedures:WEAR NIOSH APPRVD SCBA & FULL PROT EQUIP .
WATER SPRAY MAY BE INEFFECTIVE. IF WATER IS USED, FOG NOZZ ARE
PREF. WATER MAY BE USED TO COOL CLSD (SUP DAT)
Unusual Fire/Explosion Hazard:KEEP CONTRS TIGHTLY CLSD. ISOLATE FROM
HEAT, ELEC EQUIP, SPKS, & OPEN FLAMES. CLSD CONTRS MAY EXPLODE WHEN
EXPOSED TO EXTREME HEAT. APPLICATION TO HOT (SUP DAT)

Spill Release Procedures:REMOVE ALL SOURCES OF IGNIT. VENT AREA. FOR
COLORS & REDUCERS: REMOVE W/INERT ABSORB. FOR CATALYSTS: ALL PERS
IN AREA SHOULD BE PROTECTED AS DIRECTED. COVER SPILL W/ABSORB MATL.
DEACTIVATE SPILLED MAT L W/10% AMMONIUM HYDROXIDE SOLN (ING 22)
Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER.

Handling and Storage Precautions:NO PERS W/CHRONIC (LONG-TERM)
LUNG/BRTHG PROBLEMS/IF THEY EVER HAD RXN TO ISOCYANATES, SHOULD USE
THESE PRODS/BE IN AREA WHERE THEY ARE BEING USED.
Other Precautions:KEEP AWAY FROM HEAT, SPKS & OPEN FLAME. DURING USE &
UNTIL ALL VAPS ARE GONE: KEEP AREA VENTD; DO NOT SMOKE; EXTING ALL
FLAMES, PILOT LIGHTS & HEATERS; TURN OFF STOVES, ELEC TOOLS &
APPLIANCES. CONTAC T NEHC FOR MORE SPECIFIC INFO .

Respiratory Protection:WHERE OVERSPRAY IS PRESENT, USE POS PRESS
AIR-SUPP RESP (TC-19C NIOSH APPRVD). IF NOT AVAIL, USE PROPERLY
FITTED NIOSH APPRVD ORG VAP PARTICULATE RESP. FOLLOW RESP MFR'S
DIRECTIONS FOR USE. CONT NEHC FOR MORE SPECIFIC INFO .
Ventilation:LOC EXHST PREF. GEN EXHST ACCEPTABLE IF EXPOS IS MAINT
BELOW APPLIC EXPOS LIMS. REFER TO OSHA STDS 1910.94/107/108.
Protective Gloves:IMPERVIOUS GLOVES .
Eye Protection:ANSI APPRVD CHEM WORKERS GOGGLES .
Other Protective Equipment:EMERGENCY EYEWASH AND DELUGE SHOWER MEETING
ANSI DESIGN CRITERIA .
Work Hygienic Practices:AVOID BRTHG VAP & SPRAY MIST. AVOID CONT W/SKIN
& EYES. WASH HANDS AFTER USING.
Supplemental Safety and Health
TRADE NAME/PART #: B/T POLYURETHANE ENAMEL SYSTEMS. FIRE FIGHT PROC:
CONTRS TO PVNT PRESS BUILD-UP & POSS AUTOIGNIT/EXPLO WHEN EXPOSED
TO EXTREME HEAT. EXPLO HAZ: SURFS REQUIRES SPECIAL PREC. DURING E
MER CNDTNS OVEREXP TO DECOMP PRODS MAY CAUSE HLTH HAZ. SYMPS MAY
NOT BE IMMED APPARENT. OBTAIN MED ATTN.

Boiling Pt:B.P. Text:>174F,>79C
Vapor Pres:SEE INGS
Vapor Density:HVR/AIR
Spec Gravity:0.85-1.40
Evaporation Rate & Reference:SLOWER THAN ETHER
Appearance and Odor:NONE SPECIFIED BY MANUFACTURER
Percent Volatiles by Volume:30-100

Stability Indicator/Materials to Avoid:YES
CONTAM OF CATALYST W/WATER. ALCOHOLS. AMINES & OTHER COMPOUNDS WHICH
REACT W/ISOCYANATES, MAY RSLT IN DANGEROUS (ING 11)
Stability Condition to Avoid:NONE KNOWN.
Hazardous Decomposition Products:BY FIRE: CARBON DIOXIDE & MONOXIDE,
OXIDES OF METALS IN INGS SECTION. OXIDES OF NITROGEN, POSS OF
HYDROGEN CYANIDE.

Waste Disposal Methods:WASTE MAY BE HAZARDOUS AS DEFINED UNDER RCRA 40
CFR 261. WASTE MUST BE TESTED FOR IGNITABILITY TO DETERMINE
APPLICABLE EPA HAZARDOUS WASTE NUMBERS. CONTACT NEHC FOR MORE
SPECIFIC INFORMATION .

Disclaimer (provided with this information by the compiling agencies):
This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.