Product ID:NAPA HEAVY DUTY A/F 374-5, 75547024
MSDS Date:04/02/1995
FSC:9150
NIIN:00N089006
Status Code:A
MSDS Number: CHTMZ

VALVOLINE INC

LEXINGTON, KY 40512
US

Emergency Phone: 800-274-5263

Info Phone: 606-264-7000

Cage: GO029

VALVOLINE OIL CO

14000 LEXINGTON, KY 40512 US

Telephone: 606-357-7206 / 800-274-5263

Cage: 72527

ETHYLENE GLYCOL (SARA 313) (CERCLA)

CAS: 107-21-1

RTECS: KW2975000

Fraction By Weight: 90-95%

OSHA PEL N/K

ACGIH TLV: 50 PPM, VAPOR, C

EPA Report Quantity: 1 LB

DOT Report Quantity: 1 LB

DIETHYLENE GLYCOL

CAS: 111-46-6

RTECS: ID5950000

Fraction By Weight: 1-5%

OSHA PEL N/K

ACGIH TLV: N/K

DIPOTASSIUM PHOSPHATE

CAS: 7758-11-4

OSHA PEL N/K

ACGIH TLV: N/K

WATER

CAS: 7732-18-5

RTECS: ZC0110000

OSHA PEL N/K

ACGIH TLV: N/K

CORROSION INHIBITORS

OSHA PEL N/K

ACGIH TLV: N/K

SILICON SILICATE

RTECS: 9999999ZZ

OSHA PEL N/K

ACGIH TLV: N/K

DEFOAMER

OSHA PEL N/K

ACGIH TLV: N/K

DYE

OSHA PEL N/K

ACGIH TLV: N/K

ETHYLENE OXIDE (SARA 302/313) (CERCLA) (MAY CONTAIN TRACE

CAS: 75-21-8

RTECS: KX2450000

Fraction By Weight: <0.1%

OSHA PEL 1 PPM

ACGIH TLV: 1 PPM

EPA Report Quantity: 10 LBS

DOT Report Quantity: 10 LBS

MAY AGGRAVATE PRE-EXISITING DISORDERS OF THESE

RTECS: 9999999ZZ

DOWN. IF INDIVIDUAL IS CONSCIOUS & ALERT,

RTECS: 9999999ZZ

PLACING TWO FINGERS AT BACK OF THROAT. IF POSS, DO

RTECS: 9999999ZZ

DEVELOP, IMMED MOVE INDIVIDUAL AWAY FROM EXPOS &

RTECS: 9999999ZZ

QUIET. IF NOT BRTHG, BEGIN ARTF RESP. IF BRTHG IS

RTECS: 9999999ZZ

GLYCOL. ETHANOL REDUCES METABOLISM OF ETHYLENE

RTECS: 9999999ZZ

SOON AS POSS IN CASES OF SEV POISONING SINCE

RTECS: 9999999ZZ

CARE WILL BE DELAYED SEVERAL HRS, USE THREE TO FOUR

RTECS: 9999999ZZ

BEFORE/DURING TRANSPORT TO HOSPITAL. HEMODIALYSIS

RTECS: 9999999ZZ

SALVAGE TANK, REMAINING LIQ MAY BE TAKEN UP ON

RTECS: 9999999ZZ

& SHOVELED INTO CNTNRS. PVNT RUN-OFF TO SEWERS,

RTECS: 9999999ZZ

NOTIFY PROPER AUTHORITIES AS REQUIRED, THAT A SPILL

RTECS: 9999999ZZ

CNDTNS (SEE INDUS HYGIENIST). ENGINEERING OR

RTECS: 9999999ZZ

EXPOSURE. IF NEEDED USE A NIOSH APPRVD DUST RESP

RTECS: 9999999ZZ

NEOPRENE, NITRILE RUBBER, POLYVINYL CHLORIDE.

RTECS: 9999999ZZ

ONLY. BEFORE USE, REVIEW MSDS FOR MORE DETAILED

RTECS: 9999999ZZ

LD50 LC50 Mixture:NONE SPECIFIED BY MANUFACTURER.
Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:NO IARC:NO OSHA:NO
Health Hazards Acute and Chronic:EYES: EXPOS MAY CAUSE MILD EYE IRRIT.
SYMPS MAY INCL STINGING, TEARING & REDNESS. SKIN: EXPOS MAY CAUSE
MILD SKIN IRRIT. SYMPS MAY INCL REDNESS & BURNING. INHAL: EXPOS TO
VAP/MIST IS POSS. SYMPS MAY INCL: IRRIT (NOSE, THROAT, RESP
TRACT).INGEST: SINGLE DOSE ORAL TOX IS LOW. SWALLOWING SMALL AMTS
(EFTS OF OVEREXP)
Explanation of Carcinogenicity:NOT RELEVANT
Effects of Overexposure:HLTH HAZ: DURING NORM HNDLG IS NOT LIKELY TO
CAUSE HARMFUL EFTS; SWALLOWING LARGE AMTS MAY BE HARMFUL. SYMPS MAY
INCL: GI IRRIT (NAUS, VOMIT, DIARR). CNS DEPRESS (DIZZ, DROW, WEAK,
FATG, NAUS, HDCH, U NCON). KIDNEY DMG. CHRONIC: THIS MATL (OR
COMPONENT) MAY CAUSE BIRTH DEFECTS IN HUMANS BASED ON POS TEST
RSLTS (SUPDAT)
Medical Cond Aggravated by Exposure:PRE-EXISTING LUNG DISORDERS, EG,
ASTHMA-LIKE CONDITIONS, MAY BE AGGRAVATED BY EXPOSURE TO THIS
MATERIAL & MAY AGGRAVATE PRE-EXISTING KIDNEY DAMAGE, LIVER
ABNORMALITIES, CNS EFFECTS.

First Aid:SKIN: REMOVE CONTAM CLTHG. WASH EXPOS AREA W/SOAP & WATER. IF
SYMPS PERSIST, SEEK MED ATTN. LAUNDER CLTHG BEFORE REUSE. EYES: IF
SYMPS DEVELOP, IMMED MOVE AWAY FROM EXPOS & INTO FRESH AIR. FLUSH
EYES GENTLY W/WATER FOR AT LST 15 MIN WHILE HOLDING LIDS APART;
SEEK IMMED MED ATTN. INGEST: IF SWALLOWED, SEEK MED ATTN. IF
DROWSY/UNCON, DO NOT GIVE ANYTHING BY MOUTH (PLACE ON LEFT SIDE
W/HEAD (ING 11)

Flash Point Method:COC
Flash Point:250F,121C
Lower Limits:3.2%
Extinguishing Media:ALCOHOL FOAM OR CARBON DIOXIDE OR DRY CHEMICAL.
Fire Fighting Procedures:USE NIOSH APPROVED SCBA AND FULL PROTECTIVE
EQUIPMENT . REFER TO THE PERSONAL PROTECTIVE EQUIPMENT SECTION OF
THIS MSDS.
Unusual Fire/Explosion Hazard:NEVER USE WELDING OR CUTTING TORCH ON OR
NEAR DRUM (EVEN EMPTY) BECAUSE PRODUCT (EVEN JUST RESIDUE) CAN
IGNITE EXPLOSIVELY.

Spill Release Procedures:SM SPILL: ABSORB LIQ ON VERMICULITE, FLOOR
ABSORB/OTHER ABSORB MATL. LG SPILL: EXCLUDE PERS NOT WEARING PROT
EQUIP FROM SPILL AREA UNTIL CLEAN-UP HAS BEEN COMPLETED. STOP SPILL
AT SOURCE. DIKE AREA OF SPILL TO PVNT SPREADING. PUMP LIQ TO (ING
19)
Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER.

Handling and Storage Precautions:CNTNRS OF MATL MAY BE HAZ WHEN EMPTY.
SINCE EMPTY CNTNRS RETAIN PROD RESIDUES (VAP, LIQ &/OR SOLID), ALL
HAZ PRECS GIVEN IN MSDS MUST BE OBSERVED.
Other Precautions:AVOID CNTCT W/EYES, SKIN & CLTHG. WASH THOROUGHLY
AFTER HNDLG. WEAR APPROP PROT EQUIP ESSNTL FOR YOUR OPERATION. DO
NOT TRANSFER TO UNLABELED CNTNR. KEEP CNTNR CLSD WHEN NOT IN USE.
KEEP OUT OF REACH OF CHILDREN. FOR INDUSTRIAL USE (ING 25)

Respiratory Protection:IF WORKPLACE EXPOS LIM(S) OF PROD/ANY COMPONENT
IS EXCEEDED, NIOSH APPRVD AIR SUPPLIED RESP IS ADVISED IN ABSENCE
OF PROPER ENVIRONMENTAL CTL. OSHA REGS ALSO PERMIT OTHER NIOSH
APPRVD RESPS (NEG PRESS TYPE) UNDER SPECIFIED (ING 22)
Ventilation:PROVIDE SUFFICIENT MECHANICAL (GENERAL AND/OR LOCAL
EXHAUST) VENTILATION TO MAINTAIN EXPOSURE BELOW TLV(S).
Protective Gloves:RESISTANT GLOVES SUCH AS: (ING 24)
Eye Protection:ANSI APPRVD CHEM WORKERS GOGGLES .
Other Protective Equipment:ANSI APPROVED EYE WASH & DELUGE SHOWER . TO
PREVENT RPTD/PRLNGD SKIN CONTACT, WEAR IMPERVIOUS CLOTHING & BOOTS.
Work Hygienic Practices:NONE SPECIFIED BY MANUFACTURER.
Supplemental Safety and Health
EFTS OF OVEREXP: W/LAB ANIMALS. OVEREXP TO THIS MATL (OR ITS
COMPONENTS) HAS BEEN SUGGESTED AS CAUSE OF FOLLOWING EFTS IN LAB
ANIMALS & MAY AGGRAVATE PRE-EXISTING DISORDERS OF THESE ORGANS IN
HUMANS: KIDNEY DMG. OVEREXP TO THIS MATL (OR ITS COMPONENTS) HAS
BEEN SUGGESTED AS CAUSE OF FOLLOWING EFTS IN HUMANS & (ING 10)

Boiling Pt:B.P. Text:330F,166C
Vapor Pres:18 @ 20C
Vapor Density:HVR/AIR
Spec Gravity:1.128
pH:9-11
Evaporation Rate & Reference:SLOWER THAN ETHER
Appearance and Odor:GREEN LIQUID; FAINT GLYCOL ODOR.
Percent Volatiles by Volume:90-95

Stability Indicator/Materials to Avoid:YES
AVOID CONTACT WITH STRONG OXIDIZING AGENTS.
Stability Condition to Avoid:NONE SPECIFIED BY MANUFACTURER.
Hazardous Decomposition Products:MAY FORM CARBON DIOXIDE AND CARBON
MONOXIDE, VARIOUS HYDROCARBONS, ETC.

Waste Disposal Methods:SMALL SPILL: DISPOSAL OF IN ACCORDANCE WITH ALL
LOCAL, STATE AND FEDERAL REGULATIONS. LARGE SPILL: DISPOSE OF IN
ACCORDANCE WITH ALL APPLICABLE LOCAL, STATE AND FEDERAL
REGULATIONS.

Disclaimer (provided with this information by the compiling agencies):
This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.