Product ID:PLASTIC STEEL 5-MINUTE PUTTY (SF) RESIN, 10240
MSDS Date:12/08/1998
FSC:8030
NIIN:00N039846
Status Code:A
MSDS Number: CJJFG

ITW DEVCON

30 ENDICOTT ST
DANVERS, MA 01923
US

Emergency Phone: 800-424-9300 (CHEMTREC)

Info Phone: 978-777-1100

Cage: 16059

ITW DEVCON

DANVERS, MA 01923-3712 US

Telephone: 978-777-1100

Cage: 0RZG3

CARBON BLACK

CAS: 1333-86-4

RTECS: FF5800000

OSHA PEL 3.5 MG/M3

ACGIH TLV: 3.5 MG/M3

BISPHENOL A EPOXY RESIN; (BISPHENOL A DIGLYCIDYL ETHER

CAS: 25068-38-6

RTECS: CE6880000

OSHA PEL N/K

ACGIH TLV: N/K

LD50 LC50 Mixture:SEE TOXICOLOGICAL INFORMATION.
Routes of Entry: Inhalation:NO Skin:YES Ingestion:NO
Reports of Carcinogenicity:NTP:NO IARC:YES OSHA:NO
Health Hazards Acute and Chronic:SYMPTOMS OF OVEREXPOSURE: SKIN:
MODERATE IRRITANT. CONTACT AT ELEVATED TEMPERATURES CAN CAUSE
THERMAL BURNS. MAY CAUSE SKIN SENSITIZATION (RASHES, HIVES). EYES:
MODERATE IRRITANT. CONTACT AT ELEVATED TEMPERATURES CAN CAUSE
THERMAL BURNS. INHALATION: THE LOW VAPOR PRESSURE OF THE RESIN
MAKES INHALATION UNLIKELY IN NORMAL USE. INGESTION: ACUTE ORAL
TOXICITY IS LOW. MAY CAUSE GASTRIC DISTRESS. CHRONI C OVEREXPOSURE:
PROLONGED OR REPEATED SKIN CONTACT MAY CAUSE SENSITIZATION, WITH
ITCHING, SWELLING, OR RASHES ON LATER EXPOSURE.
Explanation of Carcinogenicity:CARBON BLACK: IARC MONOGRAPHS, VOLUME
65, PAGE 149, 1996: GROUP 2B. ANIMAL: LUNG.
Effects of Overexposure:SEE HEALTH HAZARDS.
Medical Cond Aggravated by Exposure:PREEXISTING EYE AND SKIN DISORDERS.
DEVELOPMENT OF PREEXISTING SKIN OR LUNG ALLERGY SYMPTOMS MAY
INCREASE.

First Aid:EYES: FLUSH W/CLEAN WATER FOR AT LEAST 15 MINUTES WHILE
GENTLY HOLDING EYELIDS OPEN. GET IMMED MEDICAL ATTENTION. SKIN:
IMMEDIATELY REMOVE CONTAMINATED CLOTHING & EXCESS CONTAMINANT.
FLUSH SKIN W/WATE R. WASH THOROUGHLY W/SOAP & WARM WATER. CONSULT
MD IF IRRITATION DEVELOPS. INHAL: REMOVE PATIENT TO FRESH AIR.
ADMINISTER OXYGEN IF BREATHING IS DIFFICULT. GET MEDICAL ATTENTION
IF SYMPTOMS PERSIST. I NGEST: DO NOT INDUCE VOMITING. GIVE TWO
GLASSES OF WATER TO DILUTE IF PATIENT IS CONSCIOUS. GET MEDICAL
ATTENTION. NOTE TO MD: IN GENERAL, EMESIS INDUCTION IS UNNECESSARY
IN HIGH VISCOSITY, LOW VOLATI LITY PRODUCTS, E.G., NEAT EPOXY
RESINS.

Flash Point Method:PMCC
Flash Point:>204.4C, 400.F
Extinguishing Media:CARBON DIOXIDE, DRY CHEMICAL, FOAM.
Fire Fighting Procedures:WEAR NIOSH APPROVED SCBA AND FULL PROTECTIVE
EQUIPMENT . MATERIAL WILL NOT BURN UNLESS PREHEATED. DO NOT ENTER
CONFINED SPACE WITHOUT FULL BUNKER GEAR. COOL FIRE-EXPOSED
CONTAINERS WITH WATER.
Unusual Fire/Explosion Hazard:HEATING ABOVE 300F IN THE PRESENCE OF AIR
MAY CAUSE SLOW OXIDATIVE DECOMPOSITION AND ABOVE 500F MAY CAUSE
POLYMERIZATION. HAZARDOUS PRODUCTS OF COMBUSTION: WHEN HEATED TO
DECOMPOSITION IT EMITS FUMES OF CL-, CARBON MONOXIDE, OTHER FUMES
AND VAPORS VARYING IN COMPOSITION AND TOXICITY.

Spill Release Procedures:AVOID PERSONAL CONTACT. ELIMINATE IGNITION
SOURCES. VENTILATE AREA. DIKE, CONTAIN & ABSORB W/CLAY, SAND/OTHER
SUITABLE MATERIAL. FOR LARGE SPILLS, PUMP TO STORAGE/SALVAGE
VESSELS. SOAK UP RESIDUE W/AB SORBENT SUCH AS CLAY, SAND/OTHER
SUITABLE MATERIAL & DISPOSE OF PROPERLY. FLUSH AREA W/WATER TO
REMOVE TRACE RESIDUE. PREVENT SPILL FROM ENTERING DRAINAGE/SEWER
SYSTEMS, WATERWAYS, & SURFACE WATERS.

Handling and Storage Precautions:AVOID CONTACT WITH SKIN, EYES, OR
CLOTHING. HANDLE MIXED RESIN AND HARDENER IN ACCORDANCE WITH THE
POTENTIAL HAZARD OF THE CURING AGENT USED. STORE IN A COOL, DRY
AREA AWAY FROM HIGH TEMPERATURES AND FLAMES.
Other Precautions:PROVIDE APPROPRIATE VENTILATION/NIOSH APPROVED
RESPIRATORY PROTECTION AGAINST DECOMPOSITION PRODUCTS DURING
WELDING/FLAME CUTTING OPERATIONS AND TO PROTECT AGAINST NUISANCE
DUST DURING SANDING/GRINDIN G OF CURED PRODUCT.

Respiratory Protection:NONE REQUIRED AT NORMAL HANDLING TEMPERATURES
AND CONDITIONS. USE NIOSH APPROVED ORGANIC VAPOR CARTRIDGES FOR
UNCURED RESIN AND NIOSH APPROVED DUST/PARTICLE RESPIRATORS DURING
GRINDING/SANDING OPERATI ONS OF CURED RESIN AS EXPOSURE LEVELS
DICTATE.
Ventilation:LOC EXHAUST VENT IS PREFERRED ALTHOUGH GOOD GEN MECH VENT
IS USUALLY ADEQ FOR MOST INDUS APPLICATIONS. LOC EXHAUST IS
RECOMMENDED FOR CONFINED AREAS.
Protective Gloves:CHEMICAL-RESISTANT GLOVES.
Eye Protection:ANSI APPROVED CHEMICAL WORKERS GOGGLES .
Other Protective Equipment:EYEWASH AND DELUGE SHOWER MEETING ANSI
DESIGN CRITERIA . OTHER GEAR AS REQUIRED TO PREVENT SKIN CONTACT.
Work Hygienic Practices:WASH THORO W/SOAP & WATER AFTER USING & ESP
BEFORE EATING, DRINKING, SMKNG, APPLYING COSMETICS/USING TOILET
FACILITIES. LAUNDER CONTAM CLTHG & PROT GEAR BEFORE REUSE. DISCARD
CONTAM LEATHER ARTICLES.
Supplemental Safety and Health
PHYSICAL/CHEMICAL PROPERTIES: PH (5% SOLUTION OR SLURRY IN WATER):
NEUTRAL; VOC (GRAMS/LITER): 0; PERCENT SOLIDS BY WEIGHT: 100.
CONDITIONS TO AVOID (POLYMERIZATION): GENERATING UNIDENTIFIED FUMES
AND VAPORS WHICH MAY BE TOXIC.

Boiling Pt:>260.C, 500.F
Vapor Pres:0.03 MM HG @ 171F
Vapor Density:>1 (AIR=1)
Spec Gravity:2.8
pH:SUP DAT
Evaporation Rate & Reference:<1 (BUTYL ACETATE=1)
Solubility in Water:NEGLIGIBLE
Appearance and Odor:DARK GRAY PASTE WITH LITTLE ODOR.
Percent Volatiles by Volume:0

Stability Indicator/Materials to Avoid:YES
STRONG LEWIS OR MINERAL ACIDS, STRONG OXIDIZING AGENTS, STRONG MINERAL
AND ORGANIC BASES (ESPECIALLY PRIMARY AND SECONDARY ALIPHATIC
AMINES).
Stability Condition to Avoid:OPEN FLAME AND EXTREME HEAT.
Hazardous Decomposition Products:OXIDES OF CARBON; ALDEHYDES, ACIDS AND
OTHER ORGANIC SUBSTANCES MAY BE FORMED DURING COMBUSTION OR
ELEVATED TEMPERATURE (>500F) DEGRADATION.
Conditions to Avoid Polymerization:HEAT IS GENERATED WHEN RESIN IS
MIXED WITH CURING AGENTS; RUN-A-WAY CURE REACTIONS MAY CHAR &
DECOMPOSE THE RESIN, (SUP DAT)

Waste Disposal Methods:PLEASE SEE ALSO REGULATORY INFORMATION SECTION.
IF THIS RESIN BECOMES A WASTE, IT WOULD NOT BE A HAZARDOUS WASTE BY
RCRA CRITERIA (40 CFR 261). DISPOSE OF ACCORDING TO APPLICABLE
FEDERAL, STATE, AND L OCAL REGULATIONS.

Toxicological Information:ACUTE ORAL EFTS: LD50 (RAT): NOT AVAIL. ACUTE
DERMAL EFTS: LD50 (RABBIT): NOT AVAIL. ACUTE INHAL EFTS: LC50
(RAT): NOT AVAIL. EYE IRRIT: NOT AVAIL. SUBCHRONIC EFTS: NO DATA
AVAIL. CARCINOGENICITY, TER ATOGENICITY, & MUTAGENICITY: BOTH RESIN
& DIGLYCIDYL ETHER OF BISPHENOL A (A COMPONENT OF THIS PROD) HAVE
PROVED TO BE INACTIVE WHEN TESTED BY IN VIVO MUTAGENICITY ASSAYS.
BOTH HAVE SHOWN ACTIVITY BY IN VITRO MICROBIAL MUTAGENICITY
SCREENING & HAVE PRDCED CHROMOSOMAL ABERRATIONS IN CULTURED RAT
LIVER CELLS. OTHER CHRONIC EFTS: 2-YR BIOASSAYS IN MICE EXPOSED BY
DERMAL RTE TO EPON 828, DGEBPA/OTHER COMMERCIAL RESINS YIELDED
(OTHER INFO)

Disclaimer (provided with this information by the compiling agencies):
This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.

Ecological:ECOTOXICITY: NO DATA AVAILABLE. MOBILITY AND PERSISTENCE: NO
DATA AVAILABLE. ENVIRONMENTAL FATE: NO DATA AVAILABLE.

Transport Information:PROPER SHIPPING NAME: NON-REGULATED. TECHNICAL
NAME: N/A. HAZARD CLASS: N/A. UN NUMBER: N/A. PACKING GROUP: N/A.
EMERGENCY RESPONSE GUIDE NUMBER: N/A. IMDG PAGE NUMBER: N/A. OTHER:
N/A.

SARA Title III Information:FOR PURPOSES OF SARA SECTION 312 HAZARDOUS
MATERIALS INVENTORY REPORTING, THE FOLLOWING HAZARD CLASSES APPLY
TO THIS MATERIAL: IMMEDIATE HEALTH HAZARD - DELAYED HEALTH HAZARD.
Federal Regulatory Information:U.S. FED REGS: ALL INGS OF THIS PROD ARE
LISTED/ARE EXEMPT FROM LISTING, ON TSCA INVENTORY. EXPORT
NOTIFICATION IS REQUIRED UNDER TSCA SEC 12B (SEE BELOW). THE
FOLLOWING RCRA CODE(S) APPLIES TO THIS M ATL IF IT BECOMES WASTE:
NONE. REGULATORY STATUS OF HAZ CHEM CONSTITUENTS OF THIS PROD:
CARBON BLACK: EXTREMELY HAZ (*): NO; TOX CHEM (**): NO; CERCLA RQ
(LBS): 0.0; TSCA 12B EXPORT NOTIFICATION: NOT REQUIRED. BISPHENOL
A DIGLYCIDYL ETHER RESIN: EXTREMELY HAZ (*): NO; TOX CHEM (**): NO;
CERCLA RQ (L BS): 0.0; TSCA 12B EXPORT NOTIFICATION: REQUIRED. *
CONSULT APPROP REGS FOR EMER PLANNING & RELEASE REPORTING REQS FOR
(STATE REGS)
State Regulatory Information:FED REGS: SUBSTANCES ON SARA SECTION 301
EXTREMELY HAZ SUBSTANCES LIST. ** SUBSTANCES FOR WHICH "TOX CHEM"
COLUMN IS MARKED "YES" ARE ON SARA SECTION 313 LIST OF TOX CHEMS,
FOR WHICH RELEASE REPORTING MAY BE REQUIRED. FOR SPECIFIC REQS,
CONSULT APPROP REGS. CANADIAN REGS: WHMIS HAZ CLASS(ES): D2B, D2A.
ALL COMPONENTS OF THIS PROD ARE ON THE DOMESTIC SUBSTANCES LIST.