Product ID:PLASTIC STEEL 5-MINUTE PUTTY (SF) HARDENER, 10240
MSDS Date:12/04/1998
FSC:8030
NIIN:00N039846
Status Code:A
Kit Part:Y
MSDS Number: CJJFH

ITW DEVCON

30 ENDICOTT ST
DANVERS, MA 01923
US

Emergency Phone: 800-424-9300 (CHEMTREC)

Info Phone: 978-777-1100

Cage: 16059

ITW DEVCON CORP

DANVERS, MA 01923 US

Telephone: 508-777-1100

Cage: EO352

TRIPOLI; (MICROCRYSTALLINE SILICA)

CAS: 1317-95-9

RTECS: VV7336000

OSHA PEL see Table Z-3

ACGIH TLV: 0.1 MG/M3

QUARTZ; (CRYSTALLINE SILICA)

CAS: 14808-60-7

RTECS: VV7330000

OSHA PEL see Table Z-3

ACGIH TLV: 0.1 MG/M3

2,4,6-TRIS.(.(DIMETHYLAMINO)METHYL.).PHENOL;

CAS: 90-72-2

RTECS: SN3500000

OSHA PEL N/K

ACGIH TLV: N/K

MERCAPTAN AMINE BLEND

OSHA PEL N/K

ACGIH TLV: N/K

LD50 LC50 Mixture:SEE TOXICOLOGICAL INFORMATION.
Routes of Entry: Inhalation:YES Skin:YES Ingestion:NO
Reports of Carcinogenicity:NTP:YES IARC:YES OSHA:NO
Health Hazards Acute and Chronic:ACUTE: SKIN: CAN CAUSE SEVERE
IRRITATION, ESPECIALLY ON PROLONGED CONTACT. POTENTIAL SENSITIZER.
EYES: CAUSES SEVERE IRRITATION WITH POSSIBLE PERMANENT DAMAGE AND
EVEN BLINDNESS. INHALATION: CONSIDERE D SLIGHTLY TOXIC. CAN CAUSE
IRRITATION OF RESPIRATORY TRACT. OVEREXPOSURE TO FUMES OR VAPORS
MAY CAUSE DELAYED LUNG INJURY AND CHEMICAL PNEUMONIA. INGESTION:
SLIGHTLY TOXIC. MAY CAUSE FATIGUE, MUSCLE WEAKNESS,
GASTROINTESTINAL IRRITATION, NAUSEA, VOMITING AND DIARRHEA.
CHRONIC: PROLONGED OR SEVERE OVEREXPOSURE TO DMP VAPOR CAN CAUSE
DELAYED LUNG DAMAGE AND CHEMICAL PNEUMONIA. PROLONGED OR REPEATED
CONTACT MAY CAUSE SKIN SENSITIZATION.
Explanation of Carcinogenicity:SILICA, CRYSTALLINE-QUARTZ/SILICA,
CRYSTALLINE-TRIPOLI: IARC MONOGRAPHS, VOLUME 68, 1997: GROUP 1. NTP
8TH ANNUAL REPORT ON CARCINOGENS, 1998: REASONABLY ANTICIPATED TO
BE HUMAN CARCINOGEN. HUMAN: LUN G.
Effects of Overexposure:SEE HEALTH HAZARDS.
Medical Cond Aggravated by Exposure:MAY AGGRAVATE EXISTING SKIN, EYE,
AND LUNG CONDITIONS.

First Aid:EYES: FLUSH WITH CLEAN WATER FOR AT LEAST 15 MINUTES WHILE
GENTLY HOLDING EYELIDS OPEN. GET IMMEDIATE MEDICAL ATTENTION. SKIN:
REMOVE CONTAMINATED CLOTHING AND SHOES. WASH THOROUGHLY WITH SOAP
AND WAR M WATER. CONSULT A PHYSICIAN IF IRRITATION DEVELOPS.
INHALATION: REMOVE PATIENT TO FRESH AIR. PROVIDE OXYGEN IF
BREATHING IS DIFFICULT. CONSULT A PHYSICIAN IF SYMPTOMS PERSIST.
INGESTION: DO NOT INDUC E VOMITING. GIVE LARGE AMOUNTS OF WATER
FOLLOWED BY MILK IF AVAILABLE. CONSULT A PHYSICIAN.

Flash Point Method:PMCC
Flash Point:>93.3C, 200.F
Extinguishing Media:WATER, CARBON DIOXIDE, DRY CHEMICAL, FOAM.
Fire Fighting Procedures:WEAR NIOSH APPROVED SCBA AND FULL PROTECTIVE
EQUIPMENT . COOL CONTAINERS WITH WATER SPRAY.
Unusual Fire/Explosion Hazard:TOXIC SMOKE AND VAPORS MAY FORM DURING
COMBUSTION. HAZARDOUS PRODUCTS OF COMBUSTION: OXIDES OF CARBON,
OXIDES OF SULFUR, OXIDES OF NITROGEN.

Spill Release Procedures:AVOID PERSONAL CONTACT. ELIMINATE IGNITION
SOURCES. VENTILATE AREA. DIKE, CONTAIN & ABSORB W/CLAY, SAND/OTHER
SUITABLE MATERIAL. FOR LARGE SPILLS, PUMP TO STORAGE/SALVAGE
VESSELS. SOAK UP RESIDUE W/AN ABSORBENT SUCH AS CLAY, SAND/OTHER
SUITABLE MATERIAL & DISPOSE OF PROPERLY. FLUSH AREA W/WATER TO
REMOVE TRACE RESIDUE. PREVENT SPILL FROM ENTERING DRAINAGE/SEWER
SYSTEMS, WATERWAYS & SURFACE WATERS.

Handling and Storage Precautions:AVOID CONTACT WITH SKIN, EYES, OR
CLOTHING. HANDLE MIXED RESIN AND HARDENER IN ACCORDANCE WITH THE
POTENTIAL HAZARD OF THE CURING AGENT USED. STORE IN A COOL, DRY
AREA AWAY FROM HIGH TEMPERATURES AND FLAMES.
Other Precautions:PROVIDE APPROPRIATE VENTILATION/NIOSH APPROVED
RESPIRATORY PROTECTION AGAINST DECOMPOSITION PRODUCTS DURING
WELDING/FLAME CUTTING OPERATIONS AND TO PROTECT AGAINST DUST, WHICH
INCLUDES CRYSTALLINE SIL ICA, DURING SANDING/GRINDING OF CURED
PRODUCT. A TLV OF 0.1 MG/M3 SHOULD BE OBSERVED FOR CRYSTALLINE
SILICA.

Respiratory Protection:NONE NEEDED IN NORMAL USE WITH PROPER
VENTILATION. IN POORLY VENTILATED AREAS OR WHEN CREATING A DUST OR
MIST, USE NIOSH APPROVED ORGANIC VAPOR RESPIRATOR.
Ventilation:GENERAL MECHANICAL VENTILATION IS ADEQUATE FOR OCCASIONAL
USE. FOR PROLONGED OR REPEATED USE, LOCAL EXHAUST IS RECOMMENDED.
Protective Gloves:CHEMICAL-RESISTANT RUBBER GLOVES, SUCH AS NEOPRENE,
BUTYL RUBBER OR NITRILE.
Eye Protection:ANSI APPROVED CHEMICAL WORKERS GOGGLES .
Other Protective Equipment:EYEWASH AND DELUGE SHOWER MEETING ANSI
DESIGN CRITERIA . PROTECTIVE GEAR AS NEEDED TO PREVENT SKIN
CONTACT.
Work Hygienic Practices:WASH THORO W/SOAP & WATER AFTER USING & ESP
BEFORE EATING, DRINKING, SMKNG, APPLYING COSMETICS/USING TOILET
FACILITIES. LAUNDER CONTAM CLTHG & PROT GEAR BEFORE REUSE. DISCARD
CONTAM LEATHER ARTICLES.
Supplemental Safety and Health
PHYSICAL/CHEMICAL PROPERTIES: PH (5% SOLUTION OR SLURRY IN WATER): 9.5;
VOC (GRAMS/LITER): 0; PERCENT SOLIDS BY WEIGHT: 100.

Vapor Pres:<1 MMHG @ 70F
Spec Gravity:1.13
pH:SEE SUP DAT
Solubility in Water:NEGLIGIBLE
Appearance and Odor:VISCOUS, AMBER LIQUID, WITH MERCAPTAN ODOR.
Percent Volatiles by Volume:0

Stability Indicator/Materials to Avoid:YES
STRONG OXIDIZING AGENTS.
Stability Condition to Avoid:OPEN FLAME AND EXTREME HEAT.
Hazardous Decomposition Products:OXIDES OF CARBON, OXIDES OF SULFUR,
OXIDES OF NITROGEN.
Conditions to Avoid Polymerization:WHEN THIS MATERIAL IS MIXED WITH AN
EPOXY RESIN HEAT IS GENERATED; BE CAREFUL WHEN MIXING MORE THAN AN
OUNCE OR SO.

Waste Disposal Methods:PLEASE SEE ALSO REGULATORY INFORMATION SECTION.
IF THIS MATERIAL BECOMES A WASTE, IT WOULD NOT BE A HAZARDOUS WASTE
BY RCRA CRITERIA (40 CFR 261). DISPOSE OF ACCORDING TO APPLICABLE
FEDERAL, STATE, AN D LOCAL REGULATIONS.

Toxicological Information:ACUTE ORAL EFTS: LD50 (RAT): NO DATA AVAIL.
ACUTE DERMAL EFTS: LD50 (RABBIT): NO DATA AVAIL. RABBIT: SEV
IRRITANT. ACUTE INHAL EFTS: LC50 (RAT): NO DATA AVAIL. EYE IRRIT:
RABBIT: SEV IRRITANT. SUBCHRO NIC EFTS/CARCIN, TERATOGENICITY,
MUTAGENICITY/OTHER CHRONIC EFTS: NO DATA. TOX INFO ON HAZ CHEM
CONSTITUENTS: ORAL LD50 (RAT): MICROCRYSTALLINE SILICA/CRYSTALLINE
SILICA/MERCAPTAN AMINE BLEND: N/K; DM P: 1200 MG/KG. DERMAL LD50
(RABBIT): MICROCRYSTALLINE SILICA/CRYSTALLINE SILICA/MERCAPTAN
AMINE BLEND: N/K; DMP: 1350 MG/KG. INHAL LC50 4HR (RAT):
MICROCRYSTALLINE SILICA/CRYSTALLINE SILICA/MERCAPTAN AMINE BLEND:
N/K; DMP: > 0.5 MG/L.

Disclaimer (provided with this information by the compiling agencies):
This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.

Ecological:ECOTOXICITY: NO DATA. MOBILITY AND PERSISTENCE: NO DATA.
ENVIRONMENTAL FATE: NO DATA.

Transport Information:PROPER SHIPPING NAME: NON-REGULATED. TECHNICAL
NAME: N/A. HAZARD CLASS: N/A. UN NUMBER: N/A. PACKING GROUP: N/A.
EMERGENCY RESPONSE GUIDE NUMBER: N/A. IMDG PAGE NUMBER: N/A. OTHER:
N/A.

SARA Title III Information:SARA SECTION 301 EXTREMELY HAZARDOUS
SUBSTANCE LIST: NONE OF THE INGREDIENTS. SARA SECTION 313 TOXIC
CHEMICALS LIST: NONE OF THE INGREDIENTS. FOR PURPOSES OF SARA
SECTION 312 HAZARDOUS MATERIALS INVEN TORY REPORTING, THE FOLLOWING
HAZARD CLASSES APPLY TO THIS MATERIAL: IMMEDIATE HEALTH HAZARD --
DELAYED HEALTH HAZARD.
Federal Regulatory Information:U.S. FEDERAL REGULATIONS: ALL
INGREDIENTS OF THIS PRODUCT ARE LISTED, OR ARE EXEMPT FROM LISTING,
ON THE TSCA INVENTORY. THE FOLLOWING RCRA CODE(S) APPLIES TO THIS
MATERIAL IF IT BECOMES WASTE: NONE. CERCLA RQ (LBS) FOR EACH OF
THE INGREDIENTS: 0.0. TSCA 12B EXPORT NOTIFICATION FOR EACH OF THE
INGREDIENTS: NOT REQUIRED. CANADIAN REGULATIONS: WHMIS HAZARD
CLASS(ES): D2B; D2A. ALL COMPONENTS OF THIS PRODUCT ARE ON THE
DOMESTIC SUBSTANCES LIST.