Product ID:CARNOY'S SOLUTION
MSDS Date:11/03/1992
FSC:NIIN:Submitter:D DG
Status Code:A
MSDS Number: CJZCY

WARD'S NATURAL SCIENCE ESTABLISHMENT INC.

ROCHESTER, NY 14692-9012
US

Emergency Phone: 716-226-6177

Info Phone: 716-359-2502

Preparer: ALEXANDER PICCIRILLI

Cage: EO227

WARDS NATURAL SCIENCE ESTABLISHMENT INC

92912 ROCHESTER, NY 14692-9012 US

Telephone: (716) 359-2502

Cage: 63759

ETHYL ALCOHOL

CAS: 64-17-5

RTECS: KQ6300000

OSHA PEL 1900 MG/M3;1000 PPM

ACGIH TLV: 1880 MG/M3;1000 PPM

CHLOROFORM

CAS: 67-66-3

RTECS: FS9100000

OSHA PEL C240 MG/M3;C50 PPM

ACGIH TLV: 49 MG/M3;10 PPM

EPA Report Quantity: 10 LBS

DOT Report Quantity: 10 LBS

GLACIAL ACETIC ACID

CAS: 64-19-7

RTECS: AF1225000

OSHA PEL 25 MG/M3;10 PPM

ACGIH TLV: 25 MG/M3;10 PPM

EPA Report Quantity: 5000 LBS

DOT Report Quantity: 5000 LBS

Health Hazards Acute and Chronic:INHALATION:PROLONGED EXPOSURE TO HIGH
CONCENTRATIONS OR REPEATED LOW CONCENTRATION CAUSES CNS DEPRESSION
AND MAY RESULT IN LIVER OR KIDNEY AND POSSIBLE CARDIAC
SENSITIZATION. EYES:CONTACT CAUSES IRRIT ATION AND MAY BE PAINFUL.
SKIN:PROLONGED OR REPEATED CONTACT CAUSES DEFATTING OR CRACKING OF
THE SKIN. TO THE BEST OF OUR KNOWLEDGE,THE CHEMICAL MIXTURE'S
PHYSICAL AND TOXICOLOGICAL PROPERTIES HAVE NO T BEEN THOROUGHLY
INVESTIGATED.
Explanation of Carcinogenicity:LAB STUDIES HAVE SHOWN CHLOROFORM, A
COMPONENT OF THIS PRODUCT PRODUCES CANCER IN ANIMALS. HANDLE AS
SUSPECTED CARCINOGEN.CHRONIC EXPOSURE MAY CAUSE EMBRYO-FETAL
INJURY.

First Aid:INHALATION-REMOVE TO FRESH AIR. IF NOT BREATHING, GIVE
ARTIFICIAL RESPIRATION OR IF BREATHING IS DIFFICULT, GIVE OXYGEN BY
TRAINED PERSONNEL. GET IMMEDIATE MEDICAL ATTENTION. EYES-FLUSH
THOROUGHLY WIT H WATER,LIFTING UPPER & LOWER EYELIDS OCCASIONALLY.
GET MEDICAL ATTENTION. SKIN-FLUSH WITH WATER, THEN WASH WITH MILD
SOAP & WATER. INGESTION-IF CONSCIOUS & ABLE TO SWALLOW, HAVE VICTIM
DRINK SEVERAL GLASSES OF WATER. CALL PHYSICIAN OR POISON CONTROL.
INDUCE VOMITING IF ADVISED BY PHYSICIAN.NEVER GIVE ANYTHING BY
MOUTH TO UNCONSCIOUS PERSON.

Flash Point Method:COC
Flash Point:=16.1C, 61.F
ETHYL ALCOHOL
Lower Limits:3%
Upper Limits:15%
Extinguishing Media:WATER SPRAY, CARBON DIOXIDE, DRY CHEMICA L(ABC).
Fire Fighting Procedures:IN FIRE CONDITIONS, WEAR NIOSH-APPROVED,
SELF-CONTAINED BREATHING APPARATUS AND FULL PROTECTIVE CLOTHING.
Unusual Fire/Explosion Hazard:FIRE OR EXCESSIVE HEAT MAY PRODUCE
HAZARDOUS DECOMPOSITION PRODUCTS;CAN REACT VIGOROUSLY WITH
OXIDIZING MATERIALS. NOTE: BURNS WITH CLEAR, ALMOST INVISIBLE
FLAME, ESPECIALLY HARD TO SEE IN STRONG SUNL IGHT.

Spill Release Procedures:WEAR SUITABLE PROTECTIVE CLOTHING AND GOOD
VENTILATION, ABSORB MATERIAL IN VERMICULITE, SAND, GROUND. PLACE IN
SUITABLE CONTAINER FOR INCINERATION.WASH SPILL AREA WITH SOAP AND
WATER.

Handling and Storage Precautions:STORE IN COOL, DRY, WELL-VENTILATED
PLACE, PREFERABLY NOT ABOVE 30C(86F). WASH THOROUGHLY AFTER
HANDLING. AVOID CONTACT WITH SKIN, EYES AND MUCOUS MEMBRANES. KEEP
CONTAINER TIGHTLY CLOSED WHEN NOT IN USE.
Other Precautions:READ LABEL ON CONTAINER BEFORE USING. SO NOT WEAR
CONTACT LENSES WHEN WORKING WITH CHEMICALS. AVOID BREATHING VAPORS.
FOR LABORATORY USE ONLY. NOT FOR DRUG, FOOD OR HOUSEHOLD USE. KEEP
OUT OF REACH OF CHILDREN.

Respiratory Protection:NONE NEEDED IN LABORATORY HANDLING. IF MISTY
CONDITIONS PREVAIL, WORK IN VENTILATION HOOD OR WEAR NIOSH-APPROVED
RESPIRATOR.
Ventilation:LOCAL EXHAUST: RECOMMENDED. MECHANICAL (GENERAL):
RECOMMENDED.
Protective Gloves:RUBBER
Eye Protection:CHEMICAL SAFETY GLASSES
Other Protective Equipment:GOGGLES, FACE SHIELD, LAB COAT ,VENTILATION
HOOD, PROPER GLOVES, FIRE EXTINGUISHER, EYE WASH STATION.
Work Hygienic Practices:WASH THOROUGHLY AFTER HANDLING.
Supplemental Safety and Health
WARD'S P/N: 37W8071

HCC:F3
Boiling Pt:B.P. Text:61-118C
Melt/Freeze Pt:M.P/F.P Text:APPROX -65C
Vapor Pres:10.4CHLOROFORM
Vapor Density:4.12
Spec Gravity:1.0
Evaporation Rate & Reference:>1 (ETHER=1)
Solubility in Water:~70ML
Appearance and Odor:CLEAR,COLORLESS LIQUID;MILD,SWEET,VINEGAR ODOR
Percent Volatiles by Volume:100%

Stability Indicator/Materials to Avoid:YES
EXCESSIVE WATER, STRONG ALKALIES ,OXIDIZING MATERIALS.
Stability Condition to Avoid:OPEN FLAME, EXCESSIVE TEMPERATURE AND
HEAT.
Hazardous Decomposition Products:PHOSGENE, HYDROCHLORIC ACID ,CARBON
DIOXIDE, AND/OR CARBON MONOXIDE.

Waste Disposal Methods:DISCHARGE, TREATMENT, OR DISPOSAL MAY BE SUBJECT
TO FEDERAL, STATE, OR LOCAL LAWS. THESE DISPOSAL GUIDELINES ARE
INTENDED FOR THE DISPOAL OF CATALOG-SIZE QUANTITIES ONLY. DISPOSE
OF IN AN APPROVED INC INERATOR EQUIPPED WITH AN AFTERBURNER AND
SCRUBBER.

Toxicological Information:TWA: CALCULATED: 40 PPM; 97 MG/M3 (AIR)

Disclaimer (provided with this information by the compiling agencies):
This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.

Transport Information:D.O.T. DENATURED ALCOHOL SOLUTION, 3, NA 1987.