Product ID:G-135 INDUSTRIAL X-RAY DEVELOPER/REPLENISHER PART B
MSDS Date:04/05/2000
FSC:6750
NIIN:01-461-5235
Status Code:A
Kit Part:Y
MSDS Number: CLQFQ

AGFA CORPORATION

100 CHALLENGER RD
RIDGEFIELD PARK, NJ 07660
US

Emergency Phone: (303) 623-5716 HEALTH

Info Phone: 201-440-2500

Preparer: S. VAN VOLKENBURG

Cage: 1MVW0

AGFA CORPORATION

RIDGEFIELD PARK, NJ 07660 US

Telephone: 201-440-2500

Cage: 1MVW0

ACETIC ACID

CAS: 64-19-7

RTECS: AF1225000

OSHA PEL 25 MG/M3;10 PPM

ACGIH TLV: 25 MG/M3;10 PPM

EPA Report Quantity: 5000 LBS

DOT Report Quantity: 5000 LBS

DIETHYLENE GLYCOL

CAS: 111-46-6

RTECS: ID5950000

1-PHENYL-3-PYRAZOLIDONE

CAS: 92-43-3

RTECS: UQ8750000

Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:NO IARC:NO OSHA:NO
Health Hazards Acute and Chronic:ACUTE INHALATION: CAN CAUSE IRRITATION
TO THE RESPIRATORY TRACT. SKIN CONTACT: CORROSIVE TO THE SKIN.
EYES:CORROSIVE, MAY CAUSE IRRITATION AND BURNS. INGESTION: HARMFUL,
MAY CAUSE SEVERE INJURY, LIVER AND KIDNEY FAILURE. CHRONIC SKIN
CONTACT: MAY CAUSE AN ALLERGIC REACTION.
Explanation of Carcinogenicity:THE COMPONENTS OF THIS PRODUCT ARE NOT
LISTED BY NTP, IARC OR REGULATED AS A CARCINOGEN BY OSHA.
Effects of Overexposure:ACUTE INHALATION: OVEREXPOSURE TO ACETIC ACID
VAPORS CAN CAUSE IRRITATION TO THE RESPIRATORY TRACT RESULTING IN
COUGHING, RUNNY NOSE AND SORE THROAT. INHALATION OF DIETHYLENE
GLYCOL VAPORS IS UNLIKELY DUE TO ITS TEMPERATURES, HIGH
CONCENTRATIONS OF DIETHYLENE GLYCOL CAN PRODUCE DROWSINESS,
HEADACHE, DIZZINESS, AND NAUSEA. ACUTE SKIN CONTACT: DIRECT CONTACT
WITH ACETIC ACID IS CORROSIVE TO THE SKIN WITH SYMPTOMS OF
BURNING, REDDENING, ITCHING, AND SWELLING. SKIN SENSITIZATION WITH
ACETIC ACID IS RARE, BUT HAS BEEN REPORTED. CHRONIC SKIN CONTACT:
REPEATED OR PROLONGED CONTACT TO 1-PHENYL-3-PYRAZ OLIDONE MAY CAUSE
AN ALLERGIC REACTION
Medical Cond Aggravated by Exposure:PERSONS WITH PREEXISTING EYE, SKIN
OR RESPIRATORY TRACT DISORDERS MAY BE MORE SUSCEPTIBLE TO THE
EFFECTS OF THIS PRODUCT.

First Aid:EYE: IMMEDIATELY FLUSH WITH PLENTY OF RUNNING WATER FOR AT
LEAST 15 MINUTES. OBTAIN MEDICAL ATTENTION. SKIN: FLUSH AFFECTED
AREAS PROMTPLY WITH WATER FOR 15 MINUTES. REMOVE CONTAMINATED
CLOTHING, IN C ASE OF CONTINUED IRRITATION CONSULT PHYSICIAN.
INHALATION: IF INHALED, REMOVE TO FRESH AIR. IF NOT BREATHING, GIVE
ARTIFICIAL RESPIRATION. IF BREATHING IS DIFFICULT, GIVE OXYGEN.
CALL A PHYSICIAN. ING ESTION: IF SWALLOWED, CALL A PHYSICIAN.

Flash Point:>93.3C, 200.F
Extinguishing Media:WATER, CARBON DIOXIDE, DRY CHEMICAL, FOAM.
Fire Fighting Procedures:EVACUATE PERSONNEL TO A SAFE AREA. KEEP
PERSONNEL REMOVED AND UPWIND OF FIRE. WEAR SELF-CONTAINED BREATHING
APPARATUS.

Spill Release Procedures:USE APPROPRIATE PERSONAL PROTECTIVE EQUIPMENT
DURING CLEAN UP. DIKE SPILL. PREVENT LIQUID FROM ENTERING SEWERS,
WATERWAYS, OR LOW AREAS. SOAK UP WITH SAWDUST, SAND, OIL DRY OR
OTHER ABSORBENT MATERIAL . SPILL MAY BE NEUTRALIZED WITH POWDERED
SODIUM CARBONATE.
Neutralizing Agent:SPILL MAY BE NEUTRALIZED WITH POWDERED SODIUM
CARBONATE.

Handling and Storage Precautions:STORE BETWEEN 40F (4.4C) AND 80F
(26C). PREFERRED STORAGE IS AT 68F (20C). KEEP FROM FREEZING. AVOID
EYE AND SKIN CONTACT, AND STORE IN WELL-VENTILATED AREA. KEEP
CONTAINER TIGHTLY CLOSED.
Other Precautions:DO NOT STORE WITH INCOMPATIBLE MATERIALS. DO NOT
STORE OR CONSUME FOOD, DRINK OR TOBACCO IN AREA WHERE THEY MAY
BECOME CONTAMINATED WITH THIS MATERIAL. KEEP OUT OF REACH OF
CHILDREN.

Respiratory Protection:WORKPLACE AMBIENT CONCENTRATIONS SHOULD BE
MONITORED AND IF RECOMMENDED EXPOSURE LIMITS ARE EXCEEDED A
NIOSH/MSHA APPROVED RESPIRATOR SHOULD BE WORN. IF RESPIRATORS ARE
USED, INSTITUTE A PROGRAM IN AC CORDANCE WITH OSHA STANDARD 29
CFR1010.134.
Ventilation:USE SUFFICIENT GENERAL ROOM VENTILATION AND/OR LOCAL
EXHAUST TO MAINTAIN AIRBORNE LEVELS OF VAPORS BELOW APPLICABLE
EXPOSURE LIMITS.
Protective Gloves:USE CHEMICAL RESISTANT GLOVES.
Eye Protection:EYE GLASSES WITH SIDE SHIELDS OR GOGGLES.
Other Protective Equipment:FOR SKIN PROTECTION USE CHEMICAL RESISTANT
APRONS. EMERGENCY SHOWERS AND EYE WASH STATIONS SHOULD BE MADE
AVAILABLE. EDUCATE AND TRAIN EMPLOYEES IN THE SAFE USE AND HANDLING
OF THIS PRODUCT.
Supplemental Safety and Health
PART B OF A 4 PART MSDS, SAME NSN.

HCC:C2
Spec Gravity:APPROX. 1.09
pH:APPROX. 2
Solubility in Water:SOLUBLE
Appearance and Odor:CLEAR, COLORLESS LIQUID; VINEGAR ODOR.

Stability Indicator/Materials to Avoid:YES
STRONG ALKALI, OXIDIZERS, METALS.
Stability Condition to Avoid:NONE KNOWN.
Hazardous Decomposition Products:IN CASE OF FIRE OXIDES OF CO2, CARBON
MONOXIDE AND OTHER POTENTIALLY TOXIC FUMES CAN BE GENERATED DUE TO
THERMAL DECOMPOSITION.
Conditions to Avoid Polymerization:WILL NOT OCCUR.

Waste Disposal Methods:RECOVER NONUSABLE FREE LIQUID AND/OR
CONTAMINATED WATER, AND DISPOSE OF IN AN APPROVED AND PERMITTED
TREATMENT SYSTEM. REMOVE NONUSABLE SOLID MATERIAL AND/OR
CONTAMINATED SOIL, FOR DISPOSAL IN AN APPR OVED AND PERMITTED
LANDFILL. DISCHARGE TO SEWER MAY REQUIRE APPROVAL OF PERMITTING
AUTHORITY AND MAY REQUIRE PRETREATMENT.

Toxicological Information:ACETIC AICD: ORAL RAT LD50 = 3310 MG/KG,
DERMAL D50 (RABBIT) = 1060 MG/KG, INHALATION LC50 RABBIT = 5620
PPM/1 HR. EYE AND SKIN EFFECTS: CORROSIVE.

Disclaimer (provided with this information by the compiling agencies):
This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.

Ecological:NO INFO AVAILABLE.

Transport Information:PSN: ACETIC ACID SOLUTION, 8, UN2790, II. LABEL:
CORROSIVE.

SARA Title III Information:CERCLA RQ: 5,000 LBS FOR ACETIC ACID.SEC 302
EHS: NONE. SEC 311/312 HAZARD CATEGORIES: IMMEDIATE HEALTH HAZARD.
SEC 313 TOXIC CHEMICALS: NONE. RCRA STATUS: WHEN DISCARDED IN ITS
PURCHASED FORM, THIS P RODUCT MEETS THE CRITERIA OF CORROSOVITY,
AND SHOULD BE MANAGED AS A HAZARDOUS WASTE ( EPA HAZ WASTE # D002).
Federal Regulatory Information:OSHA STATUS: THIS PRODUCT IS HAZARDOUS
UNDER THE CRITERIA OF THE FEDERAL OSHA HAZARD COMMUNICATION
STANDARD 29 CFR 1910.1200. TSCA INVENTORY STATUS: THIS MATERIAL IS
LISTED ON THE TSCA INVENTORY.
State Regulatory Information:INGREDIENTS ARE LISTED ON THE FOLLOWING
STATES: MA, NJ, PA.