Product ID:14163-69 LITHIUM HYDROXIDE
MSDS Date:02/25/1991
FSC:6810
NIIN:00D000958
MSDS Number: BBDPW

Emergency Phone: 515-232-2533

Info Phone: 800-227-4224

Cage: 4T252

Telephone: 803-775-7323

Cage: 3N991

LITHIUM HYDROXIDE SOLUTION

CAS: 1310-65-2

RTECS: OJ6307070

Fraction By Weight: 100%

LD50 LC50 Mixture:ORAL LD50 (RAT) IS 225 MG/KG
Routes of Entry: Inhalation:YES Skin:NO Ingestion:YES
Reports of Carcinogenicity:NTP:NO IARC:NO OSHA:NO
Health Hazards Acute and Chronic:ACUTE: INHALATION- IRRITATION OF
RESPIRATORY TRACT, BURNS TO MUCOUS MEMBRANES, CENTRAL NERVOUS
SYSTEM DERESSION. EYES- IRRITATION, BURNS. SKIN- IRRITATION, BURNS.
INGESTION- CENTRAL NERVOUS SYSTEM DEP RESSION, BURNS TO MOUTH AND
ESOPHAGUS. CHRONIC: KIDNEY DAMAGE, BONE MARROW DAMAGE (APLASTIC
ANEMIA).
Explanation of Carcinogenicity:NONE
Effects of Overexposure:INHALATION: DIZZINESS, HEADACHE, COUGHING,
WHEEZING, CHEST PAIN. EYES: REDNESS, TEARING, BURNS. SKIN: REDNESS,
RASH, BURNS. INGESTION: NAUSEA, VOMITING, DIZZINESS, STOMACH PAIN.
Medical Cond Aggravated by Exposure:PREEXISTING RESPIRATORY DISEASES,
SKIN DISORDERS, EYE CONDITIONS.

First Aid:INHALATION: REMOVE TO FRESH AIR. RESUSCITATE IF NEEDED. SKIN:
FLUSH WITH WATER; REMOVE CONTAMINATED CLOTHING. WASH WITH SOAP AND
WATER. SEE DOCTOR. EYES: FLUSH WITH WATER FOR 15 MINUTES. SEE
DOCTOR. I NGESTION: DO NOT INDUCE VOMITING! GIVE 1-2 GLASSES OF
WATER TO CONSCIOUS PERSON. GET IMMEDIATE MEDICAL ATTENTION.

Flash Point:NONE
Extinguishing Media:DRY CHEMICAL, ALCOHOL FOAM, OR CARBON DIOXIDE
Fire Fighting Procedures:WEAR USE NIOSH/MSHA APPROVED RESPIRATOR AND
FULL PROTECTIVE GEAR.
Unusual Fire/Explosion Hazard:MAY EMIT TOXIC OR IRRITATING FUMES IN
FIRE OR ON CONTACT WITH ACIDS.

Spill Release Procedures:CONTAIN SPILL. NEUTRALIZE. SCOOP MATERIAL INTO
CONTAINER FOR DISPOSAL. MOP FLOOR WITH WATER AND SOAP/CLEANER.
Neutralizing Agent:5 % ACETIC ACID.

Handling and Storage Precautions:KEEP AWAY FROM ACIDS. WEAR PROPER
PROTECTIVE CLOTHING.
Other Precautions:DO NOT BREATH DUST. AVOID CONTACT WITH EYES, SKIN AND
CLOTHING.

Respiratory Protection:NONE NORMALLY REQUIRED. IF PEL/TLV EXCEEDED USE
NIOSH/MSHA APPROVED RESPIRATOR WITH DUST/MISTS CARTRIDGE.
Ventilation:USE ADEQUATE LOCAL VENTILATION (FUME HOOD).
Protective Gloves:PVC AND NEOPRENE
Eye Protection:SAFETY GLASSES/CHEMICAL SPLASH GOGGLES
Other Protective Equipment:CLOTHING TO PREVENT PROLONGED OR REPEATED
CONTACT. EYE WASH STATION & SAFETY SHOWER.
Work Hygienic Practices:WASH HANDS AFTER USE AND BEFORE EATING,
DRINKING, OR SMOKING.
Supplemental Safety and Health

HCC:B3
Melt/Freeze Pt:M.P/F.P Text:880F,471C
Spec Gravity:2.54
pH:>11
Solubility in Water:APPRECIABLE
Appearance and Odor:WHITE POWDER (IN PILLOWS) WITH SUFFOCATING ODOR
Corrosion Rate:.23(AL)

Stability Indicator/Materials to Avoid:YES
STRONG MINERAL ACIDS, METALS, COMBUSTIBLES, AND WATER.
Stability Condition to Avoid:CONTACT WITH INCOMPATIBLES, EXTREME
TEMPREATURES AND MOISTURE.
Hazardous Decomposition Products:OXIDES OF LITHIUM

Waste Disposal Methods:DISPOSE OF IN ACCORDANCE WITH LOCAL, STATE AND
FEDERAL REGULATIONS.

Disclaimer (provided with this information by the compiling agencies):
This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.