Product ID:BLACO-TRON DES
MSDS Date:10/01/1987
FSC:6850
NIIN:00D002041
MSDS Number: BBFPH

BARON BLAKESLEE

2001 N. JANICE AVE
MELROSE PARK, IL 60160

Emergency Phone: 312-450-3900

Cage: BARON

CIBA SPECIALTY CHEMICALS CORP, N. A. / PERFORMANCE

LOS ANGELES, CA 90039-1011 US

Telephone: 818-247-6210/800-873-1138

Cage: 99384

1,1,2-TRICHLORO-1,2,2-TRIFLUOROETHANE (FREON 113) (SARA

CAS: 76-13-1

RTECS: KJ4000000

Fraction By Weight: 93.5%

OSHA PEL 1000PPM/1250STEL

ACGIH TLV: 1000PPM/1250STEL9192

ISOPROPYL ALCOHOL (SARA III)

CAS: 67-63-0

RTECS: NT8050000

Fraction By Weight: 2%

OSHA PEL 400 PPM/500 STEL

ACGIH TLV: 400 PPM/500STEL;9192

ETHYL ALCOHOL (ETHANOL)

CAS: 64-17-5

RTECS: KQ6300000

Fraction By Weight: 3.5%

OSHA PEL 1000 PPM

ACGIH TLV: 1000 PPM; 9192

NITROMETHANE

CAS: 75-52-5

RTECS: PA9800000

Fraction By Weight: 1%

OSHA PEL 100 PPM

ACGIH TLV: 100 PPM; 9192

METHYL ALCOHOL (METHANOL) (SARA III)

CAS: 67-56-1

RTECS: PC1400000

Fraction By Weight: 0.4%

OSHA PEL S,200PPM/250STEL

ACGIH TLV: S,200PPM/250STEL; 93

EPA Report Quantity: 5000 LBS

DOT Report Quantity: 5000 LBS

LD50 LC50 Mixture:LD50 ABOUT 43 G/KG (RAT)
Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Health Hazards Acute and Chronic:LOW TOXICITY,MILD IRRITANT. IT IS AN
ANESTHETIC & INHALATION OF HIGH CONCENTRATIONS CAN PRODUCE
ASPHYXIATION. AT LEVELS OF ABOUT 2500 PPM IN AIR THERE BEGINS TO BE
INTERFERENCE WITH PSYCHOLOGICAL & PS YCHOMOTOR FUNCTIONS,EXPRESSED
AS EXCITEMENT & INCOORDINATION.
Effects of Overexposure:LOW CONCENTRATION:HEADACHE,DIZZINESS,NAUSEA;
HIGH CONC(>2500 PPM):INTOXICATION,CARDIAC EFFECTS,CENTRAL NERVOUS
SYSTEM DEPRESSION; EYE/SKIN:IRRITATION: ING:SIMILAR SYMPTOMS AS FOR
INHALATION.
Medical Cond Aggravated by Exposure:NONE STATED.

First Aid:INH:REMOVE TO FRESH AIR,GIVE MOUTH-TO-MOUTH RESUSCITATION IF
BREATHIG HAS STOPPED,GIVE OXYGEN AS NECESSARY.DO NOT GIVE
ADRENALIN(EPINEPHRINE); ING:IF CONSCIOUS,INDUCE VOMITING BY GIVING
2-4 GLASSES OF WATER & TOUCH FINGER TO BACK OF THROAT,TAKE TO A
HOSPITAL; EYE:FLUSH WITH LARGE AMOUNTS OF WATER FOR 15 MIN,LIFTING
EYELIDS; SKIN:WASH WITH SOAP & WATER,REMOVE CONTAMINATED CLOTHING &
SHOES.

Extinguishing Media:USE PROPER EXTINGUISHING MEDIA FOR SURROUNDING
FIRE.
Fire Fighting Procedures:WEAR POSITIVE PRESSURE SELF-CONTAINED
BREATHING APPARATUS FOR POSSIBLE EXPOSURE TO HYDROCHLORIC &
HYDROFLUORIC ACIDS & PHOSGENE.
Unusual Fire/Explosion Hazard:WILL DECOMPOSE AT TEMPERATURE ABOVE 250F.

Spill Release Procedures:EVACUATE AREA.PROVIDE MAX
VENTILATION.UNPROTECTED PERSONNEL SHOULD STAY UPWIND OF SPILL.WEAR
PROPER PROTECTIVE CLOTHING.DIKE AREA & CONTAIN SPILL.PREVENT
CONTAMINATION OF GROUND & SURFACE WATER.USE SA WDUST OR
VERMICULATE,SWEEP INTO CONTAINER & CLOSE.

Handling and Storage Precautions:DO NOT USE IN POORLY VENTILATED AREAS.
KEEP CONTAINERS CLOSED WHEN NOT IN USE.AVOID CONTAMINATION OF WATER
SUPPLIES.
Other Precautions:AVOID PROLONGED OR REPEATED BREATHING OF VAPORS.
AVOID CONTACT WITH EYES & SKIN.DO NOT TAKE INTERNALLY.DO NOT
EAT,DRINK OR SMOKE IN WORK AREA.

Respiratory Protection:NONE REQUIRED FOR ADEQUATELY VENTED WORK
SITUATIONS. USE NIOSH-APPROVED PRESSURE-DEMAND SELF-CONTAINED OR
SUPPLIED-AIR RESPIRATOR WHERE THE PLACE IS CONFINED OR ENCLOSED.
Ventilation:LOCAL EXHAUST FOR FILLING ZONES & MECHANICAL FOR STORAGE
AREAS.
Protective Gloves:RECOMMENDED.
Eye Protection:SPLASH PROOF GOGGLES.
Other Protective Equipment:EYE BATH & SAFETY SHOWER.
Work Hygienic Practices:USE NORMAL HYGENIC PRACTICES.
Supplemental Safety and Health

HCC:N1
Boiling Pt:B.P. Text:112F/44C
Melt/Freeze Pt:M.P/F.P Text:<-13F/-35C
Decomp Temp:Decomp Text:>250F/121C
Vapor Pres:5.6
Vapor Density:5.6
Spec Gravity:1.48
pH:7
Evaporation Rate & Reference:4.2, ETHER=1
Solubility in Water:0.05% (WT)
Appearance and Odor:COLORLESS LIQUID WITH ETHEREAL & FAINT SWEETISH
ODOR.
Percent Volatiles by Volume:100

Stability Indicator/Materials to Avoid:YES
STRONG ACIDS & STRONG ALKALIS REACTIVE METAL:POWDERED
ALUMINUM,MAGNESIUM,ZINC,MOLTEN BARIUM,LITHIUM SHAVINGS,ETC.
Stability Condition to Avoid:AVOID TEMPERATURE ABOVE 250F.AVOID
SPARKS,HOT SPARKS,WELDING,FLAMES & CIGARETTES.
Hazardous Decomposition Products:HYDROCHLORIC ACID,HYDROFLUORIC
ACID,PHOSGENE.

Waste Disposal Methods:CONTAMINATED ABSORBENT MAY BE DISPOSED OF IN A
PERMITTED HAZARDOUS WASTE FACILITY. RECOVERED LIQUID MAY BE
REPROCESSED OR INCINERATED OR TREATED IN A WASTE MANAGEMENT
FACILITY. FOLLOW FEDERAL,STATE & LOCAL REGULATIONS.

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particular situation.