Product ID:GENESOLV DM AZEOTROPE
MSDS Date:01/01/1985
FSC:6850
NIIN:00K000548
MSDS Number: BCBBC

ALLIED CHEM CORP.

COLUMBIA RD & PARK AVE
MORRISTOWN, NJ 07960
US

Cage: GO753

ALLIED-SIGNAL INC

1087R MORRISTOWN, NJ 07962-2332 US

Telephone: 201-455-4414

Cage: 1L164

1,1,2-TRICHLORO-1,2,2-TRIFLUOROETHANE (FREON 113) (SARA

CAS: 76-13-1

RTECS: KJ4000000

Fraction By Weight: 50.5%

OSHA PEL 1000PPM/1250STEL

ACGIH TLV: 1000PPM/1250STEL9192

METHYLENE CHLORIDE (SARA III)

CAS: 75-09-2

RTECS: PA8050000

Fraction By Weight: 49.5%

OSHA PEL 500 PPM/C,1000; Z2

ACGIH TLV: 50 PPM, A2; 9192

EPA Report Quantity: 1000 LBS

DOT Report Quantity: 1000 LBS

Effects of Overexposure:EYES,SKIN:IRRITNT;MAY DEFAT
SKIN;INHAL:DROWSINESS,ASPHYXIATION;INGEST:HARMFUL,MAY BE FATAL.

First Aid:INHAL:REMOVE TO FRESH AIR,GIVE CPR/O*2 IF NEED.DO NOT GIVE
ADRENALINE(EPINEPHRINE);SKIN/EYES;FLUSH W LG AMTS H*2O(LIFT
EYELIDS):INGEST:DO NOT INDUCE VOMIT.KEEP WARM, QUIET. FOR
INHAL,INGEST,OR EYES; C ALL PHYSICIAN.REMOVE CONTAMINATED CLOTHING.

Extinguishing Media:N/A;NON FLAMMABLE.USE H*2O SPRAY TO DIVERT FROM
FIRE & HEAT
Fire Fighting Procedures:SELF-CNTND BRTHG APP;H*2O SPRAY COOL CONT,
KNOCK VAPOR DOWN.
Unusual Fire/Explosion Hazard:TOXIC COMBUSTION
PRODUCTS;HALOGENS,HALOGEN ACIDS,CARBONYL HALIDES,INCLUDING
PHOSGENE;CORROSIVE GASES

Spill Release Procedures:EVACUATE UNPROTECTED PERSONS.ELIM IGNITION
SOURCES.STOP LEAK. H*2O SPRAY COOL CONT/DIVERT SPILL FROM
FIRE/HEAT.PROVIDE VENTILATION.ABSORB W COMMERCIAL ABSORBENT,SHOVEL
INTO METAL DRUMS;LG SPILL:DIKE W COMMERCIAL ABSORBENT,PUMP INTO
COVEREDDRUMS

Handling and Storage Precautions:STORE IN COOL,WELL VENTILATED,LOW FIRE
RISK AREA. PROTECT FROM PHYSICAL DAMAGE.AVOID ANY PHYSICAL
CONTACT.KEEP CONTAINERS TIGHTLY CLOSED.
Other Precautions:AVOID PROLONGED OR REPEATED CONTACT W/LIQUID OR
VAPOR. NBR OR NEOPRENE PREFERRED PROTECTIVE MATERIALS(REMOVE/WASH
IF CONTAMINATED).ALLIED CHEM. PRODUCT CODE 196-002511.

Respiratory Protection:IF EXPOSE >140 PPM,WEAR SELF-CNTND BRTHG APP OR
AIR LINE RESPIR.
Ventilation:MECHANICAL(GEN./LOCAL EXHAUST),DRAW VAPORS DOWNWARD OR
HORIZ
Protective Gloves:IMPERVIOUS
Eye Protection:SAFETY/CHEM GOGGLES
Other Protective Equipment:NORMAL FULL WORK CLOTHING COVERING
ARMS,LEG.NO CONTACT LENS.
Supplemental Safety and Health
CHEM NAME:50.5WT%TRICHLOROTRIFLUOROETHANE/40.5WT;METHYLENE
CHLORIDE;CHEM FAMILY:HALOGENATED HYDROCARBONS-AZEOTROPE;VAPOR
EXPOSRUE MAY CAUSE CARDIAC ARRHYTHMIA;NON FLAMMABLE.

HCC:T4
Boiling Pt:B.P. Text:97.7F,36.5C
Vapor Pres:460
Vapor Density:5.0
Spec Gravity:1.45
Evaporation Rate & Reference:1 (ETHER=1)
Solubility in Water:SLIGHT
Appearance and Odor:COLORLESS LIQUID;ETHERAL ODOR.
Percent Volatiles by Volume:100

Stability Indicator/Materials to Avoid:YES
HOT REACTIVE METALS,MOLTEN AL,FINE BA & LI;POWDERED AL,MG,ZN
Stability Condition to Avoid:DECOMPOSES ABOVE 250F;THERMAL DECOMP
INCREASES TOXICITY
Hazardous Decomposition Products:HALOGENS,HALOGEN ACIDS, & CARBONYL
HALIDES, PHOSGENE.

Waste Disposal Methods:KEEP IN COVERED DRUMS,PENDING DISPOSAL.DO NOT
ALLOW TRANSFER PUMPS TO OVERHEAT. PRODUCT IS HALOGENATED
SOLVENT,100% VOLATILE.CONTACT SUPPLIER FOR DISPOSAL METHODS, OR
RECYCLE.DISPOSE IN FULL REGULATOR Y COMPLIANCE.DO NOT USE
PLASTIC/RUBBER NOSE/PIPE.

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This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.