Product ID:GENESOLV DA AZEOTROPE
MSDS Date:01/01/1985
FSC:6850
NIIN:00K000561
MSDS Number: BCBBR

ALLIED CHEMICAL CORP.

Emergency Phone: 201-455-2000

Cage: 1L168

ALLIED-SIGNAL INC

1087R MORRISTOWN, NJ 07962-2332 US

Telephone: 201-455-4414

Cage: 1L164

1,1,2-TRICHLORO-1,2,2-TRIFLUOROETHANE (FREON 113) (SARA

CAS: 76-13-1

RTECS: KJ4000000

Fraction By Weight: 90.3%

OSHA PEL 1000PPM/1250STEL

ACGIH TLV: 1000PPM/1250STEL9192

ACETONE (SARA III)

CAS: 67-64-1

RTECS: AL3150000

Fraction By Weight: 9.4%

OSHA PEL 1000PPM

ACGIH TLV: 750PPM/1000STEL;9293

EPA Report Quantity: 5000 LBS

DOT Report Quantity: 5000 LBS

NITROMETHANE

CAS: 75-52-5

RTECS: PA9800000

Fraction By Weight: 0.3%

OSHA PEL 100 PPM

ACGIH TLV: 100 PPM; 9192

Effects of Overexposure:INHALE:DROWSINESS;EYE:IRRITANT;SKIN:MAY CAUSE
DEFATTING;INGEST:MAY BE QUITE HARMFUL.

First Aid:INHALE:REMOVE TO FRESH AIR,GIVE CPR/O*2 IF NEED.DO NOT GIVE
ADRENALINE(EPINEPHRINE);SKIN/EYES:FLUSH W LG AMTS H*2O(LIFT
EYELIDS);INGEST:INDUCE VOMITING IMMEDIATELY. FOR INHALE,INGEST,OR
EYES:CALL PHYS ICIAN.

Extinguishing Media:N/A; NON FLAMMABLE,USE H*2O SPRAY TO DIVERT FROM
FIRE & HEAT
Fire Fighting Procedures:SELF-CNTND BRTHG APP;H*2O SPRAY COOL
CONTAINERS,DIVERT SPILL
Unusual Fire/Explosion Hazard:CONTACT W MOLTEN ALUMINUM,BARIUM &
LITHIUM SHAVINGS PRODUCES RAPID EXOTHERMIC REACTION.

Spill Release Procedures:EVACUATE UNPROTECTED PERSONS. ELIMINATE
IGNITION SOURCES. STOP LEAK. USE H*2O SPRAY TO COOL
CONTAINERS/FLUSH SPILL AWAY FROM FIRE & HEAT.PROVIDE VENTILATION.
ABSORB W COMMERCIAL ABSORBENT.SHOVEL INTO COVERED METAL
DRUMS,PENDING DISPOSAL.

Handling and Storage Precautions:STORE IN COOL,DRY,WELL VENTILATED,LOW
FIRE RISK AREA. PROTECT FROM PHYSICAL DAMAGE. AVOID ANY PHYSICAL
CONTACT.KEEP CONTAINERS TIGHTLY CLOSED.
Other Precautions:PROLONGED EXPOSURE TO WHITE METALS WILL CAUSE
CORROSION. AVOID PROLONGED OR REPEATED BREATHING OF VAPOR OR
CONTACT.TANKS CANNOT BE EFFECTIVELY FLUSHED OF VAPOR IF SUMPS
CONTAIN LIQUID.

Respiratory Protection:SELF-CNTND BRTHG APP OR AIR LINE RESPIR.
Ventilation:MECHANICAL(GEN./LOCAL EXHAUST).
Protective Gloves:IMPERVIOUS
Eye Protection:SAFETY/CHEM GOGGLES.
Other Protective Equipment:NORMAL FULL WORK CLOTHING COVERING
ARMS,LEGS.NO CONTACT LENS
Supplemental Safety and Health
BLEND OF ACETONE,CH*3COCH*3,9.4
WT%,TRICHLOROTRIFLUOROETHANE,C*2CL*3F*3,90.3 WT%,AND
NITROMETHANE,CH*3NO*2,0.3 WT% USES INCLUDE TANK CLEANING:VAPOR
REDUCES O*2 AVAILABLE FOR BREATHING.

HCC:T4
Boiling Pt:B.P. Text:113F,44.9C
Vapor Pres:385
Vapor Density:6.0
Spec Gravity:1.42
Evaporation Rate & Reference:2 (ETHER=1)
Solubility in Water:SLIGHT
Appearance and Odor:COLORLESS LIQUID;ETHERAL & FAINT SWEETISH ODOR.
Percent Volatiles by Volume:100

Stability Indicator/Materials to Avoid:YES
STRONG OXIDANTS,HOT REACTIVE METALS.
Stability Condition to Avoid:DECOMPOSITION AT TEMPERATURES ABOVE 250F.
Hazardous Decomposition Products:HALOGENS,CARBONYL HALIDES,INCLUDING
PHOSGENE,CO,&CO*2.

Waste Disposal Methods:PRODUCT IS PRIMARILY A FLUOROCARBON, CONTAINING
NITRATED ORGANIC & KETONE. CONTACT SUPPLIER FOR DISPOSAL METHOD.
DISPOSE IN FULL REGULATORY COMPLIANCE.

Disclaimer (provided with this information by the compiling agencies):
This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.