Product ID:GENESOLV DE AZEOTROPE
MSDS Date:01/01/1987
FSC:6850
NIIN:00K000565
MSDS Number: BCBBW

ALLIED CHEMICAL CORP

Emergency Phone: 201-455-2000

Cage: 1L168

ALLIED-SIGNAL INC

1087R MORRISTOWN, NJ 07962-2332 US

Telephone: 201-455-4414

Cage: 1L164

1,1,2-TRICHLORO-1,2,2-TRIFLUOROETHANE (FREON 113) (SARA

CAS: 76-13-1

RTECS: KJ4000000

Fraction By Weight: 95.5%

OSHA PEL 1000PPM/1250STEL

ACGIH TLV: 1000PPM/1250STEL9192

ETHYL ALCOHOL (ETHANOL)

CAS: 64-17-5

RTECS: KQ6300000

Fraction By Weight: 4.5%

OSHA PEL 1000 PPM

ACGIH TLV: 1000 PPM; 9192

METHYL ALCOHOL (METHANOL) (SARA III)

CAS: 67-56-1

RTECS: PC1400000

Fraction By Weight: <0.5%

OSHA PEL S,200PPM/250STEL

ACGIH TLV: S,200PPM/250STEL; 93

EPA Report Quantity: 5000 LBS

DOT Report Quantity: 5000 LBS

Effects of Overexposure:EYES,SKIN:IRRITNT,MAY DEFAT
SKIN;INHALE,INGEST:DROWSINESS,DIZZINESS,NAUSEA,VOMIT;MAY CAUSE
ASPHYX.

First Aid:INHALE:REMOVE TO FRESH AIR,GIVE CPR/O*2 IF NEED.DO NOT GIVE
ADRENALINE (EPINEPHRINE);SKIN/EYES:FLUSH W/LG AMTS H*2O (FLUSH EYES
15 MIN-LIFT EYELIDS);INGEST:GIVE H*2O & INDUCE VOMITING
IMMEDIATELY.FOR INHALE,INGEST OR EYES:CALL PHYSICIAN.

Extinguishing Media:N/R-NON-FLAMMABLE;USE H*2O SPRAY TO DIVERT FROM
FIRE & HEAT.
Fire Fighting Procedures:NIOSH/MSHA APPROV SCBA.H*2O SPRAY TO COOL
CONT,DIVERT SPILL.
Unusual Fire/Explosion Hazard:CONTACT W MOLTEN ALUMINUM,BARIUM,&
LITHIUM SHAVINGS PRODUCES RAPID EXOTHERMIC REACTIONS.

Spill Release Procedures:EVACUATE UNPROTECTED PERSONS.ELIMINATE
IGNITION SOURCES.STOP LEAK.USE H*2O SPRAY TO COOL CONTAINERS/FLUSH
SPILL AWAY FROM FIRE & HEAT.PROVIDE VENTILATION. ABSORB W
COMMERCIAL ABSORBENT.SHOVEL INTO COV ERED METAL DRUMS, PENDING
DISPOSAL.

Handling and Storage Precautions:STORE IN COOL,DRY,WELL VENTILATED.LOW
FIRE RISK AREA.PROTECT FROM PHYSICAL DAMAGE.AVOID ANY PHYSICAL
CONTACT.KEEP CONTAINERS TIGHTLY CLOSED.
Other Precautions:AVOID PROLONGED OR REPEATED CONTACT WITH LIQUID OR
VAPOR.

Respiratory Protection:IF EXPOSED > 500PPM,NIOSH/MSHA APP SCBA OR AIR
LINE RESPIR.
Ventilation:MECHANICAL(GEN./LOCAL EXHAUST)
Protective Gloves:IMPERVIOUS
Eye Protection:SAFETY/CHEM GOGGLES
Other Protective Equipment:NORMAL FULL WORK CLOTHING COVERING
ARMS,LEGS.NO CONTACT LENS
Supplemental Safety and Health
ALLIED CHEMICAL PRODUCT CODE NO.196-008040.BLEND OF
TRICHLOROTRIFLUOROETHANE,C*2CL*3F*3,95.5WT%,ETHANOL,C*2H*5OH,4.5%,A
ND METHANOL,CH*3OH,0.5% MAX WITHIN ETHANOL COMPONENT.

HCC:N1
Boiling Pt:B.P. Text:111F,44C
Vapor Pres:365
Vapor Density:6.0
Spec Gravity:1.49
Evaporation Rate & Reference:2 (ETHER=1)
Solubility in Water:NEGLIGIBLE
Appearance and Odor:COLORLESS LIQUID GAS; FAINT ETHERAL ODOR.
Percent Volatiles by Volume:100

Stability Indicator/Materials to Avoid:YES
STRONG OXIDANTS,REACTIVE METALS,POWDERED AL,ZN,MG
Stability Condition to Avoid:DECOMPOSES ABOVE 250F;THERMAL
DECOMP.INCREASES TOXICITY.
Hazardous Decomposition Products:HALOGENS,CARBONYL HALIDES,INCLUDING
PHOSGENE,CO, & CO*2.

Waste Disposal Methods:PRODUCT IS PRIMARILY A FLUOROCARBON, CONTAINING
NITRATED ORGANIC & KETONE. CONTACT SUPPLIER FOR DISPOSAL METHODS.
DISPOSE IN FULL REGULATORY COMPLIANCE.

Disclaimer (provided with this information by the compiling agencies):
This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.