Product ID:196-008030,GENESOLV DE-35 SOLVENT
MSDS Date:01/01/1985
FSC:6850
NIIN:00K000568
MSDS Number: BCBBZ

ALLIED CHEMICAL CO.

COLUMBIA RD & PARK AVE
MORRISTOWN, NJ 07960
US

Cage: 1L168

ALLIED-SIGNAL INC

1087R MORRISTOWN, NJ 07962-2332 US

Telephone: 201-455-4414

Cage: 1L164

1,1,2-TRICHLORO-1,2,2-TRIFLUOROETHANE (FREON 113) (SARA

CAS: 76-13-1

RTECS: KJ4000000

Fraction By Weight: 65.0%

OSHA PEL 1000PPM/1250STEL

ACGIH TLV: 1000PPM/1250STEL9192

METHYL ALCOHOL (METHANOL) (SARA III)

CAS: 67-56-1

RTECS: PC1400000

Fraction By Weight: 1.35%

OSHA PEL S,200PPM/250STEL

ACGIH TLV: S,200PPM/250STEL; 93

EPA Report Quantity: 5000 LBS

DOT Report Quantity: 5000 LBS

ETHYL ALCOHOL (ETHANOL)

CAS: 64-17-5

RTECS: KQ6300000

Fraction By Weight: 35.0%

OSHA PEL 1000 PPM

ACGIH TLV: 1000 PPM; 9192

Effects of Overexposure:INH:HEAD,DIZZ,NAUSE,VOMIT;SKIN:IRRIT,MAY
DEFAT;EYES*IRRITANT,VAP MAY HAVE MILD IRRIT,POSS DAMAGE

First Aid:INH:REMOVE TO FRESH AIR.GIVE OXY/CPR IF REQD.DO NOT GIVE
EDRENALIN;EYES:FLUSH W/LG AMT OF WATER;SKIN:WASH W/WATER;ING:INDUCE
VOMIT BY GIVING 2-4 GLASSES OF WATER.NEVER GIVE ANYTHING BY MOUTH
TO UNCON PERSON:GET MED ATTN FOR ANY ABOVE PROBLEM.

Flash Point:142F-147F,OC
Autoignition Temp:Autoignition Temp Text:366C
Lower Limits:3.3
Upper Limits:19.0
Extinguishing Media:CO*2,CHEM(ALCOHOL)FOAM,DRY CHEM.
Fire Fighting Procedures:SELF-CNTND BRTHG APP APPRVD BY NIOSH.COOL
CNTNR BY WATERSPRA
Unusual Fire/Explosion Hazard:PROLONG EXP TO WHITE METLS CAUSE
CORR.CONTACT W/MOLTEN AL,BA & LI SHAVINGS REACT EXOTHERMALLY

Spill Release Procedures:EVACUATE AREA.USE PROTECTVE EQUIP.ELIMINATE
SOURCE OF IGN/HEAT.STOP LEAK W/O RISK.ABSORB W/ABSROBENT MATL(SUCH
AS VERMICULITE) & SHOVEL INTO METAL DRUMS & CLOSE.FOR LG SPILL,DIKE
W/ABSORB/SAND,PUMP IN TO DRUMS & CLOSE.DELAYD CLEANUP INCREASFIRE
HAZ.

Handling and Storage Precautions:STORE IN COOL WELL-VENTILATED AREA OF
LOW FIRE RISK.PROTECT CONTNRS FROM PHYSICAL DAMAGE & KEEP
CLOSED.AVOID BREATNG VAP,EYE/SKIN CONTACT.KEEP FM HEAT
Other Precautions:MEDICAL SURVEILLANCE/EMPLOYEE TRAING PROPOSED.TANKS
CANNOT BE EFFECTIVLY FLUSHED OF VAP IN SUMPS CONTNG LIQ.FOLLOW TANK
ENTRY PROCEDURES IF CLEANING REQD.SEE LABEL IN PROD CONTNR.

Respiratory Protection:SELF-CNTND BRTHG APP OR SUPPLIED-AIR RESPIR
EFFECTVE TO 4500 PPM
Ventilation:MECH(GEN)FOR STORAGE LOC & LOCAL EXHAUST FOR FILLING ZONES.
Protective Gloves:PROTEC GLOVE
Eye Protection:CHEM SAFETY GOGGLES
Other Protective Equipment:COMPLETE PROTEC CLOTHING & BOOTS EYE-WASH
FACILITY
Supplemental Safety and Health
FORMULA:C*2H*50H/C*2CL*3F*3/CH*3OH.BASED IN ASSUMPTION THAT FLASH POINT
BY CLOSED CUP WILL BE LOWERED THAN OPEN CUP METHOD,THE STORAGE
COMPATIBILITY CODE F4 IS ASSIGNED.

HCC:F4
Boiling Pt:B.P. Text:44.8C,113F
Vapor Pres:360
Vapor Density:3.0
Spec Gravity:1.16
Evaporation Rate & Reference:15 (ETHER=1)
Solubility in Water:SLIGHT
Appearance and Odor:COLORLESS LIQ W/ETHEREAL & FAINT ALCOHOL ODOR.
Percent Volatiles by Volume:100

Stability Indicator/Materials to Avoid:YES
STRONG OXIDANTS,REACTIVE METLS,CA,POWD AL,ZN,MG,ETC.
Stability Condition to Avoid:WILL DECOMPOSE AT TEMP ABOVE 250F.DO NOT
BOIL ABOVE 140F.
Hazardous Decomposition Products:HALOGENS,CARBONYL HALIDES,PHOSGENE,CO
& CO*2.

Waste Disposal Methods:SPILL OR LEAK MATL COLLECT SHOULD BE DILUTED
W/WATER.USERS.SHOULD REVIEW FED,STATE,LOCAL REGS BEFORE
DISCHARGING/DISPOSING WASTE MATL.DISPOSER MUST COMPLY
W/FEDERAL,STATE & LOCAL REGS.

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expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.