Product ID:METHYLENEDIANILINE(MDA)
MSDS Date:01/01/1985
FSC:6810
NIIN:00K000612
MSDS Number: BCBFB

ALLIED CHEMICAL CORPORATION

Emergency Phone: 201-455-2000

Cage: 1L168

ALLIED-SIGNAL INC

1087R MORRISTOWN, NJ 07962-2332 US

Telephone: 201-455-4414

Cage: 1L164

4,4'-METHYLENE DIANILINE (SARA III)

CAS: 101-77-9

RTECS: BY5425000

Fraction By Weight: UNK

ACGIH TLV: S; 0.1 PPM; A2; 9192

EPA Report Quantity: 1 LB

DOT Report Quantity: 1 LB

ANILINE (SARA III)

CAS: 62-53-3

RTECS: BW6650000

Fraction By Weight: TR

OSHA PEL S, 5 PPM

ACGIH TLV: S, 2 PPM; 9293

EPA Report Quantity: 5000 LBS

DOT Report Quantity: 5000 LBS

Effects of Overexposure:CAUSES LIVER DAMAGE,FEVER,CHILLS,VOMIT,NO
APPETITE,ALLERGIC REACT SOME PEOPLE,SUSPEC ANIML TUMERGEN.

First Aid:INGEST:INDUCE VOMIT UNTIL VOMIT FLUID CLEAR.INHALED:REMOVE TO
FRESH AIR,GIVE CPR IF BRTHG STOPPED.CALL PHYSICIAN IMMEDIATELY.IN
CASE OF CONTACT,WASH EYES WITH WATER,SKIN WITH SOAP & WATER.FOR
EYES,GET MEDICAL ATTENTION.

Flash Point:428F COC
Lower Limits:UNK
Upper Limits:UNK
Extinguishing Media:DRY CHEMICAL OR CO*2
Fire Fighting Procedures:WEAR SELF-CNTND BRTHG APP W FUL FACEPIECE.H*2O
TO COOL CONT
Unusual Fire/Explosion Hazard:HEAT DECOMPOSITION YIELDS ANILINE
(POSSIBLY YIELD CO,CO*2 & NITROGEN OXIDES)

Spill Release Procedures:SWEEP UP W MINIMUM DUSTNG,AMPLE VENTNG IF IN
FLAKE FORM.IF POWDER,WET DOWN & SHOVEL INTO CONT.CLOSE CONTAINERS
AND LABEL.DO NOT SEWER ANY WASH WATER,PASTE OR OTHER PRODUCT.

Handling and Storage Precautions:NO EATING/SMOKING WHILE HANDLING.STORE
IN COOL PLACE.KEEP CONTAINER CLOSED.PROTECT FROM PHYSICAL DAMAGE.
Other Precautions:PRACTICE GOOD PERSONAL HYGIENE AND HOUSEKEEPING.MDA
IS A SIGNIFICANT LIVER TOXIN.EXPOSURE MOST COMMON THROUGH
INHALATION OR DUST OR VAPORS AND ABSORPTION THROUGH SKIN.

Respiratory Protection:IF DUSTY USE HIEPF.IF MATL HEATED USE GMOUF(SEE
SUPPL DATA)
Ventilation:LOCAL EXHAUST:FOR DUSTY COND.OR VAPOR PRESENCE
Protective Gloves:NEOPRENE(CLEAN)
Eye Protection:CHEM SAFETY GOGGLES
Other Protective Equipment:CLEAN COVERALLS/CAP(FRESH DAILY),EYE/SAFETY
SHOWER
Supplemental Safety and Health
RESPIR PROT:HIEPF-HIGH EFF.PARTICULATE RESPIR W FULL FACE
PIECE.GMOVF-GAS MASK W ORGANIC VAPOR CANIS W FULL FACEPIECE.

HCC:N1
Boiling Pt:B.P. Text:750F
Vapor Pres:.01
Spec Gravity:1.18
Evaporation Rate & Reference:NEGLIGIBLE
Solubility in Water:SLIGHT
Appearance and Odor:LIGHT TAN FLAKES,FAINT AMINE ODOR
Percent Volatiles by Volume:NEG

Stability Indicator/Materials to Avoid:YES
STRONG ACIDS AND THEIR ANHYDRIDES,STRONG OXIDANTS
Stability Condition to Avoid:FP:428F COC
Hazardous Decomposition Products:NO DATA BUT COMBUSTION YIELDS
CO,CO*2,NITROGEN OXIDES

Waste Disposal Methods:DISPOSAL SUBJECT TO FEDERAL,STATE & LOCAL
REGULATIONS.USERS SHOULD REVIEW OPERATIONS FOR COMPLIANCE,THEN
CONSULT WITH APPROPRIATE AGENCIES BEFORE DISPOSING WASTE MATERIAL.

Disclaimer (provided with this information by the compiling agencies):
This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.