Product ID:METHANOL(CANCELLED, SEE 6810005973608)
MSDS Date:01/01/1987
FSC:6810
NIIN:00-503-0095
MSDS Number: BFBSK

AAPER ALCOHOL AND CHEMICAL CO.

11 ISAAC SHELBY DRIVE
SHELBYVILLE, KY 40065
US

Emergency Phone: 1-800-854-6813 /POISON CONTROL CTR/

Info Phone: 502-633-0650

Cage: 61305

AAPER ALCOHOL AND CHEMICAL CO

339 SHELBYVILLE, KY 40066-0339 US

Telephone: 502-633-0650

Cage: 61305

METHYL ALCOHOL (METHANOL) (SARA III)

CAS: 67-56-1

RTECS: PC1400000

Fraction By Weight: >99%

OSHA PEL S,200PPM/250STEL

ACGIH TLV: S,200PPM/250STEL; 93

EPA Report Quantity: 5000 LBS

DOT Report Quantity: 5000 LBS

Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Health Hazards Acute and Chronic:SEE SIGNS & SYMPTOMS OF OVEREXPOSURE.
Effects of
Overexposure:EYES-IRRITATION,BURNING.SKIN-DRYING,DERMATITIS.INHAL-H
EADACHE,NAUSEA,VOMITING,DIZZ,VISUAL
DISTURB,INTOX,SLEEPINESS,UNCONSCIOUSNESS,DEATH.TOXIC EFFECTS
EXERTED ON CNS,ESP OPTIC NERVE.INGEST-100-250ML C AN BE FATAL.LESS
AMT-BLINDNESS,DIZZ,HEADACHE,NAUSEA.ABSORP RAPID-EXCRETION
SLOW,YIELD DELAYED EFFECTS,COMPOUND EFFT
Medical Cond Aggravated by Exposure:NONE NOTED

First Aid:EYES-FLUSH W/WATER 15 MIN-GET IMMED MED ATTN. SKIN-REMOVE
CONTAM CLOTH;WASH AREAS W/SOAP & WATER;IF IRRIT PERSISTS GET MED
ATTN. INHAL-GET TO FRESH AIR;GIVE ARTIF RESPIR IF NEEDED;GET IMMED
MED ATTN. INGEST-IF CONSCIOUS,GIVE 2 GLASSES WATER& INDUCE
VOMITING;GET IMMED MED ATTN. AFTER VOMIT GIVE MILK,WATER,OR SODIUM
BICARB SOLN/1 TSP/1 QT/

Flash Point Method:TCC
Flash Point:54F (12C)
Autoignition Temp:Autoignition Temp Text:685F
Lower Limits:6.7
Upper Limits:36.0
Extinguishing Media:WATER SPRAY,DRY CHEMICAL,CARBON DIOXIDE,ALCOHOL
FOAM. DO NOT USE A DIRECT WATER STREAM.
Fire Fighting Procedures:USE SLF-CONTND BREATHING APPARATUS & FULL
PROTECTIVE CLOTHING. USE WATER SPRAY TO COOL NEARBY CONTNRS &
STRUCTURES EXPOSED TO FIRE.
Unusual Fire/Explosion Hazard:EXTINGUISH ALL SOURCES IGNITION. PRODUCT
MAY BURN W/FLAME INVIS IN DAYLIGHT. MIXTURES W/WATER & AS LITTLE AS
21% PRODUCT ARE FLAMMABLE.

Spill Release Procedures:WEAR RESPIR PROTECT & PROTECT CLOTH;CONTAIN
SPILL;TRANS TO SECURE CONTNRS;IF NECESSARY USE ABSORBENT MEDIA.
DETERMINE IF RELEASE IS REPORTABLE SPILL.

Handling and Storage Precautions:STORE IN COOL,DRY,WELL-VENT AREA AWAY
FM INCOMPATIBLE MATLS;VENT CONTNR FREQUENTLY TO RELIEVE
PRESSURE.KEEP CONTR TIGHTLY CLOSED.AVOID PHYSICAL CONTAC
Other Precautions:ELECTRICALLY GROUND ALL EQUIP WHEN HANDLING
PRODUCT;USE ONLY NON-SPARKING TOOLS.WASH THOROUGHLY AFTER HANDLING.

Respiratory Protection:NIOSH APPRD SLF-CONTND BREATH APPARATUS IN
PRESSURE DEMAND MODE OR SUPPLIED AIR RESPIRATOR IF USE CONDITIONS
GENERATE VAPORS OR MISTS.
Ventilation:LOCAL MECHANICAL EXHAUST TO KEEP EMISSIONS AT PT OF USE
Protective Gloves:RUBBER
Eye Protection:CHEM GOGGLES OR FULL FACEPIECE RESPIRATR
Other Protective Equipment:LONG-SLVD SHIRT,TROUSERS,SAFETY SHOES,RUBBER
APRON. EYEWASH & SAFETY SHOWER.
Work Hygienic Practices:AVOID CONTACT WITH EYES,SKIN.DO NOT DRINK.WASH
THOROUGHLY AFTER HANDLING.REMOVE CONTAMINATED CLOTHING & LAUNDER.
Supplemental Safety and Health
THIS NSN REPLACED BY 6810-00-597-3608

HCC:F2
Boiling Pt:B.P. Text:148F
Vapor Pres:44.6
Vapor Density:1.1
Spec Gravity:0.79
Solubility in Water:COMPLETE
Appearance and Odor:CLEAR,COLORLESS LIQUID

Stability Indicator/Materials to Avoid:YES
STRONG OXIDIZING AGENTS,ALUMINUM,ZINC,ANY METAL THAT DISPLACES
HYDROGEN;CERTAIN PLASTICS,RUBBERS,ACIDS & ALKALIS.
Stability Condition to Avoid:HEAT,SPARKS,OPEN FLAMES
Hazardous Decomposition Products:MAY LIBERATE CARBON MONOXIDE,CARBON
DIOXIDE,FORMALDEHYDE

Waste Disposal Methods:IAW ALL APPLICABLE LAWS & REGS.

Disclaimer (provided with this information by the compiling agencies):
This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.