Product ID:MIL-C-46168D PART B 4:1 BLEND
MSDS Date:11/17/1988
FSC:8010
NIIN:01-260-0916
MSDS Number: BHBFL

NILES CHEMICAL PAINT CO.

225 FORT STREET
NILES, MI 49120

Emergency Phone: (219) 236-5856

Info Phone: (616) 683-3377

Preparer: MICHAEL J. LICHATOWICH

Cage: 02388

NILES CHEMICAL PAINT

307 NILES, MI 49120 US

Telephone: 616-683-3377/219-236-5856

Cage: 02388

ALIPHATIC POLYISOCYANATE

CAS: 28182-81-2

RTECS: NQ9170000

Fraction By Weight: 75%

1,6-DIISOCYANATOHEXANE (HEXAMETHYLENE DIISOCYANATE)

CAS: 822-06-0

RTECS: MO1740000

Fraction By Weight: <0.7%

ACGIH TLV: 0.005 PPM; 9192

EPA Report Quantity: 1 LB

DOT Report Quantity: 1 LB

XYLENES (O-,M-,P- ISOMERS) (SARA III)

CAS: 1330-20-7

RTECS: ZE2100000

Fraction By Weight: 12.5%

OSHA PEL 100 PPM/150 STEL

ACGIH TLV: 100 PPM/150STEL;9192

EPA Report Quantity: 1000 LBS

DOT Report Quantity: 1000 LBS

N-BUTYL ACETATE (SARA III)

CAS: 123-86-4

RTECS: AF7350000

Fraction By Weight: 12.5%

OSHA PEL 150 PPM/200 STEL

ACGIH TLV: 150 PPM/200STEL;9192

EPA Report Quantity: 5000 LBS

DOT Report Quantity: 5000 LBS

LD50 LC50 Mixture:ORAL LD50: 20 G/KG (RAT)
Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:NO IARC:NO OSHA:NO
Health Hazards Acute and Chronic:INHALATION: MUCOUS MEMBRANES, NOSE,
THROAT, LUNGS & EYES, COUGHING, CHEST DISCOMFORT, SHORTNESS OF
BREATH & REDUCED LUNG FUNCTION, HEADACHE, NAUSEA, NARCOSIS, FATIGUE
& LOSS OF APPETITE.
Explanation of Carcinogenicity:NONE
Effects of Overexposure:INHALATION: CHEST TIGHTNESS, WHEEZING, COUGH,
SHORTNESS OF BREATH, ASTHMATIC ATTACK, LUNG DAMAGE, PERMANENT
BRAIN/NERVOUS SYSTEM DAMAGE/LOSS OF MEMORY, INTELLECTUAL ABILITY &
COORDINATION. SKIN/EYES:
REDDENING/SWELLING/RASH/SCALING/BLISTERING/DEFATTED/CRACKED/DERMATI
TIS. INGESTION: ACTION IN THE MOUTH/DIGESTIVE TRACT.
Medical Cond Aggravated by Exposure:RESP SYSTEM/CORNEAL
INJURY/BURN/PULMONARY SENSITIZER/BLOOD/LIVER
DAMAGE/KIDNEYS/ASTHMA/RESP
DISORDERS/BRONCHITIS/EMPHYSEMA/HYPERREACTIVITY; SKIN ALLERGIES,
ECZEMA & RASH.

First Aid:INHALATION: MOVE TO AN AREA FREE FROM RISK OF FURTHER
EXPOSURE. ADMINISTER OXYGEN. SKIN: REMOVE CONTAMINATED
CLOTHING/WASH THOROUGHLY BEFORE REUSE. WASH AFFECTED AREA
THOROUGHLY W/SOAP & WATER. SEEK M ED ATT. EYE: FLUSH W/CLEAN,
LUKEWARM WATER FOR AT LEAST 15 MINS. OBTAIN MED ATT. INGESTION:
DON'T INDUCE VOMITING. DON'T GIVE ANYTHING BY MOUTH TO AN
UNCONSCIOUS PERSON. CONSULT PHYSICIAN.

Flash Point Method:PMCC
Flash Point:91F
Lower Limits:1.0%
Upper Limits:7.6%
Extinguishing Media:FOAM, "ALCOHOL", CO2, DRY CHEMICAL
Fire Fighting Procedures:FULL EMERGENCY EQUIPMENT/SCBA & FULL
PROTECTIVE CLOTHING.
Unusual Fire/Explosion Hazard:VAPORS MAY BE >AIR/BUILD UP/TRAVEL ALONG
THE GROUND/FLASHBACK. CLOSED CONTAINER MAY EXPLODE WHEN EXPOSED TO
EXTREME HEAT/BURST WHEN CONTAMINATED W/WATER, CO2.

Spill Release Procedures:EVACUATE NONESSENTIAL PERSONNEL. REMOVE ALL
SOURCES OF IGNITION/VENTILATE AREA. DIKE/IMPOUND SPILLED
MATERIAL/CONTROL FURTHER SPILLAGE IF FEASIBLE. COVER THE SPILL
W/SAWDUST/VERMICULITE/FULLER'S EARTH /OTHER ABSORBANT MATERIAL.
Neutralizing Agent:TMN-10 2%, WATER 90-95%, DETERGENT 2%

Handling and Storage Precautions:GROUND CONTAINERS DURING
STORAGE/TRANSFER OPERATIONS. STORE IN TIGHTLY CLOSED CONTAINERS TO
PREVENT MOISTURE CONTAMINATION. AVOID CONTACT W/SKIN/EYES.
Other Precautions:DON'T RESEAL IF CONTAMINATION IS SUSPECTED. AT
MAXIMUM STORAGE TEMPS NOTED, MATERIAL MAY SLOWLY POLYMERIZE W/O
HAZARD. IF CONTAINER IS EXPOSED TO HIGH HEAT, IT CAN BE
PRESSURIZED/POSSIBLY RUPTURE EXPL OSIVELY.

Respiratory Protection:IN ADDITION, A RESPIRATOR THAT IS
RECOMMENDED/APPROVED FOR USE IN ISOCYANATE CONTAINING ENVIRONMENTS
(AIR PURIFYING OR FRESH AIR SUPPLIED) MAY BE NECESSARY.
Ventilation:PROVIDE LOCAL EXHAUST VENTILATION TO KEEP Protective Gloves:RESISTANT
Eye Protection:SAFETY GLASSES, GOGGLES, FACE SHIELD
Other Protective Equipment:SAFETY SHOWERS/EYEWASH STATION.
Work Hygienic Practices:WASH HANDS THOROUGHLY BEFORE EATING/BEFORE
USING RESTROOM. SMOKE ONLY IN SMOKING AREAS.
Supplemental Safety and Health
EPA HAZARDOUS WASTE CODE: D-001 (IGNITABLE). WT PER GAL: 8.85. CONTACT
LENSES SHOULDN'T BE WORN.

HCC:F4
Vapor Density:>AIR
Evaporation Rate & Reference:SLOWER THAN ETHER
Solubility in Water:INSOLUBLE
Appearance and Odor:CLEAR TO PALE YELLOW LIQUID/SOLVENT ODOR.
Percent Volatiles by Volume:30%

Stability Indicator/Materials to Avoid:YES
WATER, AMINES, STRONG BASES, ALCOHOLS, METAL COMPOUNDS, & SURFACE
ACTIVE MATERIALS.
Stability Condition to Avoid:ISOLATE FROM HEAT, SPARKS, & OPEN FLAME
Hazardous Decomposition Products:CO2/CO/OXIDES OF NITROGEN, TRACES OF
HNC/HDI. DURING FIRE HDI VAPORS/OTHER IRRITATING, HIGHLY TOXIC
GASES MAY GENERATED.
Conditions to Avoid Polymerization:MOISTURE, HIGH TEMPERATURES, SHOCK
FROM DROPPING. HDI REACTS SLOWLY W/WATER TO FORM CO2 GAS.

Waste Disposal Methods:WASTE MUST BE DISPOSED OF IN ACCORDANCE
W/FEDERAL/STATE/LOCAL ENVIRONMENTAL CONTROL REGS. DON'T HEAT, CUT
ON OR NEAR EMPTY CONTAINERS W/ELECTRICAL/GAS TORCH. EMPTY CONTAINER
MUST BE HANDLED W/CARE DUE TO PRODUCT RESIDUE/FLAMMABLE SOLVENT
VAPOR.

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This information is formulated for use by elements of the Department
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disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.