Product ID:DENATURED ALCOHOL SDA-3-A
MSDS Date:02/13/1987
FSC:6810
NIIN:00-201-0904
MSDS Number: BHBGL

MIDWEST GRAIN PRODUCTS INC

1300 MAIN
ATCHISON, KS 66002
US

Emergency Phone: 913-367-1480

Info Phone: 913-367-1480

Preparer: JOHN M. WOHLGEMUTH

Cage: 3T076

MIDWEST GRAIN PRODUCTS INC

130 ATCHISON, KS 66002 US

Telephone: 913-367-1480; 800255-0302

Cage: 3T076

ETHYL ALCOHOL (ETHANOL)

CAS: 64-17-5

RTECS: KQ6300000

Fraction By Weight: 95.2%

OSHA PEL 1000 PPM

ACGIH TLV: 1000 PPM; 9192

METHYL ALCOHOL (METHANOL) (SARA III)

CAS: 67-56-1

RTECS: PC1400000

Fraction By Weight: 4.8%

OSHA PEL S,200PPM/250STEL

ACGIH TLV: S,200PPM/250STEL; 93

EPA Report Quantity: 5000 LBS

DOT Report Quantity: 5000 LBS

Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:NO IARC:NO OSHA:NO
Health Hazards Acute and Chronic:HEALTH HAZARD TO EYES,LIVER,HEART AND
KIDNEYS.
Effects of Overexposure:IRRITATION OF THE EYES,BLURRED
VISION,BLINDNESS,SKIN
IRRITATION,WEAKNESS,DROWSINESS,VOMITING,DRUNKENNESS,DEATH.
Medical Cond Aggravated by Exposure:NONE NOTED.

First Aid:EYES: FLUSH WITH PLENTY OF WATER FOR 15 MINUTES.SEE DOCTOR.
SKIN:REMOVE CONTAMINATED CLOTHING AND SHOES. WASH WITH SOAP AND
WATER.SEE DOCTOR. INHALATION: REMOVE VICTIM TO FRESH AIR.GIVE
OXYGEN/CPR IF

Flash Point Method:CC
Flash Point:=12.8C, 55.F
Lower Limits:3.3
Upper Limits:19
Extinguishing Media:FOAM,CARBON DIOXIDE,DRY CHEMICAL.
Fire Fighting Procedures:DO NOT USE WATER.WEAR SCBA AND PROTECTIVE
CLOTHING.USE WATER SPRAY TO COOL FIRE EXPOSED CONTAINERS AND TO
DISPERSE UNIGNITED VAPORS.
Unusual Fire/Explosion Hazard:FLAMMABLE LIQUID.TOXIC GASES SUCH AS
CARBON MONOXIDE AND FORMALDEHYDE MAY BE RELEASED IN A FIRE.

Spill Release Procedures:CONTACT YOUR LOCAL ENVIRONMENTAL OFFICER.WEAR
PROTECTIVE CLOTHING & EQUIPMENT.EVACUATE PERSONNEL.ELIMINATE
IGNITION SOURCES.VENTILATE AREA.USE NON-SPARKING TOOLS.STOP
LEAK.ABS0RB IN INERT ABSORBENT & PLACE INTO APPROPIATE DISPOSAL
CONTAINER& SEAL.

Handling and Storage Precautions:STORE IN COOL,DRY,WELL VENTILATED
PLACE,AWAY FROM HEAT,IGNITION SOURCES AND INCOMPATIBLE
MATERIALS.KEEP CONTAINERS CLOSED WHEN NOT IN USE.
Other Precautions:BOND AND GROUND CONTAINERS.NO SMOKING IN AREA.

Respiratory Protection:NIOSH/MSHA RESPIRATOR WITH CARTRIDGE APPROPIATE
FOR EXPOSURE OF CONCERN OR SCBA IF TLV IS EXCEEDED.
Ventilation:SUFFICIENT MECHANICAL (GENERAL) AND/OR LOCAL EXHAUST
VENTILATION TO MAINTAIN EXPOSURE BELOW TLV.
Protective Gloves:RUBBER.
Eye Protection:CHEMICAL SAFETY GOGGLES.
Other Protective Equipment:FULL WORK CLOTHING TO PREVENT REPEATED OR
PROLONGED SKIN CONTACT. EYE WASH STATION AND SAFETY SHOWER.
Work Hygienic Practices:AVOID CONTACT WITH EYES & SKIN.DO NOT BREATHE
VAPORS.WASH THOROUGHLY AFTER HANDLING.LAUNDER CONTAMINATED
CLOTHING.
Supplemental Safety and Health
DENATURED ALCOHOL: CONTAINS TOXIC METHANOL. AVOID CONTACT AND BREATHING
OF VAPORS.

HCC:F5
NRC/State Lic Num:NOT RELEVANT
Boiling Pt:=78.3C, 173.F
Vapor Pres:44
Vapor Density:1.6
Spec Gravity:0.79
Evaporation Rate & Reference:5.9 (BUTYL ACETATE=1)
Solubility in Water:COMPLETE
Appearance and Odor:WATER CLEAR PUNGENT LIQUID,CHARACTERISTIC ODOR.
Percent Volatiles by Volume:100

Stability Indicator/Materials to Avoid:YES
OXIDIZING AGENTS SUCH AS ACETYL CHLORIDE,NITRIC ACID AND HYDROGEN
PEROXIDE.METHANOL MAY ATTACK SOME FORMS OF PLASTICS.
Stability Condition to Avoid:HEAT,SPARKS,OPEN FLAMES.
Hazardous Decomposition Products:CARBON MONOXIDE,CARBON
DIOXIDE,INCOMPLETELY BURNED CARBON PRODUCTS.

Waste Disposal Methods:KEEP IN COVERED DRUMS PENDING DISPOSAL.CONTACT
YOUR LOCAL ENVIRONMENTAL OFFICER FOR DISPOSAL.DISPOSE OF IN
ACCORDANCE WITH ALL APPLICABLE FEDERAL, STATE AND LOCAL
ENVIRONMENTAL REGULATIONS.

Disclaimer (provided with this information by the compiling agencies):
This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.