Product ID:FREON TMC CLEANING AGENT
MSDS Date:04/01/1989
FSC:6810
NIIN:01-164-1300
MSDS Number: BHBXV

E.I. DU PONT DE NEMOURS & CO. INC.

1007 MARKET STREET
WILMINGTON, DE 19899
US

Emergency Phone: 800-441-3637

Info Phone: 800-441-9450 OR 302-999-5072

Preparer: K.P. BROWN

Cage: 18773

E.I. DUPONT DE NEMOURS & CO

WILMINGTON, DE 19898 US

Telephone: 800-441-7515;800-441-9442

Cage: 18873

1,1,2-TRICHLORO-1,2,2-TRIFLUOROETHANE (FREON 113) (SARA

CAS: 76-13-1

RTECS: KJ4000000

Fraction By Weight: 50.5%

OSHA PEL 1000PPM/1250STEL

ACGIH TLV: 1000PPM/1250STEL9192

METHYLENE CHLORIDE (SARA III)

CAS: 75-09-2

RTECS: PA8050000

Fraction By Weight: 49.5%

OSHA PEL 500 PPM/C,1000; Z2

ACGIH TLV: 50 PPM, A2; 9192

EPA Report Quantity: 1000 LBS

DOT Report Quantity: 1000 LBS

LD50 LC50 Mixture:LD50 ORAL RAT,CH*2CL*2:5000MG/KG
Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:NO IARC:YES OSHA:NO
Health Hazards Acute and Chronic:ACUTE:IRRITATION OF EYES AND
SKIN;INHALATION MAY CAUSE HEATH IRREGULARITIES,UNCONSCIOUSNESS OR
DEATH;MISUSE CAN BE FATAL;CNS EFFECTS LIKE
HEADACHE,DIZZINESS,CONFUSION,INC-ORDINATION;VAPOR MAY REDUCE A
VAILABLE OXYGEN/BLOOD OXYGEN CARRYING CAPACITY DUE TO METHYLENE
CHLORIDE.
Explanation of Carcinogenicity:LISTED BY IARC AND ACGIH AS SUSPECTED
CARCINOGEN TO ANIMALS OR HUMAN.
Effects of Overexposure:SEE HEALTH HAZARDS DATA.
Medical Cond Aggravated by Exposure:PRE-EXISTING CONDITIONS MAY BE
WORSEN.

First Aid:INHALATION:REMOVE TO FRESH AIR;CPR OR OXYGEN IF NEEDED;CALL A
PHYSICIAN IMMEDIATELY. EYES & SKIN:FLUSH WITH PLENTY OF WATER FOR
ABOUT 15-20 MINUTES;CALL A PHYSICIAN. INGESTION:DO NOT INDUCE
VOMITING;C ALL A PHYSICIAN IMMEDIATELY.

Flash Point:NONE
Extinguishing Media:USE ANY SUITABLE MEDIA FOR SURROUNDING FIRE.
Fire Fighting Procedures:USE NIOSH/MSHA APPROVED SCBA IN AN ENCLOSED
AREA.
Unusual Fire/Explosion Hazard:USE WATER SPRAY OR FOG TO COOL
CONTAINERS;DRUMS MAY RUPTURE UNDER FIRE CONDITIONS;DECOMPOSITION
MAY OCCUR.

Spill Release Procedures:USE PROPER PERSONAL PROTECTTION;REMOVE ALL
IGNITION SOURCES;CONTAIN FREE LIQUID IF POSSIBLE;USE SUITABLE INERT
ABSORBENT MATERIAL AD RECOVER FOR PROPER DISPOSAL.

Handling and Storage Precautions:STORE IN CLEAN,DRY AREA;DO NOT HEAT
ABOVE 125F.

Respiratory Protection:USE NIOSH/MSHA APPROVED RESPIRATOR FOR ORGANIC
VAPOR IF ABOVE PEL/TLV OR SCBA IN CASE OF LARGE SPILL OR CONFINED
AREA.
Ventilation:LOCAL/GENERAL TO MAINTAIN PEL/TLV.
Protective Gloves:BUTYL RUBBER.
Eye Protection:CHEMICAL GOGGLES.
Other Protective Equipment:APRON,EYE-WASH FACILITIES.
Work Hygienic Practices:AVOID CONTACT WITH EYES AND SKIN;DO NOT BREATHE
VAPOR/MIST IF ABOVE PEL/TLV.WASH THOROUGHLY AFTER EACH USE.
Supplemental Safety and Health

HCC:T4
Boiling Pt:B.P. Text:97.2F/36.2C
Vapor Pres:409 MMHG
Vapor Density:4.7 (AIR=1
Spec Gravity:1.42
pH:NEUTRL
Evaporation Rate & Reference:1.83 (CCL*4=1)
Solubility in Water:SLIGHT (0.66%)
Appearance and Odor:CLEAR LIQUID,COLORLESS,SLIGHT ETHEREAL .
Percent Volatiles by Volume:100

Stability Indicator/Materials to Avoid:YES
ALKALI OR ALKALINE EARTH METALS;AL,ZNC,BE ETC IN POWERED FORM.
Stability Condition to Avoid:OPEN FLAME AND HIGH TEMPERATURE.
Hazardous Decomposition Products:HCL,HF AND POSSIBLY CARBONYL HALIDES.

Waste Disposal Methods:CONSULT LOCAL AUTHORITIES;DISPOSAL MUST BE IN
ACCORDANCE WITH LOCAL,STATE AND FEDERAL REGULATIONS.

Disclaimer (provided with this information by the compiling agencies):
This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.