Product ID:TOLUENE,A42444,A42500
MSDS Date:04/27/1989
FSC:6810
NIIN:00-411-4192
MSDS Number: BHBYQ

PHILLIPS 66 COMPANY

BARTLESVILLE,, OK 74004
US

Emergency Phone: 918-661-3865/8118

Info Phone: 918-661-8327

Cage: 46935

SHAPE PRODUCTS

OAKLAND, CA 94621-4427 US

Telephone: 510-534-1186 OR 800-444-0015

Cage: 3D869

TOLUENE (SARA III)

CAS: 108-88-3

RTECS: XS5250000

Fraction By Weight: 99.95%

OSHA PEL 200 PPM/150 STEL

ACGIH TLV: 50 PPM; 9293

EPA Report Quantity: 1000 LBS

DOT Report Quantity: 1000 LBS

Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:NO IARC:NO OSHA:NO
Health Hazards Acute and Chronic:ACUTE;IRRITATION OF
EYES,SKIN,RESPIRATORY AND G.I.TRACT;CNS EFFECTS LIKE
HEADACHE,DIZZINESS,CNS DEPRESSION NAUSEA. CHRONIC:DRYING OF
SKIN,DERMATTIS.
Explanation of Carcinogenicity:NONE OF THE COMPOUNDS IN THIS PRODUCT IS
LISTED BY IARC, NTP, OR OSHA AS A CARCINOGEN.
Effects of Overexposure:SEE HEALTH HAZARDS DATA.
Medical Cond Aggravated by Exposure:PERSONS WITH A HISTORY OF AILMENTS
OR WITH A PRE-EXISTING DISEASE INVOLVING THE EYES, SKIN, OR
RESPIRATORY TRACT MAY BE AT INCREASED RISK FROM EXPOSURE.

First Aid:INHALATION:REMOVE TO FRESH AIR. RESUSCITATE IF NOT BREATHING.
GET MEDICAL ATTENTION. EYES:IMMEDIATELY FLUSH WITH PLENTY OF WATER
FOR 15 MINUTES HOLDING EYELIDS OPEN. GET MEDICAL ATTENTION.
SKIN:REMOVE CONTAMINATED CLOTHING. WASH WITH SOAP AND WATER. IF
IRRITATION PERSISTS, GET MEDICAL ADVICE. INGESTION:DO NOT INDUCE
VOMITING. GIVE NOTHING BY MOUTH IF UNCONSCIOUS. GET IMMEDIATE
MEDICAL ATTENTION.

Flash Point Method:TCC
Flash Point:40.0F,4.4C
Autoignition Temp:Autoignition Temp Text:TCC
Lower Limits:1.2
Upper Limits:7.1
Extinguishing Media:USE CARBON DIOXIDE, FOAM, DRY CHEMICAL, OR WATER
FOG.
Fire Fighting Procedures:FIRE FIGHTERS SHOULD USE NIOSH APPROVED SCBA &
FULL PROTECTIVE EQUIPMENT WHEN FIGHTING CHEMICAL FIRE. USE WATER
SPRAY TO COOL NEARBY CONTAINERS EXPOSED TO FIRE.
Unusual Fire/Explosion Hazard:CONTAINERS MAY BURST WHEN EXPOSED TO HEAT
OF FIRE. CARBON OXIDES FORMED WHEN BURNED.

Spill Release Procedures:SMALL SPILL: WIPE/SOAK UP WITH PAPER TOWEL OR
INERT ABSORBANT. PUT IN DISPOSAL CONTAINER. REMOVE RESIDUE WITH
WATER. LARGE SPILL: EVACUATE AND VENTILATE AREA. IF POSSIBLE, STOP
LEAK. DIKE TO RETAIN RU N OFF. VACUUM UP FREE LIQUID. ABSORB/WASH
RESIDUE.
Neutralizing Agent:NOT APPLICABLE.

Handling and Storage Precautions:STORE IN A COOL, DRY, WELL VENTILATED
AREA. KEEP CONTAINERS TIGHTLY CLOSED WHEN NOT IN USE. PROTECT
CONTAINERS FROM PHYSICAL DAMAGE.
Other Precautions:DO NOT TAKE INTERNALLY. DO NOT BREATHE MIST. AVOID
PROLONGED OR REPEATED BREATHING OF VAPOR. AVOID CONTACT WITH EYES.
USE WITH ADEQUATE VENTILATION. WASH THOROUGHLY AFTER HANDLING. FOR
INDUSTRIAL USE ONLY.

Respiratory Protection:IF VENTILATION DOES NOT MAINTAIN INHALATION
EXPOSURES BELOW PEL(TLV), USE NIOSH/MSHA APPROVED ORGANIC VAPOR
CARTRIDGE AND DUST/MIST PRE-FILTER RESPIRATORS AS PER CURRENT 29
CFR 1910.134, INSTRUCTIONS/ WARNINGS AND NIOSH-RESPIRATOR
SELECTION.
Ventilation:MECHANICAL (GENERAL) ROOM VENTILATION IS NORMALLY ADEQUATE.
LOCAL EXHAUST MAY BE REQUIRED IF WORK AREA NOT VENTED.
Protective Gloves:NEOPRENE, NITRILE, VPC OR NATURAL RUBBER
Eye Protection:SAFETY GOGGLES WITH OPTIONAL FACE SHIELD
Other Protective Equipment:EYE WASH STATION AND SAFETY SHOWER.
INDUSTRIAL-TYPE WORK CLOTHING AND APRON AS REQUIRED.
Work Hygienic Practices:OBSERVE GOOD PERSONAL HYGIENE PRACTICES AND
RECOMMENDED PROCEDURES. DO NOT WEAR CONTAMINATED CLOTHING OR
FOOTWEAR.
Supplemental Safety and Health
AVOID PROLONGED OR REPEATED EXPOSURE. DO NOT GET ON SKIN OR IN EYES. DO
NOT BREATHE VAPORS OR MISTS.

HCC:F2
Boiling Pt:B.P. Text:231F,111C
Vapor Pres:1.03
Vapor Density:3.1
Spec Gravity:0.872
Evaporation Rate & Reference:>1.0(N-BUTYL ACETATE = 1)
Solubility in Water:NEGLIGIBLE
Appearance and Odor:CLEAR LIQUID,MILD AROMATIC ODOR
Percent Volatiles by Volume:100

Stability Indicator/Materials to Avoid:YES
STRONG OXIDIZING AGENTS,OXYGEN.
Stability Condition to Avoid:HIGH TEMPERATURES, SPARKS, OPEN FLAMES
Hazardous Decomposition Products:CARBON MONOXIDE, CARBON DIOXIDE

Waste Disposal Methods:DISPOSAL SHOULD BE MADE IN ACCORDANCE WITH ALL
APPLICABLE FEDERAL, STATE AND LOCAL LAWS AND REGULATIONS.

Disclaimer (provided with this information by the compiling agencies):
This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.