Product ID:VIRGINIA ICE MACHINE CLEANER H418-419 (#606
MSDS Date:04/20/1999
FSC:6850
NIIN:01-169-8438
MSDS Number: BHCCP

Emergency Phone: (800)424-9300

Info Phone: 214-330-7731

Preparer: J. KENNETH NOVAK

Cage: 58727

Telephone: 0000000000

Cage: 58727

PHOSPHORIC ACID (SARA III)

CAS: 7664-38-2

RTECS: TB6300000

OSHA PEL 1 MG/M3/3 STEL

ACGIH TLV: 1 MG/M3/3 STEL; 9192

EPA Report Quantity: 5000 LBS

DOT Report Quantity: 5000 LBS

LD50 LC50 Mixture:NO DATA PROVIDED BY RESPONSIBLE PARTY.
Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:NO IARC:NO OSHA:NO
Health Hazards Acute and Chronic:EMERGENCY OVERVIEW: CORROSIVE TO ALL
BODY TISSUES. CAUSES DESTRUCTION OF EYE AND SKIN TISSUE. HARMFUL IF
INHALED OR SWALLOWED. POTENTIAL HEALTH EFFECTS: INHALATION:
CORROSIVE TO RESPIRATORY PASSAGES. MAY CAUSE COUGHING, WHEEZING,
LARYNGITIS, SHORTNESS OF BREATH, HEADACHE, NAUSEA. EYE CONTACT:
IMMEDIATE IRRITATION AND BURNING FOLLOWED BY DESTRUCTION OF EYE
TISSUE. SKIN CONTACT: IMMEDIATE IRRITATION AND BURNING FOLLOWED BY
DESTRUCTION OF SKIN TISSUE. MODERATELY TOXIC WHEN ABSORBED THROUGH
SKIN. INGESTION: CORROSIVE TO DIGESTIVE TRACT. MAY CAUSE NAUSEA,
VOMITING, LOSS OF CONSCIOUSNESS. CHRONIC EF FECTS: KIDNEY AND LIVER
DAMAGE.
Explanation of Carcinogenicity:NO DATA PROVIDED BY RESPONSIBLE PARTY.
Effects of Overexposure:INHALATION: MAY CAUSE COUGHING, WHEEZING,
LARYNGITIS, SHORTNESS OF BREATH, HEADACHE, NAUSEA. EYE CONTACT:
IMMEDIATE IRRITATION AND BURNING FOLLOWED BY DESTRUCTION OF EYE
TISSUE. SKIN CONTACT: IMMEDIAT E IRRITATION AND BURNING FOLLOWED BY
DESTRUCTION OF SKIN TISSUE. INGESTION: MAY CAUSE NAUSEA, VOMITING,
LOSS OF CONSCIOUSNESS.
Medical Cond Aggravated by Exposure:AGGRAVATES PRE-EXISTING SKIN
DISORDERS.

First Aid:INHALATION: REMOVE TO FRESH AIR.IF NEEDED, START ARTIFICIAL
RESPIRATION. CALL A PHYSICIAN. EYE:IMMEDIATELY FLUSH EYES WITH
WATER FOR 15 MINUTES. CALL A PHYSICIAN. SKIN: FLUSH WITH PLENTY OF
WATER & WA SH WITH SOAP & WATER FOR 15 MINUTES OR UNTIL ALL TRACES
HAVE BEEN REMOVED. SEEK MEDICAL ATTENTION IF SYMPTOMS DEVELOP AND
PERSIST. INGESTION: DO NOT INDUCE VOMITING. RINSE MOUTH OUT WITH
WATER. GET IM MEDIATE MEDICAL ATTENTION.

Autoignition Temp:Autoignition Temp Text:N/E
Extinguishing Media:USE WATER FOG OR SPRAY, CARBON DIOXIDE (CO2), FOAM,
OR DRY POWDER.
Fire Fighting Procedures:APPROACH FIRE FROM UPWIND. AVOID BREATHING
SMOKE, FUMES, MIST OR VAPORS ON THE DWONWIND SIDE. FIREFIGHTERS
WEAR PROTECTIVEW CLOTHING AND SELF-CONTAINED BREATHING APPARATUS.
Unusual Fire/Explosion Hazard:NO DATA PROVIDED BY RESPONSIBLE PARTY.

Spill Release Procedures:EMERGENCY RESPONSE COORDINATOR MUST HAVE
MANDATED TRAINING. ELIMINATE ALL IGNITION SOURCES. PICK UP WITH
ABSORBENT MATERIALS & PLACE IN NON-LEAKING CONTAINER, SEAL TIGHTLY
FOR DISPOSAL. LARGE SPILLS: EVACUATE HAZARD AREA. WEAR APPROPRIATE
RESPIRATOR & PROTECTIVE CLOTHING. SHUT OF SOURCE OF LEAK IF SAFE TO
DO SO. DIKE & CONTAIN. REMOVE WITH VACUUM TRUCKS OR PUMP TO SALVAGE
VESSELS.
Neutralizing Agent:SODA ASH (DLA-HMIS).

Handling and Storage Precautions:ALWAYS ADD ACID TO WATER; NEVER WATER
TO ACID. AVOID CONTACT WITH SKIN, EYES AND CLOTHING. AFTER HANDLING
THIS PRODUCT, WASH HANDS BEFORE EATING, DRINKING OR SMOKING. IF
CONTACT OCCURS, REMOVE CLOTHIN G. IF NEEDED, TAKE 1ST AID ACTIONS.
LAUNDER CONTAMINATED CLOTHING BEFORE REUSE.
Other Precautions:STORE AWAY FROM CAUSTIC/ALKALIES.

Respiratory Protection:USE NIOSH-APPROVED RESPIRATOR.
Ventilation:LOCAL EXHAUST RECOMMENDED.
Protective Gloves:IMPERVIOUS.
Eye Protection:SAFETY GOGGLES & FULL FACE SHIELD
Other Protective Equipment:USE BOOTS, APRONS, EYE WASH STATION AND
SAFETY SHOWER AS NEEDED FOR PROTECTION AGAINST SPILLS AND/OR
SPALSHES.
Work Hygienic Practices:AFTER HANDLING THIS PRODUCT, WASH HANDS BEFORE
EATING, DRINKING OR SMOKING. IF CONTACT OCCURS, REMOVE CLOTHING.
LAUNDER CONTAMINATED CLOTHING BEFORE REUSE.
Supplemental Safety and Health
THIS NSN REPLACES DUPLICATE NSN:4110-01- 169-8438 (FSC IS DIFFERENT).

HCC:C1
Boiling Pt:>130.C, 266.F
Melt/Freeze Pt:=-27.6C, -18.F
Vapor Pres:0.3 MMHG
Spec Gravity:1.6
pH:1-2
Evaporation Rate & Reference:N/D (N-BUTYL ACETATE=1)
Solubility in Water:COMPLETE
Appearance and Odor:CLEAR COLORLESS LIQUID.

Stability Indicator/Materials to Avoid:YES
CAUSTICS, ALKALINE MATERIALS
Stability Condition to Avoid:HIGH TEMPERATURES.
Hazardous Decomposition Products:FROM COMBUSTION: SMOKE, CARBON
MONOXIDE (C0), CARBON DIOXIDE (CO2), PHOSPHORIC OXIDES (POX).
Conditions to Avoid Polymerization:WILL NOT OCCUR.

Waste Disposal Methods:DISPOSE AS HAZARDOUS WASTE. CLASSIFICATION AND
DOCUMENTATION IS REQUIRED BEFORE DISPOSAL. FOLLOW ALL LOCAL, STATE
AND FEDERAL REGULATIONS.

Toxicological Information:LDLO=220 MG/KG (IPR-MAN); LD50=1530 MG/KG
(ORAL-RAT); LD50=2470 MG/KG (SKIN-RAT).

Disclaimer (provided with this information by the compiling agencies):
This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.

Ecological:DANGEROUS TO AQUATIC LIFE IN HIGH CONCENTRATIONS. PHOSPHORIC
ACID: 138 PPM/24 HR/MOSQUITO FISH/TLM/FRESH WATER.

Transport Information:US DOT PROPER SHIPPING NAME: PHOSPHOORIC ACID, 8,
UN1805, PGIII. HAZARD CLASS: 8. INEDNTIFICATION NUMBER: UN1805. DOT
EMERGENCY GUIDE NUMBER: 154. REPORTABLE QUANTITY (RQ): 465 GALLONS
(PHOSPHORIC ACI D). INTERNATIONAL: PHOSPHORIC ACID, 8, UN1805,
PGIII, IMDG 8204.

SARA Title III Information:SARA TITLE III, SECTION 313: PHOSPHORIC
ACID, CAS# 7664-36-2, 70-80%.
Federal Regulatory Information:TSCA: COMPONENTS OF THIS PRODUCT LISTED
ON THE TSCA INVENTORY. CERCLA: THE REPORTABLE QUANTITY (RQ) IS 465
LBS.
State Regulatory Information:CALIFORNIA PROPOSITION 65: NOT LISTED.
STATE RIGHT TO KNOW PROGRAMS: NJ, MA, PA.