Product ID:GRISOLVE MT-N
MSDS Date:09/01/1995
FSC:6850
NIIN:01-202-2964
MSDS Number: BHCLG

GRIGNARD CO INC

900 PORT READING AVE
PORT READING, NJ 07064-0221
US

Emergency Phone: 908-541-6661

Info Phone: 908-541-6661

Cage: 27843

GRIGNARD CO INC

PORT READING, NJ 07064-1044 US

Telephone: 731-541-1916

Cage: 27843

METHYLENE CHLORIDE (SARA 313) (CERCLA)

CAS: 75-09-2

RTECS: PA8050000

OSHA PEL 25 PPM

ACGIH TLV: 50 PPM, A2; 9596

EPA Report Quantity: 1000 LBS

DOT Report Quantity: 1000 LBS

METHYL CHLOROFORM (1,1,1-TRICHLOROEHANE) (SARA 313)

CAS: 71-55-6

RTECS: KJ2975000

OSHA PEL 350 PPM

ACGIH TLV: 350 PPM/450STEL;9596

EPA Report Quantity: 1000 LBS

DOT Report Quantity: 1000 LBS

LD50 LC50 Mixture:LD50 (ORAL, RAT) IS UNKNOWN.
Routes of Entry: Inhalation:YES Skin:NO Ingestion:NO
Reports of Carcinogenicity:NTP:NO IARC:NO OSHA:NO
Health Hazards Acute and Chronic:TARGET ORGANS:CARDIAC, LIVER, CNS,
KIDNEY. ACUTE- INHALATION OF HIGH CONCENTRATIONS OF VAPORS MAY
CAUSE CNS EFFECTS. MAY CAUSE EYE IRRITATION. MAY CAUSE DEFATTING OF
SKIN & IRRITATION. INGESTION MAY R ESULT IN IRRITATION OF GI TRACT.
OVEREXPOSURE MAY CAUSE CARDIAC & LIVER ABNORMALITY, KIDNEY DAMAGE.
CHRONIC- DERMATITIS.
Explanation of Carcinogenicity:NONE
Effects of Overexposure:HEADACHE, DROWSINESS, DIZZINESS, LOSS OF
COORDINATION, IRRITATION, SKIN DEFATTING, DIARRHEA, ABDOMINAL PAIN,
CONFUSION
Medical Cond Aggravated by Exposure:PERSONS WITH PRE-EXISTING SKIN
DISORDERS, EYE PROBLEMS OR IMPAIRED LIVER, KIDNEY, CARDIAC, CNS OR
RESPIRATORY FUNCTION MAY BE MORE SUSCEPTIBLE TO THE EFFECTS OF THIS
PRODUCT.

First Aid:GET MEDICAL HELP IF SYMPTOMS PERSIST. INHALED:MOVE TO FRESH
AIR. PROVIDE CPR/OXYGEN IF NEEDED. EYES:FLUSH WITH WATER FOR 15
MINUTES. HOLD EYELIDS OPEN. SKIN:WASH WITH SOAP & WATER. ORAL:GET
MEDICAL AT TENTION. NOTE TO PHYSICIAN: NEVER ADMINISTER ADRENALINE
FOLLOWING OVER EXPOSURE. INCREASED SENSITIVITY OF HEART TO
ADRENALINE MAY BE CAUSED BY OVEREXPOSURE.

Flash Point:NONE
Lower Limits:14%
Upper Limits:22%
Extinguishing Media:WATER FOG. WATER SPRAY MAY BE USED TO KEEP FIRE
EXPOSED CONTAINERS COOL.
Fire Fighting Procedures:WEAR FULL PROTECTIVE CLOTHING AND
NIOSH-APPROVED SELF-CONTAINED BREATHING APPARATUS WITH FULL
FACEPIECE OPERATED IN THE POSITIVE PRESSURE MODE.
Unusual Fire/Explosion Hazard:VAPORS CONCENTRATED IN CONFINED/POORLY
VENTILATED AREAS CAN BE IGNITED UPON CONTACT WITH OPEN IGNITION
SOURCES. CAN PRODUCE HYDROGEN CHLORIDE AND PHOSGENE.

Spill Release Procedures:WEAR PROTECTIVE EQUIPMENTS. VENTILATE AREA
WELL. PICK UP WITH INERT ABSORBENT MATERIAL SUCH AS SAND OR
VERMICULITE. SWEEP INTO APPROVED CONTAINERS FOR DISPOSAL. AVOID
CONTAMINATING ENVIRONMENTS. DO NO T FLUSH TO SEWERS OR WATERWAYS.
Neutralizing Agent:NOT RELEVANT

Handling and Storage Precautions:STORE IN CLOSED CONTAINERS, IN
VENTILATED AREA AWAY FROM OPEN FLAMES, RED HOT SURFACES AND WELDING
ARCS.
Other Precautions:KEEP OUT OF REACH OF CHILDREN. FOR INDUSTRIAL USE
ONLY. AVOID BREATHING VAPORS. AVOID CONTACT WITH EYES AND SKIN.
VAPORS HEAVIER THAN AIR AND WILL COOLECT IN LOW AREAS. DO NOT ENTER
SUCH AREAS UNLESS SPECIAL BREATHING APPARATUS IS USED.

Respiratory Protection:IF TLV IS EXCEEDED OR IN EVENT OF A SPILL, WEAR
NIOSH APPROVED RESPIRATORY EQUIPMENT FOR ORGANIC VAPOR. USE
SELF-CONTAINED BREATHING APPARATUS OPERATD IN PRESSURE DEMAND MODE
FOR WORK PERFORMED IN CON FINED PLACES. REFER TO 29CFR 1910.134.
Ventilation:USE LOCAL EXHAUST OR DILUTION VENTILATION AS APPROPRIATE TO
CONTROL EXPOSURE TO BELOW PERMISSIBLE LIMITS.
Protective Gloves:NITRILE, PVA
Eye Protection:SPLASH PROOF GOGGLES/FACE SHIELD
Other Protective Equipment:BOOTS, APRON OR CHEMICAL SUITS TO MINIMIZE
EXPOSURE. EYE WASH STATION & SAFETY SHOWER RECOMMENDED.
Work Hygienic Practices:WASH THOROUGHLY AFTER USE AND BEFORE EATING,
DRINKING OR USING TOILET FACILITIES.
Supplemental Safety and Health
FORMULA CHANGED. FOR PREVIOUS FORMULATION, SEE PNI A, SAME NSN.

HCC:T4
NRC/State Lic Num:NOT RELEVANT
Boiling Pt:B.P. Text:116F,47C
Decomp Temp:Decomp Text:340F,171C
Vapor Pres:355 @ 68F
Vapor Density:>1
Spec Gravity:1.312
Evaporation Rate & Reference:1.5 (N-BUTYL ACETATE=1)
Solubility in Water:NONE
Appearance and Odor:TRANSPARENT LIQUID - SLIGHT ODOR

Stability Indicator/Materials to Avoid:YES
Stability Condition to Avoid:OPEN FLAMES, WELDING ARCS
Hazardous Decomposition Products:MAY FORM CARBON MONOXIDE, CARBON
DIOXIDE, HYDROCHLORIC ACID, PHOSGENE, CHLORINE.

Waste Disposal Methods:MATERIAL MAY BE DISPOSED OF BY A LICENSED
RECLAIMER. COMPLY WITH LOCAL, STATE AND FEDERAL LAWS.

Disclaimer (provided with this information by the compiling agencies):
This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.