Product ID:MIL-C-81302, CLEANING SOLVENT
MSDS Date:10/19/1990
FSC:6850
NIIN:00-105-3084
MSDS Number: BJCXY

SPEER PRODUCTS INC

4242 B F GOODRICH BLVD
MEMPHIS, TN 38118-6920
US

Emergency Phone: 901-362-1950

Info Phone: 901-362-1950

Preparer: DGSC-SSH

Cage: FO248

SPEER PRODUCTS INC

18993 MEMPHIS, TN 38118-6920 US

Telephone: 901-362-1950/901-754-6155

Cage: FO248

1,1,2-TRICHLORO-1,2,2-TRIFLUOROETHANE (FREON 113) (SARA

CAS: 76-13-1

RTECS: KJ4000000

OSHA PEL 1000PPM/1250STEL

ACGIH TLV: 1000PPM/1250STEL9192

THE PROPELLANT OF THE MATERIAL PURCHASED IN 1976 WAS

RTECS: 9999999ZZ

OSHA PEL NOT RELEVANT

ACGIH TLV: NOT RELEVANT

DICHLORODIFLUOROMETHANE (SARA III)

CAS: 75-71-8

RTECS: PA8200000

OSHA PEL 1000 PPM

ACGIH TLV: 1000 PPM; 9192

EPA Report Quantity: 5000 LBS

DOT Report Quantity: 5000 LBS

LD50 LC50 Mixture:LD 50 ORAL RAT 43000 MG/KG
Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:NO IARC:NO OSHA:NO
Health Hazards Acute and Chronic:PRODUCT IS NEITHER CORROSIVE NOR AN
IRRITANT. IT WILL DEFAT & DRY SKIN,POSSIBLY CAUSING DERMATITIS.
VAPOR IS HEAVIER THAN AIR AND CAN CAUSE SUFFOCATION BY REDUCING
OXYGEN AVAILABLE FOR BREATHING.
Explanation of Carcinogenicity:FREON 113 IS NOT LISTED AS A CARCINOGEN
BY IARC, NTP OR OSHA.
Effects of Overexposure:BREATHING HIGH CONCENTRATIONS OF VAPOR MAY
CAUSE LIGHT-HEADEDNESS, GIDDINESS, SHORTNESS OF BREATH, AND MAY
LEAD TO NARCOSIS, CARDIAC IRREGULARITIES, UNCONSCIOUSNESS OR DEATH.
LIQUID CAN CAUSE DEFATTIN G OF TISSUE.
Medical Cond Aggravated by Exposure:SKIN DISEASE - FREON 113 IS A
DEFATTING AGENT AND CAN CAUSE DERMATITIS ON PROLONGED EXPOSURE.
PERSONS WITH PRE-EXISTING SKIN DISORDERS MAY BE MORE SUSCEPTIBLE TO
THE EFFECTS OF THIS AGENT.

First Aid:EYE:FLUSH W/ WATER 15 MIN HOLD LIDS OPEN SEE A DOCTOR.
SKIN:WASH WITH SOAP & WATER. TREAT FOR FROST-BITE IF NEEDED.
INHALED:REMOVE TO FRESH AIR. RESTORE BREATHING, AS NEEDED. DO NOT
GIVE EPINEPHRINE OR SIMILAR DRUGS. INGESTED:DO NOT INDUCE
VOMITING. GET IMMEDIATE MEDICAL CARE. IF IRRITATION PERSISTS,OR
IS SEVERE,SEE A DOCTOR.

Flash Point:NONE
Extinguishing Media:PRODUCT IS NON FLAMMABLE. EXTINGUISH FIRE WITH
MEDIA APPROPRIATE FOR SOURCE OF FIRE.
Fire Fighting Procedures:FIRE FIGHTERS SHOULD USE NIOSH APPROVED SCBA &
FULL PROTECTIVE EQUIPMENT WHEN FIGHTING CHEMICAL FIRE. USE WATER
SPRAY TO COOL NEARBY CONTAINERS EXPOSED TO FIRE.
Unusual Fire/Explosion Hazard:CONTENTS UNDER PRESSURE! EXPOSURE TO
TEMPERATURES OVER 130 F MAY RESULT IN RUPTURE OF THE CONTAINER.

Spill Release Procedures:VENTILATE AREA. DO NOT FLUSH INTO SEWERS.
COLLECT ON ABSORBENT MATERIAL AND TRANSFER TO STEEL DRUMS FOR
RECOVERY OR DISPOSAL.
Neutralizing Agent:NONE

Handling and Storage Precautions:STORE IN A CLEAN, COOL, DRY AND
WELL-VENTILATED AREA OF LOW FIRE RISK. PROTECT CONTAINERS FROM
PHYSICAL DAMAGE AND KEEP CLOSED.
Other Precautions:PERSONNEL USING THIS PRODUCT IN ENCLOSED AREAS SHOULD
USE ONLY FORMAL TANK ENTRY PROCEDURE BASED ON RECOGNIZED SAFETY
PRINCIPLES. APPLY ALL SAFETY PRECAUTIONS TO EMPTY CONTAINERS AS
THEY MAY CONTAIN P RODUCT RESIDUES/VAPORS OR PRESSURES.

Respiratory Protection:RESPIRATOR WILL NOT NORMALLY BE NECESSARY. USE
NIOSH/MSHA APPROVED AIR SUPPLIED RESPIRATOR OR SELF CONTAINED
BREATHING APPARATUS IF EXPOSURE IS ABOVE THE TLV/PEL. SEE 29 CFR
1910.134 FOR REGULATIONS PERTAINING TO RESPIRATOR USE.
Ventilation:PROVIDE LOCAL EXHAUST AT FILLING ZONES AND OTHER OPERATING
SPACES WHERE LEAKAGE IS PROBABLE. MECHANICAL FOR OTHER.
Protective Gloves:LINED BUTYL RUBBER, PVA OR NEOPRENE
Eye Protection:SAFETY GLASSES OR SPLASH GOGGLES
Other Protective Equipment:USE IMPERVIOUS CLOTHING IF THERE IS DANGER
OF REPEATED OR PROLONGED CONTACT WITH LIQUID.
Work Hygienic Practices:USE GOOD CHEMICAL HYGIENE PRACTICE. AVOID
CONTACT. REMOVE AND WASH CLOTHING PROMPTLY UPON CONTAMINATION.
Supplemental Safety and Health
MSDS ORIGIONATED 19OCT90 BY DGSC-SSH TO COVER MATERIAL PURCHASED IN
1976 ON CONTRACT DLA400-76C-1046. MFR HAD NO RECORDS OF THE
CONTRACT. SPECIFICATION DETAILS LIQUID CONTENTS. PROPELLANT WAS
PROBAB LY DICHLOROMETHANE AT THAT TIME.

HCC:V2
Boiling Pt:B.P. Text:118F,48C
Spec Gravity:1.57
Solubility in Water:NEGLIGIBLE
Appearance and Odor:CLEAR COLORLESS LIQUID, SLIGHT SOLVENT ODOR
Percent Volatiles by Volume:100

Stability Indicator/Materials to Avoid:YES
ALKALI, ALKALINE EARTH METALS, POWDERED REACTIVE METALS SUCH AS
ALUMINUM, ZINC, ETC.
Stability Condition to Avoid:TEMPERATURES ABOVE 130F
Hazardous Decomposition Products:DECOMPOSED BY HIGH TEMPERATURES (OPEN
FLAMES, GLOWING METAL SURFACES, ETC.) FORMING HYDROCHLORIC AND
HYDROFLUORIC ACIDS.

Waste Disposal Methods:DISPOSE I/A/W ALL FEDERAL, STATE AND LOCAL
REGULATIONS. MANUFACTURER SUGGESTS THAT RECLAIMATYION BY
DISTILLATION OR DISPOSAL BY A PERMITTED FACILITY.

Disclaimer (provided with this information by the compiling agencies):
This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.