Product ID:SPECIALLY DENATURED ETHYL ALCOHOL 3A
MSDS Date:04/01/1989
FSC:6810
NIIN:00-201-0907
MSDS Number: BJDLN

GRAIN PROCESSING CROP

1600 OREGON ST
MUSCATINE, IA 52761
US

Emergency Phone: 319-264-4265

Info Phone: 319-264-4265

Cage: GRAIN

HOC INDUSTRIES, INC

2609 WICHITA, KS 67219 US

Telephone: 316-838-4663

Cage: 0A9L8

ETHYL ALCOHOL (ETHANOL)

CAS: 64-17-5

RTECS: KQ6300000

Fraction By Weight: 95.22%

OSHA PEL 1000 PPM

ACGIH TLV: 1000 PPM; 9192

METHYL ALCOHOL (METHANOL) (SARA III)

CAS: 67-56-1

RTECS: PC1400000

Fraction By Weight: 4.78%

OSHA PEL S,200PPM/250STEL

ACGIH TLV: S,200PPM/250STEL; 93

EPA Report Quantity: 5000 LBS

DOT Report Quantity: 5000 LBS

LD50 LC50 Mixture:LD50 (ORAL RAT) IS 7060 MG/KG (ETHANOL)
Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:NO IARC:NO OSHA:NO
Health Hazards Acute and Chronic:ACUTE: MAY BE FATAL IF SWALLOWED.
HARMFUL IF INHALED OR ABSORBED THROUGH THE SKIN. CAUSES SKIN, EYE,
AND UPPER RESPIRATORY TRACT IRRITATION. CAN CAUSE CENTRAL NERVOUS
SYSTEM DEPRESSION. CHRONIC: DAMAG E TO THE LIVER, DAMAGE TO THE
HEART, DAMAGE TO THE KIDNEYS.
Explanation of Carcinogenicity:NONE OF THE COMPOUNDS IN THIS PRODUCT IS
LISTED BY IARC, NTP, OR OSHA AS A CARCINOGEN.
Effects of Overexposure:SEE HEALTH HAZARDS.
Medical Cond Aggravated by Exposure:PERSONS WITH A HISTORY OF AILMENTS
OR WITH A PRE-EXISTING DISEASE INVOLVING THE SKIN, EYE, RESPIRATORY
TRACT, LIVER OR KIDNEY MAY BE AT INCREASED RISK FROM EXPOSURE.

First Aid:INHALATION:REMOVE TO FRESH AIR. RESUSCITATE IF NOT BREATHING.
GET MEDICAL ATTENTION. EYES:IMMEDIATELY FLUSH WITH PLENTY OF WATER
FOR 15 MINUTES. GET MEDICAL ATTENTION. SKIN:REMOVE CONTAMINATED
CLOTHIN G. FLUSH WITH WATER. IF IRRITATION PERSISTS, GET MEDICAL
ADVICE. INGESTION:DO NOT INDUCE VOMITING UNLESS INSTRUCTED TO DO
SO. GIVE NOTHING BY MOUTH IF UNCONSCIOUS. GET IMMEDIATE MEDICAL
ATTENTION.

Flash Point Method:TOC
Flash Point:60.0F,15.6C
Lower Limits:3.3
Upper Limits:19.0
Extinguishing Media:USE CARBON DIOXIDE, "ALCOHOL-TYPE" FOAM, OR DRY
CHEMICAL.
Fire Fighting Procedures:FIRE FIGHTERS SHOULD USE NIOSH APPROVED SCBA &
FULL PROTECTIVE EQUIPMENT WHEN FIGHTING CHEMICAL FIRE. USE WATER
SPRAY TO COOL NEARBY CONTAINERS EXPOSED TO FIRE.
Unusual Fire/Explosion Hazard:VAPORS FORM FROM THIS PRODUCT AND MAY
TRAVEL OR MOVE BY AIR CURRENTS TO AN IGNITION SOURCE AND FLASH
BACK.

Spill Release Procedures:WEAR APPROPRIATE RESPIRATORY PROTECTION AND
PROTECTIVE CLOTHING. CONTAIN SPILLED MATERIAL. TRANSFER TO SECURE
CONTAINERS. WHERE NECESSARY, COLLECT USING ABSORBENT MEDIA.
ELIMINATE ANY SOURCE OF IGNITI ON. VENTILATE AREA. WASH RESIDUE
WITH WATER.
Neutralizing Agent:NOT APPLICABLE.

Handling and Storage Precautions:STORE IN A FLAMMABLE LIQUID STORAGE
ROOM OR CABINET. KEEP CONTAINERS TIGHTLY CLOSED WHEN NOT IN USE.
PROTECT CONTAINERS FROM PHYSICAL DAMAGE.
Other Precautions:MAKE FREQUENT CAREFUL LEAKAGE INSPECTIONS. ISOLATE
FROM OXIDEZERS, CHEMICALS CAPABLE OF SPONTANEOUS HEATING, MATERIALS
REACTING WITH AIR OR MOISTURE TO LIBERATE HEAT, IGNITION SOURCES
AND EXPLOSIVES. KEEP OUT OF DIRECT SUN & AWAY FROM HEAT.

Respiratory Protection:IF VENTILATION DOES NOT MAINTAIN INHALATION
EXPOSURES BELOW PEL(TLV), USE NIOSH/MSHA APPROVED RESPIRATORS.
RESPIRATORS SHOULD BE SELECTED BASED ON THE FORM AND CONCENTRATION
OF CONTAMINANT IN AIR & IN ACCORDANCE WITH OSHA (29 CFR 1910.134).
Ventilation:MECHANICAL (GENERAL) ROOM VENTILATION IS NORMALLY ADEQUATE.
LOCAL EXHAUST MAY BE REQUIRED IF WORK AREA NOT VENTED.
Protective Gloves:NEOPRENE, NITRILE, VPC OR NATURAL RUBBER
Eye Protection:SAFETY GOGGLES WITH OPTIONAL FACE SHIELD
Other Protective Equipment:EYE WASH STATION AND SAFETY SHOWER.
INDUSTRIAL-TYPE WORK CLOTHING AND APRON AS REQUIRED.
Work Hygienic Practices:OBSERVE GOOD PERSONAL HYGIENE PRACTICES AND
RECOMMENDED PROCEDURES. DO NOT WEAR CONTAMINATED CLOTHING OR
FOOTWEAR.
Supplemental Safety and Health
AVOID PROLONGED OR REPEATED EXPOSURE. DO NOT GET ON SKIN OR IN EYES. DO
NOT BREATHE VAPORS OR MISTS. CAUTION: FOR MANUFACTURING,
PROCESSING, REPACKING OR INDUSTRIAL USE. NOT FOR HOUSHOLD USE.
CONTAINE R HAZARDOUS WHEN EMPTY. EMPTIED CONTAINERS RETAIN RESIDUAL
LIQUID AND VAPOR. FOLLOW PRECAUTIONS ON LABEL AND IN MSDS.

HCC:F5
Boiling Pt:B.P. Text:173F,78C
Vapor Pres:43.9
Vapor Density:1.59
Spec Gravity:0.794
Evaporation Rate & Reference:2.0 (N-BUTYL ACETATE=1)
Solubility in Water:INFINITE
Appearance and Odor:COLORLESS; WATER WHITE LIQUID; MILD, FRAGRANT ODOR
Percent Volatiles by Volume:100

Stability Indicator/Materials to Avoid:YES
STRONG OXIDIZING AGENTS
Stability Condition to Avoid:HIGH TEMPERATURES, SPARKS, AND OPEN FLAMES
Hazardous Decomposition Products:CARBON MONOXIDE CAN FORM ON INCOMPLETE
COMBUSTION.

Waste Disposal Methods:ALL RECOVERED MATERIAL SHOULD BE PACKAGED,
LABELED, TRANSPORTED, AND DISPOSED OR RECLAIMED IN ACCORDANCE WITH
ALL APPLICABLE FEDERAL, STATE AND LOCAL LAWS AND REGULATIONS AND IN
CONFORMANCE WITH GOOD ENGINEERING PRACTICES.

Disclaimer (provided with this information by the compiling agencies):
This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.