Product ID:6011
MSDS Date:12/20/1988
FSC:3439
NIIN:00-262-2652
MSDS Number: BKBKF

TRI-MARK INC

8585 INDUSTRY PARK DR
PIQUA, OH 45356-9511
US

Emergency Phone: 513-773-2010

Info Phone: 513-773-2010

Cage: 1X069

TRI-MARK INC

PIQUA, OH 45356-9511 US

Telephone: 800-543-8934

Cage: 1X069

IRON

CAS: 7439-89-6

RTECS: NO4565500

Fraction By Weight: 70-90%

MANGANESE (SARA III)

CAS: 7439-96-5

RTECS: OO9275000

Fraction By Weight: 1-6%

OSHA PEL (C) 5 MG/M3 DUST

ACGIH TLV: 5 MG/M3 DUST 9293

TITANIUM DIOXIDE

CAS: 13463-67-7

RTECS: XR2275000

Fraction By Weight: 2-10%

OSHA PEL 15 MG/M3 TDUST

ACGIH TLV: 10 MG/M3 TDUST; 9293

POTASSIUM SILICATE

CAS: 1312-76-1

Fraction By Weight: <5%

SODIUM SILICATE

CAS: 1344-09-8

Fraction By Weight: 3-15%

LD50 LC50 Mixture:UNCLASSIFIED WELDING FUMES=5MG/M3 PEL
Routes of Entry: Inhalation:YES Skin:YES Ingestion:NO
Reports of Carcinogenicity:NTP:NO IARC:NO OSHA:NO
Health Hazards Acute and Chronic:SHORT TERM EXPOSURE TO WELDING FUMES,
GASES OR DUST MAY RESULT IN DISCOMFORT SUCH AS DIZZINESS, NAUSEA,
FEVER, DRYNESS AND/OR IRRITATION OF NOSE, THROAT AND EYES. SKIN
SENSITIVITY MAY ALSO BE NOTED. A CUTE EXPOSURE FROM SOME TOXIC
GASES MAYCAUSE PULMONARY EDEMA, ASPHYXIATION AND EXCESSIVE EXPOSURE
CAN BE FATAL.
Explanation of Carcinogenicity:NICKEL AND CHROMIUM ARE CONSIDERED
POSSIBLE CARCINOGENS UNDER OSHA. RESPIRATORY CANCER FROM WELDING IS
UNCONFIRMED.
Effects of Overexposure:EXPOSURE TO WELDING FUMES MAY RESULT IN
DISCOMFORT SUCH AS DIZZINESS, NAUSEA, FEVER, DRYNESS AND/OR
IRRITATION OF NOSE, THROAT AND EYES. SKIN SENSITIVITY MAY ALSO BE
NOTED. WATERY EYES, HEADACHE, BREA THING DIFFICULTY, FREQUENT
COUGHING AND/OR CHEST PAINS MAY OCCUR FROM ACUTE EXPOSURE. TOXIC
GASES CAN BE FATAL.
Medical Cond Aggravated by Exposure:SOME WORKERS MAY BE AFFECTED BY A
PRE-EXISTING CONDITION OR OTHER OCCUPATIONAL ILLNESS BECAUSE OF THE
WIDE VARIATION IN INDIVIDUAL SUSCEPTIBILITIES.

First Aid:IN CASE OF ELECTRICAL SHOCK, TURN OFF POWER PRIOR TO REMOVAL
FROM EXPOSURE AREA AND ADMINISTRATION OF FIRST AID. REMOVE FROM
EXPOSURE AREA AND CALL FOR MEDICAL AID. ADMINISTER OXYGEN IF
BREATHING IS D IFFICULT. IF NOT BREATHING, BEGIN ARTIFICIAL
RESPIRATION. IF NO DETECTABLE PULSE, BEGIN EXTERNAL HEART MASSAGE.
EMPLOY FIRST AID TECHNIQUES RECOMMENDED BY THE AMERICAN RED CROSS.

Extinguishing Media:USE WATER FOG, CARBON DIOXIDE, FOAM, OR DRY
CHEMICAL.
Fire Fighting Procedures:WEAR FIRE FIGHTING PROTECTIVE EQUIPMENT AND A
FULL FACED SELF CONTAINED BREATHING APPARATUS. EVACUATE AREA. COOL
FIRE EXPOSED CONTAINERS WITH WATER SPRAY.
Unusual Fire/Explosion Hazard:COMBUSTION OR HEAT OF FIRE MAY PRODUCE
HAZARDOUS DECOMPOSITION PRODUCTS AND VAPORS.

Spill Release Procedures:CLEAN UP ANY GRINDING DUST OR WASTE RESIDUES
AND PLACE IN SUITABLE DOT APPROVED CONTAINERS AND DISPOSE OF IN
FULL COMPLIANCE WITH FEDERAL, STATE AND LOCAL REGULATIONS. AVOID
INHALATION AND SKIN EXPOSU RE.

Handling and Storage Precautions:WEAR GLOVES AND FLAME RETARDANT
CLOTHING WHEN CUTTING, GRINDING OR WELDING. DO NOT EXPOSE SKIN TO
RADIATION WHEN HOT CUTTING OR WELDING.
Other Precautions:PROVIDE PROTECTIVE SCREENS TO SHIELD OTHERS. WHEN
ELECTRODES AND FLUXES ARE CONSUMED, THE FUME AND GAS DECOMPOSITION
PRODUCTS GENERATED ARE DIFFERENT IN FORM FROM THE INGREDIENTS
LISTED. NEW COMPOUNDS NOT IN THE ELECTRODES MAY FORM.

Respiratory Protection:USE WELD FUME RESPIRATOR OR AIR SUPPLIED
RESPIRATOR WHEN CUTTING, GRINDING OR WELDING IN A CONFINED SPACE OR
WHERE LOCAL EXHAUST OR GENERAL VENTILATION DOES NOT KEEP EXPOSURE
BELOW RECOMMENDED LIMITS. USE ONLY NIOSH APPROVED RESPIRATORS.
Ventilation:USE ENOUGH VENTILATION WHEN CUTTING, GRINDING OR WELDING TO
KEEP THE DUST, FUMES & GASES FROM THE WORKERS BREATHING ZONE
Protective Gloves:WELDERS LEATHER GLOVES
Eye Protection:OSHA APPROVED GOGGLES/FACE SHIELD W/LENS
Other Protective Equipment:FLAME RETARDANT CLOTHING WHEN CUTTING,
GRINDING OR WELDING. DO NOT EXPOSE SKIN TO RADIATION WHEN HOT
CUTTING OR WELDING.
Work Hygienic Practices:WASH THOROUGHLY BEFORE EATING OR SMOKING.
LAUNDER CONTAMINATIED CLOTHING BEFORE REUSE.
Supplemental Safety and Health
WELDING AND HOT CUTTING FUMES & GASES CANNOT BE CLASSIFIED SIMPLY.
THEIR COMPOSITION AND QUANTITY ARE DEPENDENT ON THE METAL BEING
WELDED, THE PROCEDURES, PROCESSES AND THE TYPE OF WIRE OR
ELECTRODES USED. OTHER INFLUENCING FACTORS ARE THEPRESENCE OF
CONTAMINANTS. CHLORINATED SOLVENTS MAY DECOMPOSE TO TOXIC GASES.

HCC:N1
Appearance and Odor:ROD

Stability Indicator/Materials to Avoid:YES
STRONG ACIDS AND BASES
Stability Condition to Avoid:NONE
Hazardous Decomposition Products:WELDING AND CUTTING OPERATION MAY
INCLUDE OXIDES OF THE METALS, CHROMATES, FLUORIDES, COMPLEX
METALLICS, AND OZONE.

Waste Disposal Methods:DISPOSE I/A/W FEDERAL, STATE & LOCAL REGULATIONS

Disclaimer (provided with this information by the compiling agencies):
This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.